2-pyridinecarboxaldehyde isophthalylhydrazone | 374109-80-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-pyridinecarboxaldehyde isophthalylhydrazone
• CAS: 374109-80-5
• 化学式: C₂₀H₁₆N₆O₂
• 分子量: 372.386
• InChiKey: YFDCAKWWSVLOEP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.0
• 重原子数：
  28.0
• 可旋转键数：
  6.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  108.7
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  2-pyridinecarboxaldehyde isophthalylhydrazone 、 lead acetate 以 甲醇 为溶剂， 以80%的产率得到(lead)2(acetate)2(2-pyridinecarboxaldehyde isophthalylhydrazone)
  参考文献：
  名称：

  Synthesis and Characterization of a Novel Lead Complexes with Isophthalyl Bishydrazones

  摘要：

  Lead acetate reacts with 2-pyridinecarboxadehyde isophthalyl-hydrazone (H(2)pcph) giving a dinucleic [Pb-2(pcph) Ac-2] complex. As shown by X-ray crystal analysis, each lead ion is coordinated by one hydrazide nitrogen, one pyridine nitrogen, one carbonyl oxygen, and one acetate oxygen, giving rise to a unusually N2O2 distorted planar square coordination geometry.

  DOI：

  10.1080/15533170701608759

文献信息

• Metallohelical Triangles for Selective Detection of Adenosine Triphosphate in Aqueous Media
  作者：Hongmei Wu、Cheng He、Zhihua Lin、Yang Liu、Chunying Duan

  DOI：10.1021/ic801350h

  日期：2009.1.19

  Metallohelical triangles consisting of chromophore units and hydrogen-bonding trigger sites were prepared by modulating two tridentate N2O units containing amide groups within a central benzene ring at the meta sites, for the selective detection of adenosine trisphosphate in aqueous media over other ribonucleotides.