2-phenylmethylene-S-ethylhydrazinecarbothiamide hydrobromide | 92734-55-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-phenylmethylene-S-ethylhydrazinecarbothiamide hydrobromide
• 英文别名: benzaldehyde-S-ethyl-thiosemicarbazone hydrobromide
• CAS: 92734-55-9
• 化学式: BrH*C₁₀H₁₃N₃S
• 分子量: 288.211
• InChiKey: ADFWHYIWQUFMCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.67
• 重原子数：
  15.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  50.74
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  2-phenylmethylene-S-ethylhydrazinecarbothiamide hydrobromide 、 mercury dichloride 以 二氯甲烷 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Uelkueseven, B., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1995, vol. 25, p. 1549 - 1560

  摘要：

  DOI：

文献信息

• Palladium(II) complexes of benzaldehyde and 2-hydroxybenzaldehyde-4-H/phenyl-S-ethyl/allyl-thiosemicarbazones
  作者：Ayhan Yavuz Genel、Bahri Ülküseven、İrfan Kızılcıklı

  DOI：10.1134/s0036023608110132

  日期：2008.11

  The thiosemicarbazone derivatives R-1-C6H4-CH=N-N=(C-S-R-2)-NH-R-3 [R-1 = H, OH; R-2 = H, Ph; R-3 = C2H5, C3H5] were prepared by a modified general method. The Pd(II) complexes of the thiosemicarbazone ligands LI-VIsupercript stop were isolated in the compositions [Pd(L)Cl-2], [Pd(L)Cl] and [Pd(L)(2)]. The 1: 1 and 1: 2 metal complexes have non-ionic character, and the compounds were characterized by analytical data and infrared and proton resonance spectroscopy. The cis-trans and syn-anti isomers of the thiosemicarbazones were determined by means of1supercript stopH NMR, and the coordination behavior of the polydentate thiosemicarbazone ligands towards the palladium ion were discussed.