4,4,4-(1,3,5-三嗪-2,4,6-三基)三(([[1,1-联苯]-4-胺)) | 2130745-76-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4,4,4-(1,3,5-三嗪-2,4,6-三基)三(([[1,1-联苯]-4-胺))
• 英文名称: 4,4’,4’’-(1,3,5-triazine-2,4,6-triyl)tris[(1,1’-biphenyl)-4-amine]
• 英文别名: 4',4''',4'''''-(1,3,5-Triazine-2,4,6-triyl)tris(([1,1'-biphenyl]-4-amine))；4-[4-[4,6-bis[4-(4-aminophenyl)phenyl]-1,3,5-triazin-2-yl]phenyl]aniline
• CAS: 2130745-76-3
• 化学式: C₃₉H₃₀N₆
• 分子量: 582.707
• InChiKey: YZHZLVSLFBPKBX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  45
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  117
• 氢给体数：
  3
• 氢受体数：
  6

安全信息

• 危险性防范说明：
  P261,P280,P301+P312,P302+P352,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335

反应信息

• 作为产物：
  描述：

  4'-氨基-4-氰基联苯 在 三氟甲磺酸 作用下， 生成 4,4,4-(1,3,5-三嗪-2,4,6-三基)三(([[1,1-联苯]-4-胺))
  参考文献：
  名称：

  基于无金属三嗪的二维共价有机框架通过电化学水分解高效释放氢气

  摘要：

  释放 HER：共价有机骨架 C 6 -TRZ-TFP 是通过 2-羟基苯-1,3,5-三甲醛 (TFP) 和 4,4',4''-(1,3,5 -triazine-2,4,6-triyl)tris[(1,1'-biphenyl)-4-amine]。C 6 -TRZ-TFP 在电化学水分解中表现出优异的析氢活性，过电位非常低，为 200 mV。

  DOI：

  10.1002/cssc.202101663

文献信息

• Selective Molecular Separation by Interfacially Crystallized Covalent Organic Framework Thin Films
  作者：Kaushik Dey、Manas Pal、Kanhu Charan Rout、Shebeeb Kunjattu H、Anuja Das、Rabibrata Mukherjee、Ulhas K. Kharul、Rahul Banerjee

  DOI：10.1021/jacs.7b06640

  日期：2017.9.20

  Exponential interest in the field of covalent organic frameworks (COFs) stems from the direct correlation between their modular design principle and various interesting properties. However, existing synthetic approaches to realize this goal mainly result in insoluble and unprocessable powders, which severely restrict their widespread applicability. Therefore, developing a methodology for easy fabrication of these materials remains an alluring goal and a much desired objective. Herein, we have demonstrated a bottom-up interfacial crystallization strategy to fabricate these microcrystalline powders as large-scale thin films under ambient conditions. This unique design principle exploits liquid-liquid interface as a platform, allowing simultaneous control over crystallization and morphology of the framework structure. The thin films are grown without any support in free-standing form and can be transferred onto any desirable substrate. The porous (with Tp-Bpy showing highest S-BET of 1 151 m(2) g(-1)) and crystalline thin films, having high chemical as well as thermal stability, also hold the merit to tune the thickness as low as sub-100 nm. These nanostructured thin COF films demonstrate remarkable solvent-permeance and solute-rejection performance. A prominent instance is the Tp-Bpy thin film, which displays an unprecedented acetonitrile permeance of 339 L m(-2) h(-1) bar(-1).