3,5-dimethylpyridine;trichlororhenium | 220011-34-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 3,5-dimethylpyridine;trichlororhenium
• CAS: 220011-34-7
• 化学式: C₂₁H₂₇Cl₃N₃Re
• 分子量: 614.031
• InChiKey: MIPKHYRLQBDPHD-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3,5-二甲基吡啶 、 (乙酰腈)三氯化二(三苯基膦)铼 以 neat (no solvent) 为溶剂， 以18%的产率得到3,5-dimethylpyridine;trichlororhenium
  参考文献：
  名称：

  Synthesis and NMR investigation on mer-[ReIIICl3(L)3] and mer-[ReIIICl3(L)2(PPh3)] complexes (L = pyridine-like ligand). X-ray structure of mer-[ReIIICl3(3,5-lut)3]

  摘要：

  The co-ordination geometry of the monomeric rhenium complexes mer-[(ReCl3)-Cl-III(L)(3)] (L = py 1,3,5-lut 2, 4-pic 3) has been determined in the solid state by single X-ray diffraction of the representative complex 2 and in solution by proton NMR spectroscopy. Only a single stable conformation has been found in the solid state and in solution, under the experimental conditions utilised. The NMR spectra of the related complexes mer-[(ReCl3)-Cl-III(L)(2)(PPh3)] (L = py 4, 3,5-lut 5, 4-vinpy 6) have also been reported for comparison purposes. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00186-7