Cd(2,4'-biphenyldicarboxylate)(2,2'-bipyridine) | 1258104-35-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cd(2,4'-biphenyldicarboxylate)(2,2'-bipyridine)
• CAS: 1258104-35-6
• 化学式: C₁₀H₈N₂*C₁₄H₈O₄*Cd
• 分子量: 508.812
• InChiKey: WAKNXXXURYOONZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.22
• 重原子数：
  31.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  106.04
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 [1,1-联苯]-2,4-二羧酸 、 cadmium(II) acetate dihydrate 在 NaOH 作用下， 以 水 为溶剂， 以62%的产率得到Cd(2,4'-biphenyldicarboxylate)(2,2'-bipyridine)
  参考文献：
  名称：

  Hydrothermal synthesis, crystal structures and photoluminescent properties of four cadmium(II) coordination polymers derived from diphenic acid and auxiliary ligands

  摘要：

  Four novel metal coordination polymers, [Cd(dpa)(H(2)O)](n) (1), [Cd(dpa)(2,2'-bipy)](n) (2), {[Cd(2)(dpa)(2)(4,4'-bipy) 3](4,4'-bipy)(H(2)O)(2)}(n) (3) and [Cd(dpa)(bim)(2)(H(2)O)]}(n) (4) (H(2)dpa = 2,4'-biphenyl-dicarboxylic acid, 2,2'-bipy = 2,2'-bipyridine, 4,4'-bipy = 4,4'-bipyridine, bim = benzimidazole), have been synthesized and structurally characterized by elemental analysis, IR and X-ray diffraction. Single-crystal X-ray analyses reveal that the 2,4'-diphenic acids acts as bridging ligands, exhibiting rich coordination modes to link metal ions: bis-monodentate, bidentate chelating, chelating/bridging, monoatomic bridging and monodentate modes. In addition, the luminescent properties for compound 1-4 are also investigated in this work. (c) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.05.038