trans-1-methoxy-4-phenyl butene | 69485-51-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-1-methoxy-4-phenyl butene
• 英文别名: [(3E)-4-methoxy-3-butenyl]benzene；[(E)-4-methoxybut-3-enyl]benzene
• CAS: 69485-51-4
• 化学式: C₁₁H₁₄O
• 分子量: 162.232
• InChiKey: SAFFQUSOFQZBNS-UXBLZVDNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  trans-1-methoxy-4-phenyl butene 生成 3-methoxy-4-(2-phenylethyl)dioxetane
  参考文献：
  名称：

  POSNER, GARY H.;WEBB, KEVIN S.;NELSON, WILLIAM M.;KISHIMOTO, TAKASHI;SELI+, J. ORG. CHEM., 54,(1989) N4, C. 3252-3254

  摘要：

  DOI：
• 作为产物：
  描述：

  1-Methoxy-4-phenyl-1-phenylsulfanyl-butan-2-ol 、 四乙基对甲苯磺酸铵 以96%的产率得到
  参考文献：
  名称：

  SHONO TATSUYA; MATSUMURA YOSHIHIRO; KASHIMURA SHIGENORI, TETRAHEDRON LETT., 1980, 21, NO 16, 1545-1548

  摘要：

  DOI：

文献信息

• [EN] METATHESIS POLYMERIZATION METHODS<br/>[FR] PROCÉDÉS DE POLYMÉRISATION PAR MÉTATHÈSE
  申请人：UNIV WASHINGTON

  公开号：WO2016036976A1

  公开（公告）日：2016-03-10

  The present disclosure is directed to methods of making a polymer, including exposing a reaction mixture including a strained cyclic unsaturated monomer and an organic initiator to a stimulus to provide an activated organic initiator, whereby the activated organic initiator is effective to polymerize the strained cyclic unsaturated monomer via a 4-membered carbocyclic intermediate to provide a polymer having constitutional units derived from the strained cyclic unsaturated monomer.

  本公开涉及制备聚合物的方法，包括将含有紧张的环状不饱和单体和有机引发剂的反应混合物暴露于刺激物中，以提供活性有机引发剂，通过4元环碳中间体，使活性有机引发剂有效地聚合紧张的环状不饱和单体，从而提供由紧张的环状不饱和单体导出的构成单元的聚合物。
• Phospinite-imidazolines and metal complexes thereof
  申请人：Menges Federik

  公开号：US20070010493A1

  公开（公告）日：2007-01-11

  Compounds of the formulae (I) and (Ia) where X 1 is secondary phosphino; R 3 is a hydrocarbon radical having from 1 to 20 C atoms, a heterohydrocarbon radical which has from 2 to 20 atoms and at least one heteroatorn selected from the group consisting of O, S, NH and NR, or an —SO 2 —R radical; R is C 1 -C 18 -alkyl, phenyl or benzyl; the radicals R 4 are each, or the two radicals R4 together a hydrocarbon radical having from 1 to 20 C atoms; R 01 is a hydrocarbon radical having from 1 to 20 C atoms; and R 02 and R′ o2 are each, independently of one another, a hydrogen atom or independently have the meaning of R 01 , or R 01 and R 02 together with the C atom to which they are bound form a three- to eight-membered hydrocarbon or hetero hydrocarbon ring. The compounds are chiral ligands for complexes of metals of transition groups I and VIII which act as catalysts for asymmetric additions, for example of hydrogen, onto prochiral unsaturated organic compounds.

  化合物的公式（I）和（Ia），其中X1是二级膦基；R3是具有1至20个C原子的碳氢基团，具有2至20个原子并且至少有一个杂原子（选自O，S，NH和NR的群体）的杂碳氢基团，或者是一个—SO2—R基团；R是C1-C18-烷基，苯基或苄基；基团R4是每个，或两个基团R4共同形成具有1至20个C原子的碳氢基团；R01是具有1至20个C原子的碳氢基团；R02和R'o2各自独立地是氢原子，或者独立地具有R01的含义，或者R01和R02与它们所连接的C原子一起形成一个三至八元环的碳氢或杂环碳氢基团。这些化合物是过渡金属I和VIII族的配合物的手性配体，可作为催化剂用于对不对称不饱和有机化合物的加成反应，例如氢的加成反应。
• Metal-Free Ring-Opening Metathesis Polymerization
  作者：Kelli A. Ogawa、Adam E. Goetz、Andrew J. Boydston

  DOI：10.1021/ja512073m

  日期：2015.2.4

  We have developed a method to achieve ring-opening metathesis polymerization (ROMP) mediated by oxidation of organic initiators in the absence of any transition metals. Radical cations, generated via one-electron oxidation of vinyl ethers, were found to react with norbornene to give polymeric species with microstructures essentially identical to those traditionally obtained via metal-mediated ROMP

  我们开发了一种在没有任何过渡金属的情况下通过有机引发剂的氧化来实现开环复分解聚合 (ROMP) 的方法。发现通过乙烯基醚的单电子氧化产生的自由基阳离子与降冰片烯反应产生聚合物物质，其微观结构与传统上通过金属介导的 ROMP 获得的微观结构基本相同。我们发现乙烯基醚氧化可以在温和条件下使用有机光氧化还原介质完成。这导致聚合物的高产率以及 M(n) 值和初始单体与催化剂负载之间的良好相关性。此外，在曝光的开/关循环期间实现了对聚合物生长重新启动的时间控制。该方法展示了第一种用于受控 ROMP 的无金属方法。
• Metathesis polymerization methods
  申请人：University of Washington

  公开号：US10273327B2

  公开（公告）日：2019-04-30

  The present disclosure is directed to methods of making a polymer, including exposing a reaction mixture including a strained cyclic unsaturated monomer and an organic initiator to a stimulus to provide an activated organic initiator, whereby the activated organic initiator is effective to polymerize the strained cyclic unsaturated monomer via a 4-membered carbocyclic intermediate to provide a polymer having constitutional units derived from the strained cyclic unsaturated monomer.

  本公开涉及制造聚合物的方法，包括将包括应变环状不饱和单体和有机引发剂的反应混合物暴露于刺激下，以提供活化的有机引发剂，其中活化的有机引发剂可有效地通过 4 元碳环中间体聚合应变环状不饱和单体，以提供具有源自应变环状不饱和单体的构型单元的聚合物。
• POSNER, GARY H.;WEBB, KEVIN S.;NELSON, WILLIAM M.;KISHIMOTO, TAKASHI;SELI+, J. ORG. CHEM., 54,(1989) N4, C. 3252-3254
  作者：POSNER, GARY H.、WEBB, KEVIN S.、NELSON, WILLIAM M.、KISHIMOTO, TAKASHI、SELI+

  DOI：——

  日期：——