2,2,5,5-tetramethyl-4-phenyl-3-imidazoline | 90277-82-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2,5,5-tetramethyl-4-phenyl-3-imidazoline
• 英文别名: 3-Imidazoline, 2,2,5,5-tetramethyl-4-phenyl-；2,2,5,5-tetramethyl-4-phenyl-1H-imidazole
• CAS: 90277-82-0
• 化学式: C₁₃H₁₈N₂
• 分子量: 202.299
• InChiKey: HJMZJVYIMNRNSU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  24.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,2,5,5-Tetramethyl-1-oxido-4-phenylimidazole 、 5-(dichloromethyl)-2,2,4,4-tetramethyl-1,3-dioxidoimidazol-1-ium 、 sodium hydroxide 以5%的产率得到
  参考文献：
  名称：

  GRIGOREV, I. A.;SHCHUKIN, G. I.;VOLODARSKIJ, L. B., IZV. AN CCCP. CEP. XIM., 1983, N 12, 2787-2797

  摘要：

  DOI：

文献信息

• Influence of the radical center on the basic hydrolysis reaction of 4-dihalomethyl-3-imidazoline-3-oxide
  作者：I. A. Grigor'ev、G. I. Shchukin、L. B. Volodarskii

  DOI：10.1007/bf00954482

  日期：1983.12
• PHOSPHAZENE HYDROGELS WITH CHEMICAL CORSS -LINK, PREPARATION METHOD THEREOF AND USE THEREOF
  申请人：Korea Institute of Science and Technology

  公开号：EP2155806A1

  公开（公告）日：2010-02-24
• MODIFICATION OF POLYAMIDES
  申请人：Arkema, Inc.

  公开号：EP3065944A1

  公开（公告）日：2016-09-14
• [EN] PHOSPHAZENE HYDROGELS WITH CHEMICAL CORSS -LINK, PREPARATION METHOD THEREOF AND USE THEREOF<br/>[FR] HYDROGELS DE PHOSPHAZÈNE PRÉSENTANT UNE RÉTICULATION CHIMIQUE, LEUR PROCÉDÉ DE PRÉPARATION ET LEUR UTILISATION
  申请人：KOREA INST SCI & TECH

  公开号：WO2008153278A1

  公开（公告）日：2008-12-18

  [EN] A phosphazene-based polymer hydrogel with a chemical cross-linkings formed by radiating ultraviolet (UV) and/or mixing with cross-linking agent and/or enzyme, a method of preparing the same, and a hydrogel forming a chemical cross-linking by radiating ultraviolet and/or mixing with a cross-linking agent and/or an enzyme; where the hydrigel shows a sol-gel behavior and has an excellent solidity by containing the phosphazene-based polymer that is capable of cross-linking at a certain concentration, are provided.
  [FR] L'invention porte sur un hydrogel polymère à base de phosphazène présentant une réticulation chimique formée par irradiation par un rayonnement ultraviolet (UV) et/ou par mélange avec un agent de réticulation et/ou une enzyme, sur un procédé de préparation de cet hydrogel, et sur un hydrogel formant une réticulation chimique par irradiation par un rayonnement ultraviolet et/ou un mélange avec un agent de réticulation et/ou une enzyme. L'hydrogel manifeste un comportement sol-gel et possède une excellente solidité par le fait qu'il contient le polymère à base de phosphazène qui est apte à la réticulation à une certaine concentration.
• [EN] MODIFICATION OF POLYAMIDES<br/>[FR] MODIFICATION DE POLYAMIDES
  申请人：ARKEMA INC

  公开号：WO2015069455A1

  公开（公告）日：2015-05-14

  The present invention relates to an improved modified polyamide having increased molecular weight and substantially the same or marginally increased viscosity versus shear weight as the unmodified polyamide. A method for modifying polyamides to provide these improved properties also is disclosed wherein a polyamide having an initial molecular weight is contacted with at least one organic peroxide, at least one coagent and/or one free-radical trap to form an improved polyamide having an increased molecular weight and substantially the same viscosity versus shear rate. The present disclosure also relates to polyamide compositions comprising organic peroxides and articles made from the modified polyamide.