[Pd(oxalate)(bis(diphenylphosphino)ethane)]*H2O | 370591-02-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Pd(oxalate)(bis(diphenylphosphino)ethane)]*H2O
• CAS: 370591-02-9
• 化学式: C₂₈H₂₄O₄P₂Pd*H₂O
• 分子量: 610.879
• InChiKey: ABGARVQJSXPBRP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,2-双(二苯基膦)乙烷 以 二氯甲烷 、 水 、 丙酮 为溶剂， 生成 [Pd(oxalate)(bis(diphenylphosphino)ethane)]*H2O
  参考文献：
  名称：

  Oxidative degradation of the ascorbate anion in the presence of platinum and palladium. Formation and structures of platinum and palladium oxalate complexes

  摘要：

  The reactions of [Pt(NO3)(2)(dppm)] (dppm = bis(diphenylphosphino)methane) and cis -[Pt(NO3)(2)(PEt3)(2)] with sodium ascorbate are described. Complexes containing O,O-coordinated ascorbate ligands are formed initially, but on standing further oxidation and cleavage of the ligand occur to produce the corresponding oxalate complexes. The reactions were monitored by NMR spectroscopy, and reactions of [Pt(NO3)(2)(dppm)] with oxalic acid or calcium threonate also produced [pt(C2O4)(dppm)]. Reactions of [PtMe(Me2CO)(dppe)](+) or [PdMe(Me2CO)(P (boolean AND) P)](+) (P (boolean AND) P = dppe, dppp) with sodium ascorbate result in cleavage of the M-C bond and oxidation of ascorbate to again produce metal oxalate derivatives. The solid state structures of [Pt(C2O4)(dppm)]. Me2CO, [Pd(C2O4)(dppe)].H2O and [Pd-2(mu -C2O4)(dppp)(2)][BF4](2). 2Me(2)CO, determined by X-ray crystallography, are described. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00843-9