cis-[bis(diphenylphosphinomethyl)aniline]dichloroplatinum(II) | 1401420-45-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-[bis(diphenylphosphinomethyl)aniline]dichloroplatinum(II)
• CAS: 1401420-45-8
• 化学式: C₃₂H₂₉Cl₂NP₂Pt
• 分子量: 755.522
• InChiKey: AIMHVGSHNDGPEF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  8.05
• 重原子数：
  38.0
• 可旋转键数：
  5.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  N,N-bis(diphenylphosphinoylmethyl)aniline 在 苯硅烷 作用下， 以 苯 为溶剂， 反应 96.0h， 生成 cis-[bis(diphenylphosphinomethyl)aniline]dichloroplatinum(II)
  参考文献：
  名称：

  N-苄基和N-芳基双（磷-曼尼希加合物）：相关的双齿螯合物铂配合物在加氢甲酰化中的合成和催化活性

  摘要：

  微波辅助的苄基胺和芳基胺，两当量的多聚甲醛和P（O）H试剂（例如亚磷酸二烷基酯，苯基H-次膦酸乙基酯和二苯基膦氧化物）的双Kabachnik-Fields（phospha-Mannich）反应P（O）CH 2）胺衍生物的收率很高。脱氧后，双（二苯基膦氧化基）衍生物被转化为相应的环铂络合物，其催化活性在苯乙烯的加氢甲酰化中进行了测试。配合物之一的晶体结构分析表明，配合物结构与溶剂夹杂物之间有趣的相关性。

  DOI：

  10.1016/j.jorganchem.2012.07.031

文献信息

• Microwave-Assisted Synthesis of Organophosphorus Compounds
  作者：Erika Bálint、Eszter Fazekas、Judit Takács、Ádám Tajti、Amadej Juranovič、Marijan Kočevar、György Keglevich

  DOI：10.1080/10426507.2012.743544

  日期：2013.1.1

  Kabachnik-Fields reactions of a variety of amines, phospha-Michael additions to maleimide derivatives and alcoholysis of dialkyl phosphites were studied under microwave conditions.
• Bis(phosphinomethyl)phenylamines and bis(phosphinomethyl)sulfides and their reaction with d8-platinum group precursors
  作者：Marc Stickel、Caecilia Maichle-Moessmer、Lars Wesemann、Hermann A. Mayer

  DOI：10.1016/j.poly.2012.07.083

  日期：2012.10

  The potentially tridentate phosphines R2PCH2XCH2PR2 [X = NPh, R = Ph (1), Bu-t (2), Cy (3), X = S, R = Ph (4), Bu-t (5)] were treated with different Pd(II), Pt(II) as well as Rh(I) and Ir(I) complex precursors. All new palladium and platinum compounds are formed as cis bisphosphine complexes. This is also the case if the sterically demanding phosphines 2 and 3 are treated with MCl(CO)(PPh3)(2) while the comparable reaction with 1 generates trigonal bipyramidal complexes. In contrast to this the reaction of 5 with Ir(CO)(2)Cl(p-TolNH(2)) forms the macrocycle 5b. All new compounds have been characterized by H-1, C-13, P-31 NMR and IR spectroscopy. Single crystal X-ray analysis has been performed from most of the compounds as well. (C) 2012 Elsevier Ltd. All rights reserved.