antimony trichloride*γ-picoline | 38558-29-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: antimony trichloride*γ-picoline
• CAS: 38558-29-1；64645-23-4
• 化学式: C₆H₇N*Cl₃Sb
• 分子量: 321.237
• InChiKey: IGMADTFOKXXMST-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  3.08
• 重原子数：
  11.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  12.89
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  4-甲基吡啶 、 三氯化锑 以 二硫化碳 为溶剂， 以80%的产率得到antimony trichloride*γ-picoline
  参考文献：
  名称：

  Picoline as ligand with antimony trichloride and triiodide adducts

  摘要：

  Solid adducts SbX3.L-pic (X=Cl, I and L=alpha-, beta- and gamma-picolines) were synthesized and characterized by elemental analysis, H-1 and C-13 NMR, IR spectroscopy and thermal analysis. ne infrared spectroscopy and the magnetic resonance for H-1 and C-13 nuclei of these compounds suggest that the ligands coordinate through nitrogen atom. Kinetic studies were accomplished by means of thermogravimetric data, through isothermal and non-isothermal techniques. The best adjusting models for adducts thermal decomposition were R-1 for isothermal and R-1 and R-2 for the non-isothermal methods. The energy of activation values obtained by isothermal method indicate the following orders of thermal stability for adducts: i) SbCl3.alpha-pic>SbCl3.beta-pic>SbCl3.gamma-pic and ii) SbI3.beta-pic

  DOI：

  10.1023/b:jtan.0000027191.45965.f7