[Zn(glutarate)(4,4'-bipyridine)]n | 849192-60-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Zn(glutarate)(4,4'-bipyridine)]n
• 英文别名: Zn(glutarate)(4,4'-bipyridine)
• CAS: 849192-60-5；1003309-84-9
• 化学式: C₅H₆O₄*C₁₀H₈N₂*Zn
• 分子量: 351.677
• InChiKey: MSCPTBUVNBIFFI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  22.0
• 可旋转键数：
  5.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  106.04
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  在 sodium iodide 作用下， 以 水 为溶剂， 反应 12.0h， 生成 [Zn(glutarate)(4,4'-bipyridine)]n
  参考文献：
  名称：

  矩形Zn（II）金属-有机骨架中配体取代诱导的单晶向单晶转变的八面体向四面体转化及其光催化

  摘要：

  一种新的阳离子矩形锌 (II) 金属有机骨架 (MOF)，包含柔性链状桥连戊二酸 (glu) 和刚性棒状 4,4'-联吡啶 (4,4'-bipy) 配体，并带有封装的高氯酸反阴离子 {[Zn 3 (4,4'-bipy) 4 (glu) 2 ](ClO 4 ) 2 } n ( 1 ; P 1̅) 进行了研究。使用微波加热技术从高氯酸锌 (II) 盐中成功合成了配合物1。在的晶体结构1，4,4'-联吡啶配体的三核链接八面体的Zn（II）结构单元成型矩形二维薄片。glu 2–配体反反构象将结构扩展为阳离子矩形 3D MOF，其中两个晶体学相关的高氯酸盐 (ClO 4 – ) 反阴离子封装在矩形 {Zn 3 (4,4'-bipy) 4 (glu) 2 } 2+结构中作为结构的模板。X 射线衍射揭示了八面体 Zn oct MOF 1 ( P 1̅)在配体取代诱导的单晶到单晶 (SCSC) 转化后八面体到四面体

  DOI：

  10.1021/acs.cgd.1c00658

文献信息

• Anion-Controlled Synthesis of Enantiomeric Twofold Interpenetrated 3D Zinc(II) Coordination Polymer with Ligand Substitution-Induced Single-Crystal-to-Single-Crystal Transformation and Photocatalysis
  作者：Nippich Kaeosamut、Yothin Chimupala、Saranphong Yimklan

  DOI：10.1021/acs.cgd.1c00103

  日期：2021.5.5

  upon the phase formation were explored. The complex 1 was successfully synthesized from zinc(II) nitrate salt via microwave-assisted techniques as well as the conventional hydrothermal technique, whereas the employment of zinc(II) acetate or sulfate salt yielded a two-dimensional coordination polymer, [Zn(4,4′-bipy)(glu)]n, 2 (P1̅), and the use of zinc(II) chloride led to a one-dimensional (1D) zigzag

  阴离子控制的新型三维（3D）“外消旋物”的合成，该对映体是互穿的，互穿的3D锌（II）配位聚合物，其中包含桥接戊二酸酯（glu）和4,4'-联吡啶（4,4'-bipy）配体，[Zn 4（H 2 O）2（4,4'-bipy）4（glu）3 ]（NO 3）2 } n，1（P 2 1 / c），研究了配体取代诱导的单晶到单晶（SCSC）转化和光催化降解染料的方法。探索了锌（II）原料中抗衡阴离子和合成技术对相形成的影响。通过微波辅助技术和常规水热技术成功地从硝酸锌（II）盐合成了配合物1，而乙酸锌（II）或硫酸盐的使用产生了二维配位聚合物[Zn（4 ，4'-联吡啶）（谷氨酸）] ñ，2（P 1），并且使用导致的一维（1D）Z字形链锌（II），氯化[锌（4,4'-联吡啶）氯2 ] n 3（C 2 / c）。微波辅助技术说明了依赖于合成方法的形成，传统的水热技术能够形成纯的结晶相1，而声化学合成则
• New α,ω-dicarboxylate coordination polymers with 4,4′-bipyridine: Cu(bpy)(C5H6O4), Zn(bpy)(C5H6O4), Zn(bpy)(C6H8O4) and Mn(bpy)(C8H12O4)·H2O
  作者：Yue-Qing Zheng、Er-Bo Ying

  DOI：10.1016/j.poly.2004.11.025

  日期：2005.2

  Four 4,4'-bipyridine alpha,omega-dicarboxylate coordination polymers Cu(bpy)(C5H6O4) (1), Zn(bpy)(C5H6O4) (2), Zn(bpy)(C6H8O4) (3) and Mn(bpy)(C8H12O4) (.) H2O (4) have been synthesized and structurally characterized by single crystal X-ray diffraction methods (bpy = 4,4-bipyridine, (C5H6O4)(2-) = glutarate anion, (C6H8O4)(2-) = adipate anion, (C8H12O4)(2-) = suberate anion). Their crystal structures are featured by dimeric metal units, which are co-bridged by 4,4'-bipyridine ligands and dicarboxylate anions such as glutarate, adipate and suberate anions to generate 2D layers with a (4,4) topology in 1, 2 and 4 as well as to form 3D frameworks in 3. Two 3D frameworks in 3 interpenetrate with each other to form a topology identical to the well-known Nb6F15 cluster compound. Over 5-300 K, the paramagnetic behavior of 4 follows the Curie-Weiss law X-m (T - Theta) = 4.265(5) cm(3) mol(-1) with the Weiss constant Theta = -6.3(2) K. Furthermore, the thermal behavior of 3 and 4 is also discussed. (C) 2005 Elsevier Ltd. All rights reserved.
• Different aliphatic dicarboxylates affected assemble of new coordination polymers constructed from flexible–rigid mixed ligands
  作者：Xinxin Xu、Ying Ma、Enbo Wang

  DOI：10.1016/j.jssc.2007.05.033

  日期：2007.11

  In this article, seven coordination polymers: [Cd(C5H6O4)(C10H8N2)](n) (1), [Zn(C5H6O4)(C10H8N2)](n) (2), [Cd(C6H8O4)(C10H8N2)](n) (3), [Mn(C10H8N2)(H2O)(4)] (C4H4O4) center dot 4H(2)O}(n) (4), [Mn-5(C4H4O4)(4)(O)](n) (5), [Cd(C4H4O4)(C10H8N2)(H2O)](n) (6) and [Zn(C6H6O4)(C12H8N2) (H2O)](n) (7) were synthesized and characterized by single-crystallographic X-ray diffraction. Compounds 1 and 2 are two-dimensional layers connected by glutarate anions and 4,4'-bpy. Unlike compounds 1 and 2, compound 3 is a two-fold interpenetration network. Compound 4 is a one-dimensional chain-like structure, which is further extended to two-dimensional supramolecular layer structure with hydrogen bond. During the synthesis of compound 4, to our surprise, we got compound 5; compound 5 is an interesting three-dimensional network composed of pentanuclear Mn(II) building units and succinate anions. Compound 6 is also a two-dimensional supramolecular layer structure composed of one-dimensional chain-like structure with hydrogen bonds and pi-pi interactions. Compound 7 is also a one-dimensional chain-like structure, which is further connected with the same kind of interaction to generate two-dimensional supramolecular layer structure. Furthermore, compounds 1 and 2 both exhibit fluorescent property at room temperature. (C) 2007 Published by Elsevier Inc.