[Ag2(C6H4(CH2SCH2C6H4OCH2)2)2(picrate)2] | 930768-38-0

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: [Ag2(C6H4(CH2SCH2C6H4OCH2)2)2(picrate)2]
• CAS: 930768-38-0
• 化学式: C₆₀H₅₂Ag₂N₆O₁₈S₄
• 分子量: 1489.1
• InChiKey: VBTGNRYKKAKKEC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  10,13-dioxa-3,7-dithia-1,9(1,2),5(1,3)-tribenzenacyclotridecaphane 、 silver picrate 以 甲醇 、 二氯甲烷 为溶剂， 以65%的产率得到[Ag2(C6H4(CH2SCH2C6H4OCH2)2)2(picrate)2]
  参考文献：
  名称：

  Anion–ligand interaction in binuclear cyclic dimer complex of a tribenzo-S2O2 macrocycle with silver(I) picrate

  摘要：

  From the reaction of tribenzo-S2O2 macrocyclic ligand (L-1) and silver picrate (AgPic), a unique binuclear complex [Ag-2(L-1)(2)(PiC)(2)] (1) has been obtained. The species I has been characterised by single-crystal X-ray diffraction analysis providing a definitive proof of its cyclic dirner structure as well as the anion-ligand pi-pi stacking interactions between L-1 and Pic(-). The result of a comparative NMR experiment suggests that the solid structure of 1 is also retained in solution. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2006.05.032