(4-methylphenyl)sulfonyl-quinolin-8-ylazanide;nickel(2+);dihydrate | 461054-23-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: (4-methylphenyl)sulfonyl-quinolin-8-ylazanide;nickel(2+);dihydrate
• CAS: 461054-23-9
• 化学式: C₃₂H₃₀N₄NiO₆S₂
• 分子量: 689.435
• InChiKey: QALJQELQYUOFOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 8-(甲苯磺酰氨基)喹啉 、 nickel dichloride 在 NH₃ 作用下， 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 生成 (4-methylphenyl)sulfonyl-quinolin-8-ylazanide;nickel(2+);dihydrate
  参考文献：
  名称：

  Synthesis and characterization of sulfonamides containing 8-aminoquinoline and their Ni(II) complexes. Crystalline structures of the Ni complexes

  摘要：

  Reaction between 8-aminoquinoline and benzenesulfonyl, toluene-4-sulfonyl and naphthalene-2-sulfonyl chlorides in a basic medium leads to the formation of the corresponding sulfonamides. Reaction of these sulfonamides with Ni(II) salts leads to the formation of the corresponding complexes, with a NiL2 stoichiometry. Determination of the crystalline structure by X-ray diffraction shows an octahedral environment for the Ni(II) ions, sulfonamides acting as bidentate ligands and two solvent molecules completing the octahedral coordination. The spectroscopic and magnetic properties of these compounds are also discussed. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)00997-x