4'-[4-(3-hydroxypropynyl)phenyl]-2,2':6',2''-terpyridine | 345259-86-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4'-[4-(3-hydroxypropynyl)phenyl]-2,2':6',2''-terpyridine
• 英文别名: 3-[4-(2,6-dipyridin-2-ylpyridin-4-yl)phenyl]prop-2-yn-1-ol
• CAS: 345259-86-1
• 化学式: C₂₄H₁₇N₃O
• 分子量: 363.418
• InChiKey: LDKXHAKENNOPOW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  28
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  58.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 Ru(tpy)(Cl)₃ 、 4'-[4-(3-hydroxypropynyl)phenyl]-2,2':6',2''-terpyridine 以 乙二醇 为溶剂， 以28%的产率得到[ruthenium(II)(2,2':6',2''-terpyridine)(4'-[4-(3-hydroxypropynyl)phenyl]-2,2':6',2''-terpyridine)][PF6]2
  参考文献：
  名称：

  Dicobalt cluster functionalized 2,2′:6′,2″-terpyridine ligands and their ruthenium(II) complexes

  摘要：

  A series of 2.2':6'.2"-terpyridine (tpy) ligands functionalized in the 4'-position with alkyne substituents has been prepared and characterized. Treatment of these ligands with [RuCl3(tpy)] yields complexes with pendant alkyne groups which then readily react with Co-2(CO)(8) to give novel compounds containing both cluster and classical coordination motifs. The new compounds are characterized by mass spectrometric and spectroscopic methods, and the single crystal structure of [Ru(tpy)(4'-HC=CCH(2)Otpy)][PF6](2) is reported. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00631-8