1-[2-methoxy-4-methyl-5-phenyl-3-thienyl]-2-[4-methyl-2,5-bis(5''-formyl-2,2':5',2"-terthienyl)-3-thienyl]hexafluorocyclopentene | 875936-33-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 1-[2-methoxy-4-methyl-5-phenyl-3-thienyl]-2-[4-methyl-2,5-bis(5''-formyl-2,2':5',2"-terthienyl)-3-thienyl]hexafluorocyclopentene
• 英文别名: 5-[5-[5-[5-[5-[5-[5-[5-(5-Formylthiophen-2-yl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-3-[3,3,4,4,5,5-hexafluoro-2-(2-methoxy-4-methyl-5-phenylthiophen-3-yl)cyclopenten-1-yl]-4-methylthiophen-2-yl]thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]thiophene-2-carbaldehyde
• CAS: 875936-33-7
• 化学式: C₅₆H₃₂F₆O₃S₁₀
• 分子量: 1187.52
• InChiKey: WJTDPYYFUPOMSJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.8
• 重原子数：
  75
• 可旋转键数：
  14
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  299
• 氢给体数：
  0
• 氢受体数：
  19

反应信息

• 作为反应物：
  描述：

  1-[2-methoxy-4-methyl-5-phenyl-3-thienyl]-2-[4-methyl-2,5-bis(5''-formyl-2,2':5',2"-terthienyl)-3-thienyl]hexafluorocyclopentene 以 乙酸乙酯 为溶剂， 生成
  参考文献：
  名称：

  Photochromic Oligothiophenes

  摘要：

  New oligothiophenes having a photochromic switching unit were synthesized. Upon irradiation with UV and visible light the oligomers underwent photochromic reactions in solution. The chain length dependence on the photoreactivity was examined to reveal that the reactivity decreased as the chain length gets longer. These molecules can be used as new photoswitching units.

  DOI：

  10.1246/cl.2005.1580
• 作为产物：
  描述：

  3'-[3,3,4,4,5,5-Hexafluoro-2-(2-methoxy-4-methyl-5-phenyl-thiophen-3-yl)-cyclopent-1-enyl]-4'-methyl-5,5''-bis-trimethylsilanyl-[2,2';5',2'']terthiophene 在 四(三苯基膦)钯 N-溴代丁二酰亚胺(NBS) 、 sodium carbonate 作用下， 以 四氢呋喃 、 水 为溶剂， 生成 1-[2-methoxy-4-methyl-5-phenyl-3-thienyl]-2-[4-methyl-2,5-bis(5''-formyl-2,2':5',2"-terthienyl)-3-thienyl]hexafluorocyclopentene
  参考文献：
  名称：

  Photochromic Oligothiophenes

  摘要：

  New oligothiophenes having a photochromic switching unit were synthesized. Upon irradiation with UV and visible light the oligomers underwent photochromic reactions in solution. The chain length dependence on the photoreactivity was examined to reveal that the reactivity decreased as the chain length gets longer. These molecules can be used as new photoswitching units.

  DOI：

  10.1246/cl.2005.1580