cadmium N,N'-bis(2-tosylaminobenzal)-3,6-dioxa-1,8-octanediaminate*CHCl3 | 1639136-69-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cadmium N,N'-bis(2-tosylaminobenzal)-3,6-dioxa-1,8-octanediaminate*CHCl3
• CAS: 1639136-69-8
• 化学式: CHCl₃*C₃₄H₃₆CdN₄O₆S₂
• 分子量: 892.603
• InChiKey: GFNDFFNXGAZMFS-XXKWIVBCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-(2-甲酰基苯基)-4-甲基苯磺酰胺 在 高氯酸四乙基铵 作用下， 以 甲苯 、 乙腈 为溶剂， 反应 3.0h， 生成 cadmium N,N'-bis(2-tosylaminobenzal)-3,6-dioxa-1,8-octanediaminate*CHCl3
  参考文献：
  名称：

  Synthesis, crystal structure, and electroluminescent properties of zinc and cadmium tetradentate azomethine complexes

  摘要：

  Chemical and electrochemical syntheses of zinc(II) and cadmium(II) complexes based on tetradentate Schiff bases (H2L1 and H2L2) resulting from condensation of 2-tosylaminobenzaldehyde with 3,6-dioxa-1,8-octanediamine or 4,9-dioxa-1,12-dodecanediamine were performed. The structure, composition, and properties of the complexes were studied by elemental analysis, IR, H-1 NMR, and UV spectroscopy, X-ray absorption spectroscopy, and X-ray diffraction. The zinc(II) and cadmium(II) complexes luminesce in a DMF solution in the blue spectral region (lambda(PL) = 425-433 nm), the photoluminescence quantum yield phi being 0.25-0.30. Multilayer zinc(II)- and cadmium(II)-based electroluminescent structures with green-blue emission of the exciplex nature were fabricated.

  DOI：

  10.1134/s0036023614070031