(p-formylphenyl)trimethylammonium bromide | 72621-22-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (p-formylphenyl)trimethylammonium bromide
• 英文别名: p-Formylphenyltrimethylammonium；4-formyl-N,N,N-trimethyl-benzenaminium bromide；(4-formylbenzyl)trimethylammonium bromide；(4-Formylphenyl)-trimethylazanium;bromide
• CAS: 72621-22-8
• 化学式: Br*C₁₀H₁₄NO
• 分子量: 244.131
• InChiKey: LIOAJJBZQBKSPV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.3
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  十二烷基伯胺 、 (p-formylphenyl)trimethylammonium bromide 生成 {4-[(E)-Dodecyliminomethyl]-phenyl}-trimethyl-ammonium; bromide
  参考文献：
  名称：

  Formation of stable bilayer assemblies in water from single-chain amphiphiles. Relationship between the amphiphile structure and the aggregate morphology

  摘要：

  DOI：

  10.1021/ja00408a021
• 作为产物：
  描述：

  溴甲烷 、 对二甲氨基苯甲醛 以 苯 为溶剂， 反应 70.0h， 生成 (p-formylphenyl)trimethylammonium bromide
  参考文献：
  名称：

  Formation of the stable bilayer assemblies in dilute aqueous solution from ammonium amphiphiles with the diphenylazomethine segment

  摘要：

  DOI：

  10.1021/ja00522a019

文献信息

• Responsive Vesicles from Dynamic Covalent Surfactants
  作者：Christophe B. Minkenberg、Feng Li、Patrick van Rijn、Louw Florusse、Job Boekhoven、Marc C. A. Stuart、Ger J. M. Koper、Rienk Eelkema、Jan H. van Esch

  DOI：10.1002/anie.201007401

  日期：2011.4.4

  Breaking bilayers: Incorporation of dynamic covalent bonds in vesicle‐forming surfactants leads to the formation of responsive vesicles, which can be switched back and forth between the bilayer state and the isotropic solution using either dilution or a change in the pH value as external stimuli.

  双层破裂：在形成囊泡的表面活性剂中掺入动态共价键会导致形成反应性囊泡，可以使用稀释液或通过改变pH值作为外部刺激剂在双层状态和各向同性溶液之间来回切换。
• Reaction of the Azomethine Moiety Buried in Bilayer Membranes
  作者：Yoshio Okahata、Reiko Ando、Toyoki Kunitake

  DOI：10.1246/bcsj.56.802

  日期：1983.3

  water and amines of the azomethine moiety that is part of single-chain ammonium amphiphiles was examined. These amphiphiles form stable bilayer aggregates when they have the alkyl tail of C7 or C12. The reaction with water of the bilayer-forming amphiphiles ceases at the hydration stage and are 10–2000 times slower than those of the amphiphiles which do not form bilayers and undergo hydrolytic cleavage

  检查了作为单链铵两亲物的一部分的偶氮甲碱部分与水和胺的反应。当这些两亲物具有 C7 或 C12 的烷基尾时，它们会形成稳定的双层聚集体。形成双层的两亲物与水的反应在水合阶段停止，比不形成双层并进行水解裂解的两亲物慢 10-2000 倍。双层中偶氮甲碱部分的反应性随着与膜表面距离的增加而降低。双层形成两亲物的阿伦尼乌斯图显示在对应于相应双层相变 (Tc) 的温度下的不连续性。表观活化能在低于 Tc 的温度下大于在高于 Tc 的温度下。这表明在流体双层中促进了水渗透。与胺的反应受它们在双层基质中的溶解度的影响，当偶氮...
• Amphiphilic derivatives for the production of vesicles, micelles and complexants, and precursors thereof
  申请人：Grinberg Sarina

  公开号：US20050118248A1

  公开（公告）日：2005-06-02

  Amphiphilic derivatives composed of at least one fatty acid chain are derived from natural vegetable oils such as vernonia oil, lesquerella oil and castor oil, in which the several reactive groups such as epoxy, hydroxy and double bonds can be modified to polar and ionic groups. The head group of the amphiphilic derivative may be in the main fatty acid chain or in a side chain. The amphiphiles are useful for the formation of vesicles and micelles and for use as complexants and surfactants.

  由至少一个脂肪酸链组成的亲水亲油衍生物是从天然植物油中派生出来的，例如vernonia油、lesquerella油和蓖麻油，在这些油中，几种反应性基团如环氧、羟基和双键可以改性为极性和离子基团。这种亲水亲油衍生物的头基团可以在主要的脂肪酸链或侧链中。这些亲水亲油分子可用于形成囊泡和胶束，并可用作络合剂和表面活性剂。
• Preparation of quarternary ammonium salt-tagged ferrocenylphosphine-imine ligands and their application to palladium-catalyzed asymmetric allylic substitution
  作者：Hao Yuan、Zhiming Zhou、Jiangliang Xiao、Lixuan Liang、Li Dai

  DOI：10.1016/j.tetasy.2010.05.047

  日期：2010.8

  A series of novel quarternary ammonium salt-modified chiral ferrocenylphosphine-imine ligands have been synthesized and the molecular structure of BIT5 has been determined by single-crystal X-ray diffraction. The applicability of these ligands in asymmetric C*-C and C*-N bond formation was demonstrated. High enantioselectivity was obtained in the Pd-catalyzed asymmetric substitution of 1,3-diphenyl-2-propenyl acetate, with dimethyl malonate (up to 94.6% ee) and benzylamine (up to 92.6% ee). (C) 2010 Published by Elsevier Ltd.
• Formation of stable monolayer membranes and related structures in dilute aqueous solution from two-headed ammonium amphiphiles
  作者：Yoshio Okahata、Toyoki Kunitake

  DOI：10.1021/ja00512a020

  日期：1979.8