bis(triphenylphosphane)iminium perchlorate | 65300-04-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(triphenylphosphane)iminium perchlorate
• 英文别名: bis-triphenylphosphiniminium perchlorate；Triphenyl-triphenylphosphoranylidenamino-phosphonium-perchlorat
• CAS: 65300-04-1
• 化学式: C₃₆H₃₀NP₂*ClO₄
• 分子量: 638.039
• InChiKey: CUDQBEYNZVDYBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.72
• 重原子数：
  44.0
• 可旋转键数：
  6.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  103.18
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  iodophthalocyaninatoiron(III) 、 bis(triphenylphosphane)iminium perchlorate 在 KOH 作用下， 以 甲醇 、 丙酮 为溶剂， 生成 bis(triphenylphosphineiminium) bis(methoxo)phthalocyaninato(2-)ferrate(III)
  参考文献：
  名称：

  Potz, Roland; Hueckstaedt,Heiner; Homborg, Heiner, Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：
• 作为产物：
  描述：

  [bis(trisphenylphosphine)iminium]Ag(CN)2 、 silver perchlorate 以 丙酮 为溶剂， 反应 1.5h， 以94%的产率得到bis(triphenylphosphane)iminium perchlorate
  参考文献：
  名称：

  Insights into the strong in-vitro anticancer effects for bis(triphenylphosphane)iminium compounds having perchlorate, tetrafluoridoborate and bis(chlorido)argentate anions

  摘要：

  Three new compounds containing the bis(triphenylphosphane)iminium cation (PPN+) with ClO4-, BF4- and [AgCl2](-) as counter anions have been synthesized and structurally characterized. The two derivatives with ClO4- and BF4- were found to be isostructural by single crystal X-ray diffraction. Interestingly, the three compounds show extremely potent antiproliferative effects against the human cancer cell line SKOV3. To gain insights into the possible mechanisms of biological action, several intracellular targets have been considered. Thus, DNA binding has been evaluated, as well as the effects of the compounds on the mitochondria] function. Furthermore, the compounds have been tested as possible inhibitors of the seleno-enzyme thioredoxin reductase. (C) 2015 The Authors. Published by Elsevier Inc. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

  DOI：

  10.1016/j.jinorgbio.2015.08.030

文献信息

• Preparation of monomeric neutral or anionic tris(polyfluorophenyl)thallium(<scp>III</scp>) and of anionic heteronuclear tris(polyfluorophenyl)thallium–metal carbonyl complexes
  作者：Rafael Usón、Antonio Laguna、J. Antonio Abad、Ernesto de Jesús

  DOI：10.1039/dt9830001127

  日期：——

  The complex [TlR3(diox)](diox = 1,4-dioxan) has been prepared by the reaction of TlCl3 with LiR (R = 2,4,6-C6F3H2), or of [NBu4][TlR4] with HBF4(R = C6F5) and subsequent addition of dioxan. The displacement of dioxan by (a) neutral ligands leads to [TlR3L](L = OPPh3, pyridine, PPh3, or Ph2PCH2PPh2); (b) anionic ligands affords Q[TlR3X]Q =[NBu4]+ or [N(PPh3)2]+; X = Cl–, CN–, NO3–, or CF3CO2–}; and

  通过TlCl 3与LiR（R = 2,4,6-C 6 F 3 H 2）或[NBu]的反应制备了配合物[TlR 3（diox）]（diox = 1,4-二恶烷）4 ] [TlR 4 ]和HBF 4（R = C 6 F 5），然后加入二恶烷。（a）中性配体取代二恶烷导致[TlR 3 L]（L = OPPh 3，吡啶，PPh 3或Ph 2 PCH 2 PPh 2）；（b）阴离子配体提供Q [TlR 3 X] Q = [NBu4 ] +或[N（PPh 3） 2 ] +；X =氯-，CN -，NO 3 -，或CF 3 CO 2 - }; （ c）羰基金属盐得到Q [TlR 3 M *] M * = [Mo（cp）（CO） 3 ] –（cp = η–C 5 H 5），[W（cp）（CO） 3 ] –，[Co（CO） 4 ] –或[Mn（CO） 5 ] – }。
• Mixed Valence Pt(II),Pt(IV),Pt(II) Complexes from a Diplatinum(III) Synthon and Sulfur-Based Anions
  作者：Consuelo Fortuño、Antonio Martín、Piero Mastrorilli、Stefano Todisco、Mario Latronico

  DOI：10.1021/acs.organomet.9b00096

  日期：2019.5.13

  to the central platinum atom of the trinuclear Pt(III)2,Pt(II) complex [(C6F5)2PtIII(μ-PPh2)2PtIII(μ-PPh2)2PtII(C6F5)2](Pt–Pt), 1, gives rise to three different types of complexes: (i) the Pt(II),Pt(II),Pt(II) complex [NnBu4][(C6F5)2PtII(μ-PPh2)2PtIIκ2-S,P-μ-(PhS)PPh2}(μ-PPh2)PtII(C6F5)2], 2a; (ii) the Pt(II),Pt(IV),Pt(II) mixed valence complexes [NnBu4][(C6F5)2PtII(μ-PPh2)2PtIV(κ2-S,S′-EtOCS2)(μ-PPh2)2PtII(C6F5)2]

  S基阴离子，噻吩氧化物（PhS –，a），黄原酸乙酯（EtOCS 2 –，b），2-巯基吡啶二酸酯（pyS –，c）和2-巯基嘧啶酸酯（pymS –，d）的配位三核的Pt（III）的中央铂原子2，铂（II）配合物[（C 6 ˚F 5）2的Pt III（μ-PPH 2）2的Pt III（μ-PPH 2）2的Pt II（C 6 ˚F 5）2 ]（Pt–Pt），1，产生三种不同类型的络合物：（i）Pt（II），Pt（II），Pt（II）络合物[N n Bu 4 ] [（C 6 F 5）2的Pt II（μ-PPH 2）2的Pt II κ 2 -小号，P -μ-（PHS）PPH 2 }（μ-PPH 2）的Pt II（C 6 ˚F 5）2 ]，2A ; （ii）Pt（II），Pt（IV），Pt（II）混合价配合物[N n Bu 4 ] [（C 6˚F 5）2的Pt II（μ-PPH 2）2的Pt IV（κ
• Vicente, Jose; Chicote, Maria-Teresa; Gonzalez-Herrero, Pablo, Inorganic Chemistry, 1997, vol. 36, # 25, p. 5735 - 5739
  作者：Vicente, Jose、Chicote, Maria-Teresa、Gonzalez-Herrero, Pablo、Jones, Peter G.

  DOI：——

  日期：——
• Sartori, C.; Preetz, W., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Sartori, C.、Preetz, W.

  DOI：——

  日期：——
• [Au(C6F5)3(PPh2H)]: A Precursor for the Synthesis of Gold(III) Phosphide Complexes
  作者：M. Carmen Blanco、Eduardo J. Fernández、Peter G. Jones、Antonio Laguna、José M. López-de-Luzuriaga、M. Elena Olmos

  DOI：10.1002/(sici)1521-3773(19981116)37:21<3042::aid-anie3042>3.0.co;2-c

  日期：1998.11.16

  The covalent radius of AuI is about 0.07 Å smaller than that of AgI . This was determined from the crystal structures of the isostructural complexes [N(PPh3 )][Au(C6 F5 )3 (μ-PPh2 )}2 M] (M=Au (structure shown in the picture), Ag). These mixed AuIII -M phosphides were synthesized from [Au(C6 F5 )3 (PPh2 H)], the first gold complex to contain a secondary phosphane.