[meso-tris(4-methoxyphenyl)corrolato]silver(III) | 503269-85-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: [meso-tris(4-methoxyphenyl)corrolato]silver(III)
• 英文别名: T(4-MeO)PCAg(III)
• CAS: 503269-85-0
• 化学式: C₄₀H₂₉AgN₄O₃
• 分子量: 721.563
• InChiKey: XLIUKPRNCCJZDG-BZLUFMOKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  silver(I) acetate 、 5,10,15-tris(p-methoxyphenyl)corrole 以 吡啶 为溶剂， 以80%的产率得到[meso-tris(4-methoxyphenyl)corrolato]silver(III)
  参考文献：
  名称：

  Synthesis and Structure of [meso-Triarylcorrolato]silver(III)

  摘要：

  An efficient meso-triarylcorrole synthesis is detailed, and the formation and spectroscopic properties of their diamagnetic square-planar d(8) Ag(III) complexes are described. The spectroscopic properties of the [corrolato]Ag(Ill) complexes are contrasted with those of the corresponding [porphyrinato]Ag(II) complexes. The oxidation state of the central metal in the corrolato complexes was inferred from their diamagnetic NMR spectra, from X-ray photoelectron spectroscopy measurements, and by single-crystal X-ray diffractometry of the [meso-tetra-p-tolylcorrolato]-silver(III) complex TTCAgIII, as its toluene solvate (crystal data for C40H29N4Ag.C7H8: monoclinic space group C2(1)c with a = 21.4679(19) Angstrom, b = 20.7606(19) Angstrom, c = 16.0122(11) Angstrom, beta = 93.700(4)degrees, V = 7121.5(10) Angstrom(3), Z = 8, R = 0.0453, and R-w = 0.1131). The conformation of the corrolato ligand in the complex is slightly saddled. The Ag(Ill) complexes are without precedent in the coordination chemistry of corroles. The Ag(III) complexes underline the ability of meso-triarylcorroles to stabilize higher oxidation states as compared to the corresponding meso-tetraarylporphyrinato complexes.

  DOI：

  10.1021/ic0261171