manganese(III)(5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin) | 88992-32-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: manganese(III)(5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin)
• 英文别名: [Mn(meso-tetrakis(4-sulfonatophenyl)porphyrinate)]3-；{Mn(III)(tetrakis(4-sulfonatophenyl)porphyrin)}(3-)；manganese(III) 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (3-)；manganese(III) meso-tetrakis(4-sulfonato-phenyl) porphyrinate(3-)；5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin manganese(III) complex；[Mn(5,10,15,20-tetrakis(4-sulfonatophenyl)-21H,23H-porphine)](3-)；(meso-tetrakis-(4-sulfonatophenyl)porphyrinato)manganese(III)；manganese(III) tetrakis(p-sulfonatophenyl)porphyrin；Mn(III)TPPS
• CAS: 88992-32-9
• 化学式: C₄₄H₂₄MnN₄O₁₂S₄
• 分子量: 983.896
• InChiKey: YNJWINLPKXDZEJ-DAJBKUBHSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  manganese(III)(5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin) 在 异丙醇 作用下， 以 水 、 异丙醇 为溶剂， 生成 manganese(II) tetrakis(4-sulfonatophenyl)porphyrin tetraanion
  参考文献：
  名称：

  烷基和氟烷基与镍，铁和锰卟啉的反应

  摘要：

  The reactions of alkyl (CH3, C2H5, n-C4H9, CH2CO2-, CH(CO2-)2, CH2CN) and fluoroalkyl (CF3, CF2Cl) radicals with nickel, iron, and manganese porphyrins (P) have been studied by radiolytic techniques in various solvents. All the radicals (R) react with FeIIP to form R-FeIIIP with a stable Fe-C bond. These products are oxidized by O2 to FeIIIP. Although NiIP and NiIIP also react rapidly with the radicals to form Ni-C bonds, only the reactions of fluoroalkyl radicals with NiIP yield stable products. Reactions of alkyl radicals with NiIP result in unstable R-NiIIP prodUCts (t1/2 several seconds) that eventually yield NiIIP. Reactions of alkyl radicals with NiIIP are reversible, and the short-lived R-NiIIIP products (t1/2 approximately milliseconds) disappear through radical reactions, with recovery of NiIIP. Alkyl radicals react rapidly with MnIIP, probably via addition to the metal, but the adduct gives MnIIIP immediately. .CF3 radicals also react with MnIIIP by addition to C=C bonds.

  DOI：

  10.1021/j100202a092
• 作为产物：
  描述：

  manganese(II) tetrakis(4-sulfonatophenyl)porphyrin tetraanion 在 methane