diiodotris(trimethylphosphine)nickel | 53188-34-4

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: diiodotris(trimethylphosphine)nickel
• 英文别名: [nickel(II)(trimethylphosphine)3(diiodide)]
• CAS: 53188-34-4；20663-85-8；38199-77-8
• 化学式: C₉H₂₇I₂NiP₃
• 分子量: 540.734
• InChiKey: RSZUBILSQZAGGF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  5.84
• 重原子数：
  15.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  diiodotris(trimethylphosphine)nickel 以 正戊烷 为溶剂， 生成
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: Org.Verb.1, 1.1.1.1.1, page 10 - 26

  摘要：

  DOI：
• 作为产物：
  描述：

  以 乙醚 为溶剂， 生成 diiodotris(trimethylphosphine)nickel
  参考文献：
  名称：

  Klein, Hans-Friedrich; Bickelhaupt, Alfred; Lemke, Mathias, Organometallics, 1997, vol. 16, p. 668 - 676

  摘要：

  DOI：

文献信息

• Synthèse et configuration d'un complexe pentacoordiné dérivé du nickel carbonyle: diiodocarbonyle bis(triméthylphosphine)nickel
  作者：Marek Pańkowski、Michaël Bigorgne

  DOI：10.1016/s0022-328x(00)89816-2

  日期：1972.2

  Preparation of compound NiI2(CO)[P(CH3)3]2 from Ni(CO)2[P(CH3)3]2 and iodine or NiI2[P(CH3)3]3 and carbon monoxide is presented. These are the first syntheses of dihalogen derivatives of nickel carbonyl. The diiodocarbonylbis(trimethylphosphine) nickel very likely has a trigonal bipyramidal structure with the two axial positions occupied by trimethylphosphine ligands.

  由Ni（CO）2 [P（CH 3）3 ] 2和碘或NiI 2 [P（CH 3）3 ] 3和一氧化碳制备化合物NiI 2（CO）[P（CH 3）3 ] 2。提出了。这些是羰基镍的二卤代衍生物的首次合成。二碘羰基双（三甲基膦）镍很可能具有三角双锥体结构，其两个轴向位置被三甲基膦配体占据。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: Org.Verb.1, 1.1.1.2.1.1, page 67 - 79
  作者：

  DOI：——

  日期：——
• Nickel–heterocumulene complexes stabilized by trimethylphosphine: Synthesis, characterization and catalytic application in organozinc coupling with CS2
  作者：Ning Huang、Xiaoyan Li、Wengang Xu、Hongjian Sun

  DOI：10.1016/j.ica.2012.09.002

  日期：2013.1

  The reactivity of Ni(PMe3)(4) with CO2, CS2 and SCNPh was studied. Although CO2 is structurally homologous compound with CS2 and SCNPh, its reactivity with Ni(PMe3)(4) shows a different result with those of CS2 and SCNPh. Reactions of Ni(PMe3)(4) with carbon disulfide and phenyl isothiocyanate in THF give the tetrahedral coordinate complexes (Me3P)(3)Ni(eta(2)-CS2) (1) and (Me3P)(3)Ni(eta(2)-SCNPh) (3), characterized by standard spectroscopic methods and X-ray diffraction. Nickel(0) complexes 1 and 3 are stabilized by the strong donor ligand PMe3. In the case of CO2, attempts to isolate the expected nickel(0) complex (Me3P)(3)Ni(eta(2)-CO2) (4) proved to be unsuccessful. To further extend the utility of our nickel catalysts, the catalytic coupling of organozinc bearing different functionalities with CS2 was explored. With 10 mol% of 1 as the catalyst, MeZnMe, EtZnEt and PhZnBr coupled with CS2 to form the corresponding methyl dithiocarboxylate following esterfication of the initial products. (C) 2012 Elsevier B.V. All rights reserved.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: Org.Verb.1, 1.1.5.1.6, page 121 - 122
  作者：

  DOI：——

  日期：——
• Klein, H. F.; Karsch, H. H., Chemische Berichte, 1972, vol. 105, p. 2628 - 2636
  作者：Klein, H. F.、Karsch, H. H.

  DOI：——

  日期：——