[Ag(3-aminobenzonitrile)4](3,5-dinitrobenzoate)*H2O | 1293390-90-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ag(3-aminobenzonitrile)4](3,5-dinitrobenzoate)*H2O
• 英文别名: [Ag(m-abn)4](dnca)*H2O
• CAS: 1293390-90-5
• 化学式: C₇H₃N₂O₆*C₂₈H₂₄AgN₈*H₂O
• 分子量: 809.546
• InChiKey: QUHPRZAMAFTGEN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3,5-二硝基苯甲酸 、 水 、 间氨基苯甲腈 、 silver(l) oxide 在 NH₃ 作用下， 以 甲醇 、 乙醇 、 水 为溶剂， 以68%的产率得到[Ag(3-aminobenzonitrile)4](3,5-dinitrobenzoate)*H2O
  参考文献：
  名称：

  Aminobenzonitrile isomers-mediated self-assembly of mixed-ligand silver(I) coordination architectures: Synthesis, structural characterization and properties

  摘要：

  Three mixed-ligand coordination compounds (CCs) of the formula {[Ag(p-abn)(dnca)]center dot H2O}(n) (1), {[Ag(o-abn)(dnca)]-H2O}(n) (2), and {[Ag(m-abn)(4))]center dot(dnca)center dot H2O} (3) (where p-abn = 4-aminobenzonitrile, o-abn = 2-aminobenzonitrile, m-abn = 3-aminobenzonitrile, Hdnca = 3,5-dinitrobenzoic acid) were synthesized by reactions of Ag2O and aminobenzonitrile ligands with Hdnca under the ammoniacal condition. All CCs have been structurally characterized by element analysis, IR and X-ray single-crystal diffraction. The aminobenzonitrile acts as bidentate ligand in both 1 and 2, and as monodentate ligand in 3. As the change of the relative position of amino and cyano groups of aminobenzonitrile ligands, the dimensionality of 1-3 decreases from 2D to 0D mainly due to the steric effect of the substituted groups, which indicates that aminobenzonitrile isomers play important roles in the formation of the diverse coordination architectures. The three CCs exhibit photoluminescent emissions in the solid state at room temperature. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2011.01.035