[((2-((E)-[(2-aminopropyl)imino]methyl)phenolate)Cu)2Ni(CN)4] | 1353548-10-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [((2-((E)-[(2-aminopropyl)imino]methyl)phenolate)Cu)2Ni(CN)4]
• CAS: 1353548-10-3
• 化学式: C₂₄H₂₆Cu₂N₈NiO₂
• 分子量: 644.305
• InChiKey: RKUFMJRRLMXFOL-XKIMWRHNSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水杨醛 在 triethylamine 作用下， 以 甲醇 、 水 为溶剂， 生成 [((2-((E)-[(2-aminopropyl)imino]methyl)phenolate)Cu)2Ni(CN)4]
  参考文献：
  名称：

  Experimental Evidence and DFT Studies of Next-Nearest-Neighbor Magnetic Interactions through Diamagnetic 3d and 4d Ions

  摘要：

  The copper template effect allows the preparation of tridentate ligands that chelate copper ions, leaving unoccupied the fourth basal coordination position and at least one axial position of the copper coordination polyhedron. Two such cationic complexes, [LCu](+) and [(LCu)-Cu-1](+) = (L- = 2-{(E)-[(2-aminoethyl)imino]methyl}phenoxo) and L-1 = 2-{(E)-[(2-aminopropyl)imino]methyl}phenoxo), react with diamagnetic polycyanometalate tectons such as Ni(CN)(4)(2-) or Ag(CN)(2)(-) to yield different neutral 1D complexes. In {[(LCu)(2)Ni(CN)(4)]}(n) ( 1) the four cyano nitrogen atoms are involved in coordination with copper ions in such a manner that each copper atom is pentacoordinated and linked to two cyano functions that occupy axial and equatorial coordination positions. Two (LCu+)-Cu-1 cationic entities are linked, through their equatorial plane, to two trans cyano groups of the Ni(CN)(4)(2-) tecton in complex [((LCu)-Cu-1)(2)Ni(CN)(4)] (2), the two uncoordinated cyano groups being involved in hydrogen bonds. 2 is a racemate, a S stereoisomer being associated with a R one in each [((LCu)-Cu-1)(2)Ni(CN)(4)] unit. Zigzag Cu-Ag chains are present in [(LCu)Ag(CN)(2)] (3), where the copper centers are pentacoordinated and connected to the cyano groups in an alternate axial-equatorial coordination scheme. A bidimensional structure is developed by interchain argentophilic interactions. In complex 4, {(L1CuMeOH)((LCu)-Cu-1)[Ag(CN)(2)](2)}, two (LCu)-Cu-1 units are connected by a NC-Ag-CN bridge in an equatorial position. These resulting units exhibit argentophilic interactions with [Ag(CN2)](-) entities that are monocoordinated in the equatorial position to the next unit, ultimately leading to a chain. Weak Cu-Cu magnetic interactions are detected in the four compounds, antiferromagnetic in the case of equatorial-equatorial copper interactions, ferromagnetic for orthogonal interacting copper orbitals (axial-equatorial interactions), while axial-axial bridges are characterized by an absence of interaction. The presence of weak ferromagnetic interactions through large NC-Ni-CN or NC-Ag-CN bridges (Cu center dot center dot center dot Cu distances larger than 10 angstrom) furnishes experimental evidence for the existence of next-nearest-neighbor interactions through diamagnetic centers. DFT calculations do confirm the existence of these magnetic transmission pathways through the diamagnetic metal bridge.

  DOI：

  10.1021/ic202157q