[4-[(3aS,4R,7S,7aR)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenyl] 4-[2-(5-chloro-2-methylthiophen-3-yl)-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-methylthiophene-2-carboxylate | 391895-10-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: [4-[(3aS,4R,7S,7aR)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenyl] 4-[2-(5-chloro-2-methylthiophen-3-yl)-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-methylthiophene-2-carboxylate
• CAS: 391895-10-6
• 化学式: C₃₀H₁₈ClF₆NO₅S₂
• 分子量: 686.052
• InChiKey: BBJNXRVAVIVJTN-VVIORFSUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  45
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  129
• 氢给体数：
  0
• 氢受体数：
  13

反应信息

• 作为反应物：
  描述：

  [4-[(3aS,4R,7S,7aR)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenyl] 4-[2-(5-chloro-2-methylthiophen-3-yl)-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-methylthiophene-2-carboxylate 以 四氢呋喃 为溶剂， 生成 8-Chloro-4,4,5,5,6,6-hexafluoro-9a,9b-dimethyl-5,6,9a,9b-tetrahydro-4H-1,9-dithia-trindene-2-carboxylic acid 4-((1R,2S,6R,7S)-3,5-dioxo-10-oxa-4-aza-tricyclo[5.2.1.0^2,6]dec-8-en-4-yl)-phenyl ester
  参考文献：
  名称：

  Novel Photochromic Homopolymers Based on 1,2-Bis(3-thienyl)cyclopentenes

  摘要：

  Incorporation of photochromic molecules into polymer matrices is necessary for materials applications such as optical information processing. Several novel homopolymers were prepared from 1,2-bis(3-thienyl)cyclopentene derivatives using ring-opening metathesis polymerization techniques. Analysis by UV-vis absorption spectroscopy revealed that, in solution, they retained the appealing photochromic behavior exhibited by their respective monomers. The polymers were cast as thin films and spin-coated onto quartz substrates where the solid-state photochromic properties of the polymers were similar to those in solution.

  DOI：

  10.1021/ma0211939
• 作为产物：
  描述：

  8-Chloro-4,4,5,5,6,6-hexafluoro-9a,9b-dimethyl-5,6,9a,9b-tetrahydro-4H-1,9-dithia-trindene-2-carboxylic acid 4-((1R,2S,6R,7S)-3,5-dioxo-10-oxa-4-aza-tricyclo[5.2.1.0^2,6]dec-8-en-4-yl)-phenyl ester 以 四氢呋喃 为溶剂， 生成 [4-[(3aS,4R,7S,7aR)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenyl] 4-[2-(5-chloro-2-methylthiophen-3-yl)-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-methylthiophene-2-carboxylate
  参考文献：
  名称：

  Novel Photochromic Homopolymers Based on 1,2-Bis(3-thienyl)cyclopentenes

  摘要：

  Incorporation of photochromic molecules into polymer matrices is necessary for materials applications such as optical information processing. Several novel homopolymers were prepared from 1,2-bis(3-thienyl)cyclopentene derivatives using ring-opening metathesis polymerization techniques. Analysis by UV-vis absorption spectroscopy revealed that, in solution, they retained the appealing photochromic behavior exhibited by their respective monomers. The polymers were cast as thin films and spin-coated onto quartz substrates where the solid-state photochromic properties of the polymers were similar to those in solution.

  DOI：

  10.1021/ma0211939

文献信息

• Novel Photochromic Homopolymers Based on 1,2-Bis(3-thienyl)cyclopentenes
  作者：Andrew J. Myles、Neil R. Branda

  DOI：10.1021/ma0211939

  日期：2003.1.1

  Incorporation of photochromic molecules into polymer matrices is necessary for materials applications such as optical information processing. Several novel homopolymers were prepared from 1,2-bis(3-thienyl)cyclopentene derivatives using ring-opening metathesis polymerization techniques. Analysis by UV-vis absorption spectroscopy revealed that, in solution, they retained the appealing photochromic behavior exhibited by their respective monomers. The polymers were cast as thin films and spin-coated onto quartz substrates where the solid-state photochromic properties of the polymers were similar to those in solution.