(S)-2,2'-bis(diphenylphosphino)-6,6'-diphenyl-1,1'-binaphthyl

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (S)-2,2'-bis(diphenylphosphino)-6,6'-diphenyl-1,1'-binaphthyl
• 英文别名: [1-(2-Diphenylphosphanyl-6-phenylnaphthalen-1-yl)-6-phenylnaphthalen-2-yl]-diphenylphosphane
• 化学式: C₅₆H₄₀P₂
• 分子量: 774.881
• InChiKey: OXRYXLRJALVNIC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.7
• 重原子数：
  58
• 可旋转键数：
  9
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  diphenylphosphineborane 、 (S)-6,6'-diphenyl-[1,1'-binaphthalene]-2,2'-diyl bis(trifluoromethanesulfonate) 在 1,2-双(二苯基膦)乙烷氯化镍 三乙烯二胺 作用下， 以 DMF (N,N-dimethyl-formamide) 为溶剂， 反应 90.5h， 以53.4%的产率得到(S)-2,2'-bis(diphenylphosphino)-6,6'-diphenyl-1,1'-binaphthyl
  参考文献：
  名称：

  PROCESS FOR PREPARATION OF DIPHOSPHINE COMPOUNDS AND INTERMEDIATES FOR THE PROCESS

  摘要：

  公开号：

  EP1452537B1

文献信息

• Process for preparation of diphosphine compounds and intermediates for the process
  申请人：Goto Mitsutaka

  公开号：US20050027124A1

  公开（公告）日：2005-02-03

  A production method of a compound represented by the formula wherein R 1a , R 1b , R 1c , R 1d , R 1e , R 1f , R 2a , R 2b , R 2c , R 2d , R 2e an R 2f are the same or different and each is a hydrogen atom and the like, and R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and R 10 are the same or different and each is a hydrogen atom and the like, or a salt thereof, which comprises reacting a compound represented by the formula wherein X is a leaving group and other symbols are as defined above, or a salt thereof, with a phosphine-borane complex represented by the formula wherein the symbols are as defined above, or a salt thereof, in a solvent in the presence of an amine and a nickel catalyst, is provided.

  提供一种化合物的生产方法，该化合物的化学式为其中R1a，R1b，R1c，R1d，R1e，R1f，R2a，R2b，R2c，R2d，R2e和R2f相同或不同，每个都是氢原子等，R3，R4，R5，R6，R7，R8，R9和R10相同或不同，每个都是氢原子等，或其盐，包括在存在胺和镍催化剂的溶剂中，将化学式为其中X是离去基团，其他符号如上所定义的化合物或其盐与化学式为其中符号如上所定义的膦硼烷复合物或其盐反应。
• Process for Preparation of Diphosphine Compounds and Intermediates for the Process
  申请人：Goto Mitsutaka

  公开号：US20070161805A1

  公开（公告）日：2007-07-12

  A production method of a compound represented by the formula wherein R 1a , R 1b , R 1c , R 1d , R 1e , R 1f , R 2a , R 2b , R 2c , R 2d , R 2e and R 2f are the same or different and each is a hydrogen atom and the like, and R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and R 10 are the same or different and each is a hydrogen atom and the like, or a salt thereof, which comprises reacting a compound represented by the formula wherein X is a leaving group and other symbols are as defined above, or a salt thereof, with a phosphine-borane complex represented by the formula wherein the symbols are as defined above, or a salt thereof, in a solvent in the presence of an amine and a nickel catalyst, is provided.

  提供一种化合物的生产方法，该化合物的化学式表示为： 其中，R1a、R1b、R1c、R1d、R1e、R1f、R2a、R2b、R2c、R2d、R2e和R2f相同或不同，每个都是氢原子等，R3、R4、R5、R6、R7、R8、R9和R10相同或不同，每个都是氢原子等，或其盐。该方法包括在胺和镍催化剂的存在下，在溶剂中将下列化合物： 其中，X是离去基团，其他符号如上定义，或其盐，与下列膦硼烷复合物反应： 其中，符号如上定义，或其盐。
• PROCESS FOR THE REDUCTION OF A TERTIARY PHOSPHINE OXIDE TO THE CORRESPONDING TERTIARY PHOSPHINE IN THE PRESENCE OF A CATALYST AND USE OF A TERTIARY PHOSPHINE FOR REDUCING A TERTIARY PHOSPHINE OXIDE IN THE PRESENCE OF A CATALYST
  申请人：Laven Gaston

  公开号：US20130012725A1

  公开（公告）日：2013-01-10

  A process for the conversion of a tertiary phosphine oxide to the corresponding tertiary phosphine includes reacting the tertiary phosphine oxide with a reducing tertiary phosphine, in the presence of a catalyst that catalyzes the conversion.

  将三级膦氧化物转化为相应的三级膦的过程包括在催化剂的存在下，将三级膦氧化物与还原三级膦反应，催化剂催化转化。
• PHOSPHINE LIGANDS
  申请人：OXFORD ASYMMETRY INTERNATIONAL PLC

  公开号：EP0938488B1

  公开（公告）日：2002-01-02
• A PROCESS FOR THE REDUCTION OF A TERTIARY PHOSPHINE OXIDE TO THE CORRESPONDING TERTIARY PHOSPHINE IN THE PRESENCE OF A CATALYST AND USE OF A TERTIARY PHOSPHINE FOR REDUCING A TERTIARY PHOSPHINE OXIDE IN THE PRESENCE OF A CATALYST.
  申请人：Chromafora AB

  公开号：EP2552928B1

  公开（公告）日：2015-04-15