cis-[Me4N][Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)Cl] | 727730-58-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-[Me4N][Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)Cl]
• 英文别名: cis-[Me4N][Pt(κ2-(C,O)-C6(NO2)2-2,6-(OMe)3)(κ1-(C)-C6(NO2)2-2,6-(OMe)3)Cl]；chloroplatinum(1+);tetramethylazanium;2,3,4-trimethoxy-1,5-dinitrobenzene-6-ide
• CAS: 727730-58-7
• 化学式: C₄H₁₂N*C₁₈H₁₈ClN₄O₁₄Pt
• 分子量: 819.038
• InChiKey: IDNWSKHWXZMUNQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-[Me4N][Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)Cl] 以 二氯甲烷 为溶剂， 生成 cis-[Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)(tetrahydrothiophene)]
  参考文献：
  名称：

  Bis(2,6-dinitroaryl)platinum Complexes. 1. Synthesis through Transmetalation Reactions

  摘要：

  Complexes CiS-Q[Pt(kappa(2)-Ar)(kappa(1)-Ar)Cl] [Q = Ph3PCH2Ph (1), Me4N (2); kappa(2)-Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5-kappa(2)-C,O; kappa(1)-Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5- kappa(1)-C] have been prepared by reacting [HgAr2] [Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5] and Q(2)[Pt2Cl6] (4:1) in acetone at 100 degreesC. Complex 2 could be prepared by reacting [HgAr2] (i) with [Me4N](2)[Pt2Cl6] (2:1) in the presence of an excess of [Me4N]Cl or (ii) with [Me4N](2)[PtCl4] (1:1). The reaction of equimolecular amounts of 2 and Tl(acac) or AgClO4 gave, respectively, cis-Me4N[Pt(kappa(1)-Ar)(2)(acaC-kappa(2_)O,O)] (3) or cis-[Pt(kappa(2)-Ar)(kappa(1)-Ar)(OH2)] (4), which in turn reacts with neutral ligands to give cis-[Pt(kappa(2)-Ar)- (kappa(1)-Ar)L] [L = PhCN (5), tetrahydrothiophene (6)]. Hg(O2CCF3)(2) reacts with an equimolar amount of 2 to give cis-Me4N[Pt(kappa(2)-Ar)(kappa(1)-Ar){OC(O)CF3}] (7). The structures of complexes 1, 4.Et2O, 4.CH2Cl2, and 7 have been solved by X-ray diffraction studies.

  DOI：

  10.1021/om049801r
• 作为产物：
  描述：

  tetramethylammonium tetrachloroplatinate(II) 、 以 丙酮 为溶剂， 以96%的产率得到cis-[Me4N][Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)Cl]
  参考文献：
  名称：

  Bis(2,6-dinitroaryl)platinum Complexes. 1. Synthesis through Transmetalation Reactions

  摘要：

  Complexes CiS-Q[Pt(kappa(2)-Ar)(kappa(1)-Ar)Cl] [Q = Ph3PCH2Ph (1), Me4N (2); kappa(2)-Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5-kappa(2)-C,O; kappa(1)-Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5- kappa(1)-C] have been prepared by reacting [HgAr2] [Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5] and Q(2)[Pt2Cl6] (4:1) in acetone at 100 degreesC. Complex 2 could be prepared by reacting [HgAr2] (i) with [Me4N](2)[Pt2Cl6] (2:1) in the presence of an excess of [Me4N]Cl or (ii) with [Me4N](2)[PtCl4] (1:1). The reaction of equimolecular amounts of 2 and Tl(acac) or AgClO4 gave, respectively, cis-Me4N[Pt(kappa(1)-Ar)(2)(acaC-kappa(2_)O,O)] (3) or cis-[Pt(kappa(2)-Ar)(kappa(1)-Ar)(OH2)] (4), which in turn reacts with neutral ligands to give cis-[Pt(kappa(2)-Ar)- (kappa(1)-Ar)L] [L = PhCN (5), tetrahydrothiophene (6)]. Hg(O2CCF3)(2) reacts with an equimolar amount of 2 to give cis-Me4N[Pt(kappa(2)-Ar)(kappa(1)-Ar){OC(O)CF3}] (7). The structures of complexes 1, 4.Et2O, 4.CH2Cl2, and 7 have been solved by X-ray diffraction studies.

  DOI：

  10.1021/om049801r

文献信息

• Bis(2,6-dinitroaryl)platinum(II) Complexes. Cis/Trans Isomerization
  作者：José Vicente、Aurelia Arcas、María-Dolores Gálvez-López、Peter G. Jones

  DOI：10.1021/om060398t

  日期：2006.8.1

  PPh3 (1:2) gives cis-[Pt(κ1-Aryl)2LL‘] (L = L‘ = XyNC (3cis), PPh3 (8cis); L = CO, L‘ = PPh3 (6cis)). Complexes 3cis, 4cis, and 5cis isomerize on heating in solution or in the solid state to give 3trans, 4trans, and 5trans, respectively, while 6cis and 8cis decompose to give 7cis instead of their trans isomers; these, however, can be prepared by reacting 5trans or 6trans with PPh3 in molar ratios of 1:1

  配合物的顺式- [PT（κ 2 -芳基）（κ 1 -芳基）L]（κ 2 -芳基=κ 2 - （ç，ö）-C 6（NO 2）2 -2,6-（OME）3， κ 1 -芳基=κ 1（ç）-C 6（NO 2）2 -2,6-（OME）3，L =小号-DMSO（2个顺式），XyNC（4个顺式; XY = 2,6 -Me 2 C 6 H 4），CO（5顺式），PPH 3（ 7个顺式））已经被通过在室温下反应而得到的顺式- [PT（κ 2 -芳基）（κ 1 -芳基）（OH 2）]（ 1个顺式）与二甲亚砜（DMSO; 1 ：1或过量），XyNC（1：1），或CO（过量）或顺式- （ME 4 N）[PT（κ 2 -芳基）（κ 1 -芳基）氯]与PPH 3（1：1） ， 分别。1 cis与XyNC（1：2）， 5 cis与PPh 3（1：1）或cis-（Me 4的室温反应N）[PT（κ 2 -芳基）（κ 1 -芳基）氯]与PPH
• Bis(2,6-dinitroaryl)platinum Complexes. 2.¹ Di- and Trinuclear Complexes Containing Pt−Hg Bonds
  作者：José Vicente、Aurelia Arcas、María Dolores Gálvez-López、Peter G. Jones

  DOI：10.1021/om049699y

  日期：2004.7.1

  [Hg(O2CR)(2)] reacts with an equimolar amount of cis-Me4N[Pt(kappa(2)-Ar)(kappa(1)-Ar)Cl] (1) [kappa(2)-Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5-kappa(2)-C,O; kappa(1)-Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5-kappa(1)-C] or with cis-[Pt-(kappa(2) -Ar)(kappa(1)-Ar)(OH2)] (2) in a 2:1 molar ratio to give Me4N[Hg(mu-OAc)(2)Pt(kappa(1)-Ar)(2)Cl}] (5) or, depending on R, [Hg(mu-OAc)(2)Pt(kappa(2)-Ar)(2)}(2)] (6) or [HgPt(kappa(2)-Ar)(2)(O2CR)}(2)] [R = Ar (7), C6F5 (8), CF3 (9)]. Refluxing in toluene a mixture of [HgAr2] [Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5], [Pt(dba)(2)] (dba = dibenzylideneacetone), and (i) PPh3 (1:1:2) or (ii) bpy in molar ratio 1:1.3: 1.6 gave cis-[Pt(kappa(1)-Ar)Hg(kappa(1)-Ar)}L-2] [L = PPh3 (10), L-2 = bpy (11)]. Complex 10 reacts with XyNC (Xy = C6H3Me2-2,6) to give [Pt(kappa(1)-Ar)Hg(kappa(1)-Ar)}(CNXy)(PPh3)] (12). The structures of complexes 7, 9.CHCl3.CH2Cl2, and 10 have been solved by X-ray diffraction studies.