ethylsalicylaldiminato-diethyldithiocarbamatonickel(II) | 355007-79-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ethylsalicylaldiminato-diethyldithiocarbamatonickel(II)
• CAS: 355007-79-3
• 化学式: C₁₄H₂₀N₂NiOS₂
• 分子量: 355.148
• InChiKey: OFCMAJJXCDUTHH-WRQJSNHTSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [nickel(II)bis(N-ethylsalicylideneiminate)] 、 sodium N,N-diethyldithiocarbamate 以 乙醇 为溶剂， 以60%的产率得到ethylsalicylaldiminato-diethyldithiocarbamatonickel(II)
  参考文献：
  名称：

  NICKEL(II) COMPLEXES CONTAINING MIXED ALKYLSALICYLALDIMINATE AND ALKYLXANTHATE OR DIETHYLDITHIOCARBAMATE LIGANDS

  摘要：

  Stable mixed-ligand complexes of Ni(II) alkylsalicylaldiminate Schiff base and alkylxanthate or diethyldithiocarbamate have been prepared. The complexes have the general formulae K[Ni(Rsal)(R ' xan)(2)] and [Ni(Rsal)(Et2NCS2)] where Rsal = ethyl, isopropyl or isobutyl salicylaldiminate; Rxan ' = methyl-, ethyl- or butylxanthate and Et2NCS2- = diethyldithiocarbamate anion. The complexes have been characterized and studied by elemental analyses, conductivity, IR and electronic spectra as well as by thermo gravimetry. All data indicate that the xanthate complexes have an octahedral structure and the xanthate group is attached in a bidentate fashion to the nickel(II) ion. For the dithiocarbamate complexes, a square-planar structure is confirmed and the dithiocarbamate anion coordinates as a bidentate ligand.

  DOI：

  10.1081/sim-100002232