2-benzoyl-3-methoxy-4-phenacylcyclopent-2-ene-1-one | 146681-23-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 2-benzoyl-3-methoxy-4-phenacylcyclopent-2-ene-1-one
• 英文别名: 2-benzoyl-3-methoxy-4-phenacylcyclopent-2-en-1-one
• CAS: 146681-23-4
• 化学式: C₂₁H₁₈O₄
• 分子量: 334.372
• InChiKey: DYXWOEJKWVHCGQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.63
• 重原子数：
  25.0
• 可旋转键数：
  6.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  60.44
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  甲醇 、 2-benzoyl-3-hydroxy-4-phenacylcyclopent-2-ene-1-one 在 硫酸 作用下， 生成 2-benzoyl-3-methoxy-4-phenacylcyclopent-2-ene-1-one
  参考文献：
  名称：

  β-Tricarbonyl compounds. I. 2,4-Disubstituted 1,3-cyclopentanediones

  摘要：

  Stable enolic isomers of 2-aroyl-4-aracyl-1,3-cyclopentanediones such as 3 and 4 were prepared by condensation of aryl methyl ketones and diethyl maleate using an excess of sodium ethoxide (Aryl = C6H5, 4-C6H4CH3, 4-C6H4Br and 4-C6H4Cl).

  DOI：

  10.1007/bf00808280

文献信息

• β-Tricarbonyl compounds. I. 2,4-Disubstituted 1,3-cyclopentanediones
  作者：Zvjezdana Lazarević、Jasna Vorkapić-Furač、Jasenka Mühl

  DOI：10.1007/bf00808280

  日期：1992.12

  Stable enolic isomers of 2-aroyl-4-aracyl-1,3-cyclopentanediones such as 3 and 4 were prepared by condensation of aryl methyl ketones and diethyl maleate using an excess of sodium ethoxide (Aryl = C6H5, 4-C6H4CH3, 4-C6H4Br and 4-C6H4Cl).