| 1392406-58-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1392406-58-4
• 化学式: CNS*C₆H₅Se*Hg
• 分子量: 414.739
• InChiKey: VGFRFKCEMVGKEO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.14
• 重原子数：
  11.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  22.3
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  mercury(II) thiocyanate 、 di(phenylselenenyl)mercury 在 bis(2-pyridylthio)methane 作用下， 以 乙酸乙酯 、 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Synthesis and structural characterization of a binary metal cluster and a coordination polymer based on the mercury Bis(phenylselenolate) unit

  摘要：

  The versatile coordination chemistry of the Bis(phenylselenolate)(Hg(SePh)(2)) with Hg(SCN)(2) salt allows the synthesis of a cluster and a 2D coordination polymer. The reaction at low temperature in dimethylformamide (dmf) affords single crystals containing neutral clusters with the formula [Hg8S(SCN)(2)(SePh)(12)(dmf)(2)] (1). Then, the 2D coordination polymer [Hg(SCN)(SePh)] (2) is obtained in comparable yielding. The use of bis(2-pyridylthio)methane as secondary ligand significantly improves the synthesis of 2, since it is synthesized at room temperature, in a short time and in a good yield. The effects of the weak interactions in the crystal packing were also analyzed. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.06.015