tetraphenylantimony chlorate | 16894-73-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetraphenylantimony chlorate
• CAS: 16894-73-8
• 化学式: C₂₄H₂₀Sb*ClO₃
• 分子量: 513.624
• InChiKey: QYKKPQLZOQGYCB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  29.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  69.18
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  potassium chlorate 、 tetraphenylchloroantimony(V) 以 水 为溶剂， 以89%的产率得到tetraphenylantimony chlorate
  参考文献：
  名称：

  Tetraphenylantimony perrhenate and tetraphenylantimony chlorate: Syntheses and structures

  摘要：

  The reaction of tetraphenylantimony chloride with sodium perrhenate or potassium chlorate yields tetraphenylantimony perrhenate (I) and tetraphenylantimony chlorate (II), respectively. Complex I was also synthesized from pentaphenylantimony and triphenylantimony diperrhenate in toluene. According to X-ray diffraction, crystals I and II consist of almost regular tetrahedral tetraphenylstibonium cations (CSbC, 109.4(2)degrees - 109.5( 7)degrees in I and 109.1(1)degrees - 109.6(1)degrees in II) and [ReO(4)](-) (OreO, 107.6(3)degrees - 113.3(5)degrees) and [ClO(3)](-) (OClO, 96.3(9)degrees, 116.4(5)degrees) anions, respectively. The average Sb-C bond lengths (2.094(3) angstrom in I, 2.097(2) angstrom in II) are close to the sum of the covalent radii of the Sb and C atoms. The average distances Re-O in complex I (1.672(4)angstrom) and Cl-O in complex II (1.315 angstrom) correspond to multiple bonds.

  DOI：

  10.1134/s0036023609030103