2-phenylethyl octanoate | 4076-76-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-phenylethyl octanoate
• 英文别名: octanoic acid-(N'-phenyl-hydrazide)；N'-Phenyl-N-octanoyl-hydrazin；Octansaeure-(N'-phenyl-hydrazid)；β-Capryloyl-phenylhydrazin；N'-Capryloyl-N-phenyl-hydrazin；Octanoic acid, 2-phenylhydrazide；N'-phenyloctanehydrazide
• CAS: 4076-76-0
• 化学式: C₁₄H₂₂N₂O
• 分子量: 234.341
• InChiKey: GBWNQLDDRUYFOY-UHFFFAOYSA-N

物化性质

• 沸点：
  321.2±15.0 °C(Predicted)
• 密度：
  1.017±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  41.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-phenylethyl octanoate 在 四氯化碳 、 三苯基膦 作用下， 以 甲醇 、 乙腈 为溶剂， 反应 4.0h， 生成 N’-formyl-N’-phenyl-n-caprylhydrazide
  参考文献：
  名称：

  Sakamoto, Takeshi; Kikugawa, Yasuo, Chemical and pharmaceutical bulletin, 1988, vol. 36, # 2, p. 800 - 802

  摘要：

  DOI：
• 作为产物：
  描述：

  苯肼 、 alkaline earth salt of/the/ methylsulfuric acid 生成 2-phenylethyl octanoate
  参考文献：
  名称：

  Autenrieth, Chemische Berichte, 1901, vol. 34, p. 177

  摘要：

  DOI：

文献信息

• Catalytic Aerobic Oxidation of Arylhydrazides with Iron Phthalocyanine
  作者：Takuma Hashimoto、Daisuke Hirose、Tsuyoshi Taniguchi

  DOI：10.1002/adsc.201500459

  日期：2015.10.12

  A convenient method for the synthesis of 2-arylazocarboxylates from 2-arylhydrazinecarboxylates by aerobic oxidation with iron phthalocyanine is described. The reaction is applicable to oxidative activation of 1-acyl-2-phenylhydrazines. Some preliminary experiments suggest Michaelis–Menten kinetics and participation of radical species in the reaction mechanism.

  描述了一种通过用酞菁铁进行好氧氧化由2-芳基肼羧酸盐合成2-芳基偶氮羧酸盐的简便方法。该反应适用于1-酰基-2-苯基肼的氧化活化。一些初步实验表明，Michaelis-Menten动力学和自由基物种参与反应机理。
• Lipase-Catalyzed Synthesis of Carboxylic Amides: Nitrogen Nucleophiles as Acyl Acceptor
  作者：Fred van Rantwijk、Michiel A. P. J. Hacking、Roger A. Sheldon

  DOI：10.1007/s007060070086

  日期：2000.6.15

   The lipase-catalyzed aminolysis of carboxylic esters is a fairly general reaction that has been performed with a wide range of esters and amines, generally in anhydrous organic media to avoid undesirable hydrolysis of the ester. Alternatively, carboxylic amides can be synthesized by lipase mediated condensation of carboxylic acids and amines if an excess of either reactant is avoided.

  脂肪酶催化的羧酸酯的氨解反应是相当普遍的反应，通常在无水有机介质中用多种酯和胺进行，以避免酯发生不希望的水解。或者，如果避免了任何一种反应物的过量，则可以通过脂肪酶介导的羧酸和胺的缩合来合成羧酸酰胺。
• The Use of Phenylhydrazine to Characterize Organic Acids¹
  作者：G. H. Stempel、Gerson S. Schaffel

  DOI：10.1021/ja01254a509

  日期：1942.2
• SAKAMOTO, TAKESHI;KIKUGAWA, YASUO, CHEM. AND PHARM. BULL., 36,(1988) N 2, 800-802
  作者：SAKAMOTO, TAKESHI、KIKUGAWA, YASUO

  DOI：——

  日期：——
• ORGANIC SEMICONDUCTOR COMOSITION, ORGANIC THIN-FILM TRANSISTOR, ELECTRONIC PAPER, AND DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20160064674A1

  公开（公告）日：2016-03-03

  An object of the present invention is to provide an organic semiconductor composition, which improves the insulation reliability of an organic thin-film transistor without greatly reducing the mobility of the organic thin-film transistor, an organic thin-film transistor which is prepared by using the organic semiconductor composition, and electronic paper and a display device which use the organic thin-film transistor. The organic semiconductor composition of the present invention contains an organic semiconductor material (A) and a polymer compound (B) containing a repeating unit represented by the following Formula (B).