S,S-Diphenyl-N-(trimethylsilyl)sulfimin | 114155-99-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: S,S-Diphenyl-N-(trimethylsilyl)sulfimin
• 英文别名: S,S-diphenyl-N-(trimethylsilyl)sulfimine；[(diphenyl-λ4-sulfanylidene)amino]-trimethylsilane
• CAS: 114155-99-6
• 化学式: C₁₅H₁₉NSSi
• 分子量: 273.474
• InChiKey: BVMVWQFXOJXYGM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.74
• 重原子数：
  18.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  12.36
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  五氯化钼 、 S,S-Diphenyl-N-(trimethylsilyl)sulfimin 以 氯仿 为溶剂， 以81%的产率得到acetonitrile-tetrachloro-(diphenyl-λ4-sulfanylidene)molybdenum(V)
  参考文献：
  名称：

  Roesky, Herbert W.; Zimmer, Michael; Schmidt, Hans Georg, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1988, vol. 43, # 11, p. 1490 - 1494

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N-二甲基三甲基硅胺 、 S,S-二苯基硫亚胺 在 硫酸 作用下， 以94%的产率得到S,S-Diphenyl-N-(trimethylsilyl)sulfimin
  参考文献：
  名称：

  Roesky, Herbert W.; Zimmer, Michael; Noltemeyer, Mathias, Chemische Berichte, 1988, vol. 121, p. 1377 - 1380

  摘要：

  DOI：

文献信息

• Uranium(VI) Sulfilimine Complexes:  A New Class of Nitrogen Analogues of the Uranyl Ion
  作者：V. Cliff Williams、Matthias Müller、Michael A. Leech、Robert G. Denning、Malcolm L. H. Green

  DOI：10.1021/ic991294w

  日期：2000.6.1

  The compound tetraphenylphosphonium tetrachlorooxo-S,S-diphenylsulfiliminatour [Ph4P][UOCl4(NSPh2)], has been prepared in high yield from [Ph4P][UOCI5] and [Ph2S=NSiMe3]. An X-ray structure of this compound shows that the uranium atom has a pseudooctahedral geometry with oxygen and nitrogen atoms in trans positions. The structure of the analogous phosphoriminato complex [Ph4P][UOCl4(NPPh3)] has been determined for comparison. Derivatization of the sulfide group shows that only a limited range of functionalization confers stability toward reduction. The emission spectrum of the first electronic excited state reveals a greatly reduced energy compared with that of the uranyl ion. This red shift in the transition is consistent with the weakening of the U-N bond relative to the U-O bond.
• Uranium−Sulfilimine Chemistry:  Synthesis and Characterization of Cp*₂UCl(NSPh₂) and Cp*₂U(NSPh₂)₂
  作者：Kanahara A. N. S. Ariyaratne、Roger E. Cramer、John W. Gilje

  DOI：10.1021/om020678i

  日期：2002.12.1

  Two imido derivatives of U(IV), CP*2UCl(NSPh2) (1; Cp* = pentamethylcyclopentadienyl) and CP*U-2(NSPh2)(2) (2), have been prepared in high yield from CP*2UCl2 and LiNSPh2. Alternatively, 1 and 2 can be synthesized by treating CP*2UCl[(CH2)(2)PPh2] with anhydrous HNSPh2. CP*U-2(NSPh2)(2) is the first structurally characterized uranium bis(sulfilimide) complex. Its short U-N distance suggests significant uranium-imido multiple-bond character.