| 14741-66-3

• CAS: 14741-66-3
• 化学式: C₆H₃FeNO₄
• 分子量: 208.941
• InChiKey: JDHWNAVGQJQADG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  diiron nonacarbonyl 在 乙腈 作用下， 以 乙腈 为溶剂， 以45.2%的产率得到
  参考文献：
  名称：

  Cyclocarbonylation of 1,6-Enynes Promoted by Iron Carbonyls

  摘要：

  Iron carbonyls have been found to promote the cyclocarbonylation of 1,6-enynes to give cyclopentenones in good yield. The reaction is essentially the same as the intramolecular Pauson-Khand reaction. The best results were obtained using allyl propargyl ethers as substrates. Isomerization of the alkene moiety competes with cyclization in some cases, leading to reduced yields. Stereoselectivity comparable with that obtained in the Pauson-Khand reaction was observed during the cyclization of alkoxy-substituted enynes; this stereoselectivity appears to be kinetic rather than thermodynamic.

  DOI：

  10.1021/om00017a024

文献信息

• Nayak, Suresh K.; Farrell, Gerard J.; Burkey, Theodore J., Inorganic Chemistry, 1994, vol. 33, # 10, p. 2236 - 2242
  作者：Nayak, Suresh K.、Farrell, Gerard J.、Burkey, Theodore J.

  DOI：——

  日期：——
• Wang, Shian-Jy; Miller, Lance L.; Jacobson, Robert A., Inorganica Chimica Acta, 1988, vol. 145, p. 129 - 138
  作者：Wang, Shian-Jy、Miller, Lance L.、Jacobson, Robert A.、Angelici, Robert J.

  DOI：——

  日期：——
• Kinetics and mechanism of the reaction of [Et4N][HFe(CO)4] and alkyl halides. The unexpected formation of acetone
  作者：Kenton H. Whitmire、T. Randall. Lee、E. S. Lewis

  DOI：10.1021/om00136a025

  日期：1986.5.1
• Low temperature photochemistry of [Fe2(CO)6(bipy)-(P(n-Bu)3)]. Stabilization of an intermediate photoproduct in a decomposition reaction
  作者：Hans K. van Dijk、Derk J. Stufkens、Ad Oskam

  DOI：10.1016/0022-328x(88)80078-0

  日期：1988.2