[(η(6)-C6Me6)Ru(S2C6H4)] | 187409-13-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(η(6)-C6Me6)Ru(S2C6H4)]
• 英文别名: benzene-1,2-dithiolate;1,2,3,4,5,6-hexamethylbenzene;ruthenium(2+)
• CAS: 187409-13-8
• 化学式: C₁₈H₂₂RuS₂
• 分子量: 403.575
• InChiKey: NBQKNXPYMVCRNI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(η(6)-C6Me6)Ru(S2C6H4)] 、 三乙基膦 以 四氢呋喃 为溶剂， 以64%的产率得到[(η(6)-C6Me6)Ru(S2C6H4)(PEt3)]
  参考文献：
  名称：

  Mashima, Kazushi; Kaneyoshi, Hiromu; Kaneko, Sei-ichi, Organometallics, 1997, vol. 16, p. 1016 - 1025

  摘要：

  DOI：
• 作为产物：
  描述：

  [(η(6)-C6Me6)Ru(S(2,6-C6H3Me2))3] 、 disodium benzene-1,2-dithiolate 以 四氢呋喃 为溶剂， 以46%的产率得到[(η(6)-C6Me6)Ru(S2C6H4)]
  参考文献：
  名称：

  Mashima, Kazushi; Kaneyoshi, Hiromu; Kaneko, Sei-ichi, Organometallics, 1997, vol. 16, p. 1016 - 1025

  摘要：

  DOI：

文献信息

• Structural and Electrochemical Properties of a Ruthenium–Diiron Dithiolene Complex
  作者：Takuya Sagawa、Satoru Tsukada、Kazuki Yamamoto、Takahiro Gunji

  DOI：10.1002/ejic.201700783

  日期：2017.9

  The ruthenium-diiron dithiolene complex [(η6-C6Me6)Ru(CO)(μ-CO)2Fe2(μ-bdt)(CO)4] (2) was synthesized and two crystallographic isomers were isolated, which depend on the recrystallization temperature; specifically, 2 and its isomer (2') were obtained at -30 oC and room temperature, respectively. A single crystal of 2 was converted to 2' by leaving it in hexane at room temperature for one week. A single

  合成了钌-二铁二硫烯配合物[(η6-C6Me6)Ru(CO)(μ-CO)2Fe2(μ-bdt)(CO)4] (2) 并分离了两种晶体异构体，这取决于重结晶温度; 具体而言，2 及其异构体 (2') 分别在 -30 oC 和室温下获得。通过在室温下将其置于己烷中一周，将 2 的单晶转化为 2'。2' 的单晶在 -30 oC 的己烷中没有转化为 2。然而，2 可以通过 2' 从二氯甲烷和己烷的混合溶剂中重结晶得到。这些结果表明 2 是溶剂中最稳定的形式。异构化的发生是因为与 2 相比，2' 堆积结构的稳定性。此外，发现 2 作为质子还原的催化剂；
• Preparation of Ruthenium Dithiolene Complex/Polysiloxane Films and Their Responses to CO Gas
  作者：Satoru Tsukada、Takuya Sagawa、Kazuki Yamamoto、Takahiro Gunji

  DOI：10.3390/molecules23040845

  日期：——

  To develop advanced materials using metal complexes, it is better to prepare metal complexes contained in composite or hybrid films. To achieve this purpose, we synthesized ruthenium complexes with dihalogen-substituted benzendithiolate ligands, [(η⁶-C₆Me₆)Ru(S₂C₆H₂X₂)] (X = F, 3,6-Cl, Br, 4,5-Cl), 1b-1e. We also investigated preparation of 1c or 1e containing polysiloxane composite films and their

  为了使用金属络合物开发高级材料，最好制备复合膜或杂化膜中包含的金属络合物。为了达到这个目的，我们合成了具有二卤素取代的苯二硫代磺酸盐配体[[（η⁶-C₆Me₆）Ru（S 2C₆H2 X 2）]（X = F，3,6-Cl，Br，4,5-Cl），1b-1e的钌配合物。 。我们还研究了含1c或1e的聚硅氧烷复合膜的制备及其与CO气体的反应性。所有钌络合物1b-1e与CO气体反应，生成羰基配体加合物2b-2e。钌配合物1b-1e在550和420 nm附近显示出两个强吸收峰。暴露于CO气体后，这些吸收峰立即降低而没有峰移动。在含1c或1e的聚硅氧烷复合膜中观察到了类似的趋势。
• Synthesis and reactions of coordinatively unsaturated 16-electron chalcogenolate complexes, Ru(EAr) 2(η6-arene) and cationic binuclear chalcogenolate complexes, [(η6-arene) Ru(μ-EPh)3 Ru(η6-arene)]PF6
  作者：Kazushi Mashima、Sei-ichi Kaneko、Kazuhide Tani、Hiromu Kaneyoshi、Akira Nakamura

  DOI：10.1016/s0022-328x(97)00378-1

  日期：1997.1

  ruthenium-selenolate complexes (η6-arene)Ru(Se-2,4,6-C6H2Me3)2 [arene =p=CH3C6H4(CHMe2) (5b), C6Me6 (5c)] have been prepared by treating [((η6-arene)RuCl2]2 (1) with sodium salt of 2,4,6-trimethylphenyl-selenolate in methanol. The complexes 5 are compared with the thiolate complexes such as (η6-arene)Ru(SAr)2 [SAr = 2,6-dimethylbenzenethiolate (2), SAr = 2,4,6-tri(isopropyl)benzenethiolate (3), (SAr)2 = 1,2-benzenedithiolate

  配位不饱和16电子钌- SElenolate络合物（η 6 -arene）的Ru（SE-2,4,6--C 6 H ^ 2我3）2 [芳烃= p = CH 3 Ç 6 ħ 4（CHME 2）（图5b），C 6我6（图5c）]已准备通过处理[（（η 6 -arene）的RuCl 2 ] 2（1）用在甲醇中2,4,6-三甲基- SElenolate的钠盐。配合物5是与硫醇盐配合物，如比较（η 6 -arene）的Ru（SAR）2 [SAr ＝ 2，6-二甲基苯硫醇盐（2），SAr ＝ 2，4，6-三（异丙基）苯硫醇盐（3），（SAr）2＝ 1，2-苯二硫醇盐（4）；芳烃＝ C 6 H 6（a），对-CH 3 C 6 H 4（CHME 2）（b），C 6 Me 6（c）]，这是我们最近制备的。然而，碲化物类似物尚未以类似方式获得。这些硒酸酯络合物为深绿色，归因于LMCT谱带[pπ（SE）→dπ *
• Thermochromic Triangular [MCo₂] (M = Rh, Ir, Ru) Clusters Containing a Planar Metalladithiolene Ring in η³ Coordination
  作者：Norikiyo Nakagawa、Teppei Yamada、Masaki Murata、Manabu Sugimoto、Hiroshi Nishihara

  DOI：10.1021/ic051829n

  日期：2006.1.1

  The first series of triangular cluster complexes of [MCo(2)] (M = Rh, Ir, Ru) with a planar metalladithiolene ring coordinating in the eta(3)-bonding mode were synthesized, and the crystal structures, spectral and electrochemical properties, and thermochromism of these complexes were revealed.

  合成了第一系列的[MCo（2）]（M = Rh，Ir，Ru）的三角形簇络合物，其具有在eta（3）-键模式下配位的平面金属二硫代噻吩环，并且其晶体结构，光谱和电化学性质，并揭示了这些配合物的热致变色现象。
• Synthesis and reactivity of hydride-bridged ruthenium dithiolene complexes
  作者：Takuya Sagawa、Satoru Tsukada、Kazuki Yamamoto、Takahiro Gunji

  DOI：10.1016/j.poly.2017.10.023

  日期：2018.1

  Syntheses of two homonuclear hydride complexes, viz. hydride-bridged ruthenium dinuclear complex [Ru(eta(6)-C6Me6)(S2C6H4)RuClH(PPh3)(2)] (3) and dihydride ruthenium dinuclear complex [Ru(eta(6)-C6Me6) (S2C6H4) RuH2(PPh3)(2)] (4), have been described. Complex 4 was obtained as a mixture of cis- and trans-dihydride isomers in a 10:1 M ratio, as indicated by the proton ratio in H-1 NMR spectra. The dinuclear complex 4 reacted with carbon monoxide for 30 min and 1 day under similar conditions to produce dicarbonyl complex [Ru(eta(6)-C6Me6)(S2C6H4)Ru(CO)(2)(PPh3)] (5), and tetracarbonyl complex [Ru-2(CO)(4)(PPh3)(2)(S2C6H4)] (6), respectively. On the other hand, treatment of 4 with carbon dioxide under ambient conditions was found to produce formic acid. (C) 2017 Elsevier Ltd. All rights reserved.