1,2,3,4,5,6-hexaphenyl-1,3,5-triphospha-2,4,6-triarsacyclohexane | 85233-03-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2,3,4,5,6-hexaphenyl-1,3,5-triphospha-2,4,6-triarsacyclohexane
• 英文别名: hexaphenyl-1,3,5-triphospha-2,4,6-triarsacyclohexane；1,3,5-tris(phenylphospha)-2,4,6-tris(phenylarsa)cyclohexane；hexaphenyl-cyclotriarsaphosphane；Phospharsenobenzol；Hexaphenyl-cyclotriarsaphosphan；1,2,3,4,5,6-hexakis-phenyl-1,3,5,2,4,6-triphosphatriarsinane
• CAS: 85233-03-0
• 化学式: C₃₆H₃₀As₃P₃
• 分子量: 780.32
• InChiKey: MWSSYKSAYDTHCY-UHFFFAOYSA-N

物化性质

• 熔点：
  190 °C
• 沸点：
  725.4±43.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.61
• 重原子数：
  42.0
• 可旋转键数：
  6.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  四氯化碳 、 1,2,3,4,5,6-hexaphenyl-1,3,5-triphospha-2,4,6-triarsacyclohexane 生成 diphenyldiphosphene
  参考文献：
  名称：

  Steinkopf; Dudek, Chemische Berichte, 1929, vol. 62, p. 2496

  摘要：

  DOI：
• 作为产物：
  描述：

  二氯苯胂 、 苯基膦 以 乙醚 为溶剂， 反应 1.0h， 以74%的产率得到1,2,3,4,5,6-hexaphenyl-1,3,5-triphospha-2,4,6-triarsacyclohexane
  参考文献：
  名称：

  Structure of product of reaction between phenylphosphine and phenyldichloroarsine and phenylarsine oxide

  摘要：

  DOI：

  10.1007/bf00956164

文献信息

• Reaction of bis(?-hydroxyethyl)phenylphosphine with phenylarsine oxide and dimethyl ester of phenylarsenous acid
  作者：O. A. Erastov、I. P. Romanova、N. A. Chadaeva

  DOI：10.1007/bf01167801

  日期：1983.1
• Synthesis and crystal structure of a molybdenum carbonyl complex, Mo(CO)4[cyclo(Ph6P3As3)], with scrambled phosphorus/arsenic identities obtained from a perfectly alternating phosphorus-arsenic heterocycle, 1,3,5-tris(phenylphospha)-2,4,6-tris(phenylarsa)cyclohexane, [cyclo(Ph6P3As3)]
  作者：Arnold L. Rheingold、Frederick P. Arnold

  DOI：10.1016/s0020-1693(00)92354-5

  日期：1992.8

  1,3,5-Tris(phenylphospha)-2,4,6-tris(phenylarsa)cyclohexane, cyclo(Ph6As3P3), whose perfectly alternating pnictogen structure was determined by the absence of direct P-P coupling in NMR spectra, reacts with MO(CO)6 at 80-degrees-C to form a complex, Mo(CO)4[C-(Ph6As3P3)], containing completely scrambled phenylpnictidene units. The structure of the complex has been crystallographically determined: monoclinic, P2(1)/n, a = 11.756(3), b=22.691(9), c = 14.777 angstrom, beta = 99.89(2)-degrees, V = 3883.5(22) angstrom3, Z = 4, R, = 5.66%. The original chair conformation of the heterocycle is converted to a twist-boat form in the product, but the presence of concentrated phosphorus character in the 1 and 4 positions coordinated to Mo indicates that ring-opening and ring-scrambling equilibria preceded complex formation.
• EROLITOV, O. A.;ROMANOVA, I. P.;CHADAEVA, N. A., IZV. AN CCCP. CEP. XIM., 1983, N 1, 235
  作者：EROLITOV, O. A.、ROMANOVA, I. P.、CHADAEVA, N. A.

  DOI：——

  日期：——
• ERASTOV, O. A.;ROMANOVA, I. N.;EFREMOV, YU. YA.;ILYASOV, A. V.;ZYABLIKOVA+, IZV. AN CCCP. CEP. XIM., 1983, N 5, 1152-1155
  作者：ERASTOV, O. A.、ROMANOVA, I. N.、EFREMOV, YU. YA.、ILYASOV, A. V.、ZYABLIKOVA+

  DOI：——

  日期：——