4H-吡喃-4-酮,2,3-二甲基- | 82231-60-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4H-吡喃-4-酮,2,3-二甲基-
• 英文名称: Cuminyl hydroperoxide
• 英文别名: 1-(hydroperoxymethyl)-2-propan-2-ylbenzene
• CAS: 82231-60-5
• 化学式: C₁₀H₁₄O₂
• 分子量: 166.22
• InChiKey: IHGXYVRBCMDFET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• Hydrogel Nanocompsites for Ophthalmic Applications
  申请人：Ravi Nathan

  公开号：US20070269488A1

  公开（公告）日：2007-11-22

  The present invention relates to reversible hydrogel systems. Particularly, the hydrogel of the present invention is made up of copolymers that can be a hydrogel when in an oxidized state and can be a solution when in a reduced state. A solution of the copolymer can be oxidized to form a hydrogel; and the hydrogel can be reduced to form a solution of the copolymer. Reversible nanogels can also be formed from a dilute solution of the copolymers. The hydrogel is formed with nanoparticles embedded therein to form a nanocomposite whose refractive index and modulus can be controlled by varying the amounts of nanoparticles and the polymer concentration of the hydrogel, respectively

  本发明涉及可逆水凝胶系统。特别是，本发明的水凝胶由共聚物组成，在氧化状态时可以是水凝胶，在还原状态时可以是溶液。共聚物的溶液可以被氧化成水凝胶；水凝胶可以被还原成共聚物的溶液。还可以从稀溶液的共聚物形成可逆纳米凝胶。水凝胶中嵌入了纳米颗粒以形成折射率和模量可以通过改变纳米颗粒的量和水凝胶的聚合物浓度来控制的纳米复合材料。
• Improved MBS impact modifier
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0985692A2

  公开（公告）日：2000-03-15

  A process and composition for MBS modifiers having (A) a rubbery core, (B) an inner graft stage comprised mainly of a hard polymer, (C) an intermediate sealer stage comprised mainly of an alkyl acrylate monomer and/or a polyunsaturated crosslinker, and (D) an outer shell to provide compatibility of the core-shell polymer with the matrix polymer, is disclosed. A process for preparing MBS impact modifiers having suprisingly improved impact performance in matrix polymers is also disclosed. Articles prepared from blends of matrix polymers and the MBS core-shell polymers described herein are also disclosed.

  本发明公开了一种 MBS 改性剂的工艺和组合物，该改性剂具有 (A) 橡胶芯，(B) 主要由硬质聚合物组成的内接枝阶段，(C) 主要由丙烯酸烷基酯单体和/或多不饱和交联剂组成的中间封端阶段，以及 (D) 用于提供芯壳聚合物与基质聚合物相容性的外壳。本发明还公开了一种制备 MBS 抗冲改性剂的工艺，这种改性剂在基体聚合物中的抗冲击性能得到了惊人的改善。还公开了由基体聚合物和本文所述 MBS 芯壳聚合物的混合物制备的物品。
• Process for the preparation of polymers having a reduced content of volatile components
  申请人：Wacker Polymer Systems GmbH & Co. KG

  公开号：US20020165341A1

  公开（公告）日：2002-11-07

  The invention relates to a process for the preparation of polymers stabilized with protective colloids in the form of water-redispersible powders or aqueous dispersions thereof having a reduced content of volatile components, by a) polymerizing by emulsion or suspension polymerization, one or more monomers from the group consisting of vinyl esters, (meth)acrylates, vinyl aromatics, olefins, 1,3-dienes and vinyl halides and optionally further monomers copolymerizable therewith, b) aftertreating the polymer dispersion thus obtained by means of postpolymerization, distillation, and/or introduction of steam or inert gas to obtain a residual content of volatile, nonaqueous components of <2000 ppm, and c) spray drying of aftertreated polymer dispersion to a residual content of volatile, nonaqueous components of <400 ppm, the dispersion being adjusted prior to spray drying to a solids content of <45% by weight before spraying, the spray drying performed with gas at an inlet temperature of >120° C., and optimally d) redispersing of the resulting powder in water.

  本发明涉及一种用保护胶体稳定的聚合物的制备工艺，其形式为水可再分散的粉末 或水分散体，挥发性成分含量较低，制备方法为 a) 通过乳液聚合或悬浮聚合将乙烯基酯、（甲基）丙烯酸酯、乙烯基芳烃、烯烃、1,3-二 烯和卤化乙烯基以及可与之共聚的其他单体中的一种或多种单体聚合、 b) 通过后聚合、蒸馏和/或引入蒸汽或惰性气体对由此获得的聚合物分散体进行后处理，使挥发性非水成分的残留量小于 2000 ppm，以及 c) 将处理后的聚合物分散液喷雾干燥，使挥发性非水成分的残留量达到 120 摄氏度，最佳方法是 d) 将得到的粉末重新分散在水中。
• Reversible hydrogel systems and methods therefor
  申请人：——

  公开号：US20040156880A1

  公开（公告）日：2004-08-12

  The present invention relates to reversible hydrogel systems for medical applications. Particularly, the hydrogel of the present invention is made up of copolymers that can be a hydrogel when in an oxidized state and can be a solution when in a reduced state. A solution of the copolymer can be oxidized to form a hydrogel; and the hydrogel can be reduced to form a solution of the copolymer. The solution can be dehydrated to produce the dry copolymer for storage. Furthermore, the present invention also relates to methods of making and using the reversible hydrogel systems.

  本发明涉及医疗应用中的可逆水凝胶系统。特别是，本发明的水凝胶由共聚物组成，共聚物在氧化状态下可以是水凝胶，在还原状态下可以是溶液。共聚物溶液经氧化后可形成水凝胶；水凝胶经还原后可形成共聚物溶液。溶液可以脱水，生成干的共聚物用于储存。此外，本发明还涉及可逆水凝胶系统的制造和使用方法。
• EP0985692B1
  申请人：——

  公开号：EP0985692B1

  公开（公告）日：2005-01-19