methyl 4-(2-(4-(dodecyloxy)benzoyl)hydrazinecarbonyl)benzoate | 1361152-19-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methyl 4-(2-(4-(dodecyloxy)benzoyl)hydrazinecarbonyl)benzoate
• 英文别名: Methyl 4-[[(4-dodecoxybenzoyl)amino]carbamoyl]benzoate；methyl 4-[[(4-dodecoxybenzoyl)amino]carbamoyl]benzoate
• CAS: 1361152-19-3
• 化学式: C₂₈H₃₈N₂O₅
• 分子量: 482.62
• InChiKey: IUIVZPOAFAAWNN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  35
• 可旋转键数：
  16
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  93.7
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  methyl 4-(2-(4-(dodecyloxy)benzoyl)hydrazinecarbonyl)benzoate 在 三氯氧磷 作用下， 反应 40.0h， 以34.1%的产率得到methyl 4-{5-[4-(dodecyloxy)phenyl]-1,3,4-oxadiazol-2-yl}benzoate
  参考文献：
  名称：

  Synthesis and Luminescence Properties of a Lollipop-Shaped Molecule Combined with Rod and Disc-Like Mesogens

  摘要：

  A novel lollipop-shaped molecule containing 1,3,4-oxadiazole moieties was designed and synthesized. The molecular structure of this 1,3,4-oxadiazole derivative was confirmed by FT-IR, H-1-NMR spectroscopy and elemental analyzer. Its phase behavior and mesomorphic property were investigated by DSC, POM and X-ray diffraction measurements. We found that this compound showed a typical mosaic texture of columnar phase during cooling run. The electron excitation and luminescence properties of this compound were investigated by UV-vis absorption spectroscopy and photo-luminescence spectroscopy both in CHCl3 solution and in solid state.

  DOI：

  10.1080/15421406.2011.600141
• 作为产物：
  描述：

  4-十二烷氧基苯甲酸乙酯 在 吡啶 、 一水合肼 作用下， 以 乙醇 、 dichlorometahne 为溶剂， 反应 52.0h， 生成 methyl 4-(2-(4-(dodecyloxy)benzoyl)hydrazinecarbonyl)benzoate
  参考文献：
  名称：

  Synthesis and Luminescence Properties of a Lollipop-Shaped Molecule Combined with Rod and Disc-Like Mesogens

  摘要：

  A novel lollipop-shaped molecule containing 1,3,4-oxadiazole moieties was designed and synthesized. The molecular structure of this 1,3,4-oxadiazole derivative was confirmed by FT-IR, H-1-NMR spectroscopy and elemental analyzer. Its phase behavior and mesomorphic property were investigated by DSC, POM and X-ray diffraction measurements. We found that this compound showed a typical mosaic texture of columnar phase during cooling run. The electron excitation and luminescence properties of this compound were investigated by UV-vis absorption spectroscopy and photo-luminescence spectroscopy both in CHCl3 solution and in solid state.

  DOI：

  10.1080/15421406.2011.600141

文献信息

• Synthesis and Luminescence Properties of a Lollipop-Shaped Molecule Combined with Rod and Disc-Like Mesogens
  作者：E-Joon Choi、Fei Xu、Jong-Ho Son、Wang-Cheol Zin

  DOI：10.1080/15421406.2011.600141

  日期：2011.11.4

  A novel lollipop-shaped molecule containing 1,3,4-oxadiazole moieties was designed and synthesized. The molecular structure of this 1,3,4-oxadiazole derivative was confirmed by FT-IR, H-1-NMR spectroscopy and elemental analyzer. Its phase behavior and mesomorphic property were investigated by DSC, POM and X-ray diffraction measurements. We found that this compound showed a typical mosaic texture of columnar phase during cooling run. The electron excitation and luminescence properties of this compound were investigated by UV-vis absorption spectroscopy and photo-luminescence spectroscopy both in CHCl3 solution and in solid state.