1,4-bis-propylamino-anthraquinone | 2475-40-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,4-bis-propylamino-anthraquinone
• 英文别名: 1,4-bis(n-propylamino)-9,10-anthraquinone；1,4-Bis-propylamino-anthrachinon；1,4-Bis(propyl-amino) anthraquinone；1,4-bis(propylamino)anthracene-9,10-dione
• CAS: 2475-40-3
• 化学式: C₂₀H₂₂N₂O₂
• 分子量: 322.407
• InChiKey: WPRQOPYKAPARST-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,4-二羟基蒽醌 以 乙腈 为溶剂， 反应 14.0h， 生成 1,4-bis-propylamino-anthraquinone
  参考文献：
  名称：

  Concerning the question of covalent bonding in hypericin-chromoproteins: Schiff base formation?

  摘要：

  Depending on the reaction conditions, peri-hydroxy substituted anthraquinones like 1,8-dihydroxyanthraquinone and 1,4-dihydroxyanthraquinone could be derivatized with ammonia, propylamine, isopropylamine, and a lysine derivative to yield a variety of imino and amino substitution and addition products. However, hypericin resisted such derivatization under a variety of reaction conditions. Therefore, the hypothesis that hypericin is bound to its apoprotein in photopigments via a Schiff base to the epsilon-amino group of a lysine residue or a terminal amino group seems to be rather unlikely.

  DOI：

  10.1007/bf00811317

文献信息

• Process of producing n-substitution products of 1, 4-diaminoanthraquinones
  申请人：GEN ANILINE WORKS INC

  公开号：US02051004A1

  公开（公告）日：1936-08-11
• Naiki, Yuki Gosei Kagaku Kyokaishi, 1954, vol. 12, p. 364,366
  作者：Naiki

  DOI：——

  日期：——
• USE OF ANTHRAQUINONE DYES AND OF FLUORESCENT DYES FOR DYEING KERATIN FIBRES, DYEING PROCESS AND COMPOSITION
  申请人：L'Oréal

  公开号：EP3558235B1

  公开（公告）日：2021-09-08
• JPS5852201A
  申请人：——

  公开号：JPS5852201A

  公开（公告）日：1983-03-28
• [EN] USE OF ANTHRAQUINONE DYES AND OF FLUORESCENT DYES FOR DYEING KERATIN FIBRES, DYEING PROCESS AND COMPOSITION<br/>[FR] UTILISATION DE COLORANTS ANTHRAQUINONIQUES ET DE COLORANTS FLUORESCENTS DESTINÉS À LA COLORATION DE FIBRES KÉRATINIQUES, PROCÉDÉ ET COMPOSITION DE COLORATION
  申请人：OREAL

  公开号：WO2018115337A1

  公开（公告）日：2018-06-28

  Use of anthraquinone dyes and of fluorescent dyes for dyeing keratin fibres, dyeing process and composition The present invention relates to a process for dyeing keratin fibres,in particular human keratin fibres such as the hair, using a) one or more particular anthraquinone dyes and b) one or more fluorescent direct dyes; to a composition comprising a) and b). The present invention also relates to a multi-compartment device containing the compounds defined above.