9-oxo-9H-thioxanthen-1-carboxylic acid-(2-acryloyloxyethyl ester) | 161470-88-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫色烯
• 英文名称: 9-oxo-9H-thioxanthen-1-carboxylic acid-(2-acryloyloxyethyl ester)
• 英文别名: 2-Prop-2-enoyloxyethyl 9-oxothioxanthene-1-carboxylate
• CAS: 161470-88-8
• 化学式: C₁₉H₁₄O₅S
• 分子量: 354.383
• InChiKey: ZVMGIUDYBOKQOI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  25
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  95
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  3-硝基邻苯二甲酸酐 在 aluminum (III) chloride 、 偶氮二甲酸二异丙酯 、 乙酸酐 、 溶剂黄146 、 三苯基膦 、 sodium hydroxide 作用下， 以 乙醇 、 水 、 二甲基亚砜 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 63.0h， 生成 9-oxo-9H-thioxanthen-1-carboxylic acid-(2-acryloyloxyethyl ester)
  参考文献：
  名称：

  Radiation curable compositions

  摘要：

  根据公式(I)的可聚合的Norrish II型光引发剂：含有公式(I)的可聚合Norrish II型光引发剂的辐射固化组合物和喷墨墨水表现出与辐射固化组合物和喷墨墨水的更好兼容性和溶解性，并且在固化后显示出光引发剂及其残留物的可萃取量较低。

  公开号：

  US08536217B2

文献信息

• RADIATION CURABLE COMPOSITIONS
  申请人：Loccufier Johan

  公开号：US20110159203A1

  公开（公告）日：2011-06-30

  A polymerizable Norrish Type II photoinitiator according to Formula (I): . Radiation curable compositions and inkjet inks containing the polymerizable Norrish Type II photoinitiator of Formula (I) exhibit improved compatibility with and solubility in radiation curable compositions and inkjet inks, and exhibit low extractable amounts of the photoinitiator and its residues after curing.

  根据公式（I）的聚合性诺里希II型光引发剂： . 含有公式（I）的聚合性诺里希II型光引发剂的辐射固化组合物和喷墨油墨在辐射固化组合物和喷墨油墨中表现出优异的相容性和溶解性，并且在固化后光引发剂及其残留物的可提取量较低。
• [EN] POLYMERIZABLE PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS<br/>[FR] PHOTOINITIATEURS POLYMÉRISABLES ET COMPOSITIONS DURCISSABLES PAR RAYONNEMENTS
  申请人：AGFA GRAPHICS NV

  公开号：WO2010029017A1

  公开（公告）日：2010-03-18

  A new type of polymerizable Norrish Type II photoinitiators having an optionally substituted benzophenone group or an optionally substituted thioxanthone group is disclosed exhibiting improved compatibility with and solubility in radiation curable compositions. Radiation curable compositions and inkjet inks containing these polymerizable Norrish Type Il photoinitiators, exhibiting low extractable amounts of the photoinitiators and their residues after curing, are also disclosed.

  本文披露了一种新型可聚合的Norris Type II光引发剂，其具有可选取代的苯基酮基团或可选取代的噻吩酮基团，表现出与辐射固化组合物的改进兼容性和溶解性。同时还披露了含有这些可聚合Norris Type II光引发剂的辐射固化组合物和喷墨墨水，这些光引发剂及其残留物在固化后的萃取量较低。
• POLYMERIZABLE PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS
  申请人：Loccufier Johan

  公开号：US20110195198A1

  公开（公告）日：2011-08-11

  A polymerizable Norrish Type II photoinitiators includes an optionally substituted benzophenone group or an optionally substituted thioxanthone group exhibiting improved compatibility with and solubility in radiation curable compositions. Radiation curable compositions and inkjet inks can contain these polymerizable Norrish Type II photoinitiators, exhibiting low extractable amounts of the photoinitiators and their residues after curing.

  一种可聚合的Norrish二型光引发剂，包括一个可选取的取代苯基酮基团或一个可选取的取代噻吩酮基团，表现出与辐射可固化组合物的良好相容性和溶解性。这些可聚合的Norrish二型光引发剂可用于辐射可固化组合物和喷墨油墨中，固化后其光引发剂和残留物的可提取量较低。
• CHANGING SURFACE PROPERTIES BY FUNCTIONALIZED NANOPARTICLES
  申请人：Giesenberg Thomas

  公开号：US20100178512A1

  公开（公告）日：2010-07-15

  A process for modifying the surface of an inorganic or organic substrate with strongly adherent nanoparticles is described, providing to the surface modified substrate durable effects like hydrophobicity, hydrophilicity, electrical conductivity, magnetic properties, flame retardance, color, adhesion, roughness, scratch resistance, UV-absorbance, antimicrobial properties, antifouling properties, antiprotein properties, antistatic properties, antifog properties, release properties. In this process, an optional first step a) a low-temperature plasma, ozonization, high energy irradiation, corona discharge or a flame is caused to act on the inorganic or organic substrate, and in a second step b) one or more defined nanoparticles or mixtures of defined nanoparticles with monomers, containing at least one ethylenically unsaturated group, or solutions, suspensions or emulsions of the afore-mentioned substances, are applied, preferably at normal pressure, to the inorganic or organic substrate. In a third step c) suitable methods are applied to dry or cure those afore-mentioned substances and, optionally, in a fourth step d) a further coating is applied on the substrate so pretreated.

  本文描述了一种用强附着力纳米颗粒改性无机或有机基底表面的方法，使表面改性后的基底具有耐久性效果，如疏水性、亲水性、电导性、磁性、防火性、颜色、附着力、粗糙度、抗刮擦性、UV吸收性、抗菌性、防污性、抗蛋白质性、抗静电性、防雾性和释放性。在此过程中，第一步（可选）是在无机或有机基底上施加低温等离子体、臭氧化、高能辐射、电晕放电或火焰，第二步（b）是将一个或多个定义的纳米颗粒或定义的纳米颗粒与至少一个乙烯基未饱和基团的单体，或上述物质的溶液、悬浮液或乳液，应用于无机或有机基底上，最好是在常压下进行。第三步（c）是应用适当的方法干燥或固化上述物质，可选地，在第四步（d）中在预处理的基底上施加进一步的涂层。
• Silicon coated release substrate
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1772479A1

  公开（公告）日：2007-04-11

  Subject of the invention is a process for the preparation of a silicon release-layer on an inorganic or organic substrate, wherein a pretreated substrate is first covered with an adhesion promoting composition and subsequently a silicon and/or fluorine containing composition is applied as the top layer.

  本发明的主题是在无机或有机基底上制备硅释放层的工艺，其中首先在预处理过的基底上覆盖一层增粘组合物，然后将含硅和/或氟的组合物作为面层使用。