4-氯-9H-噻吨-9-酮 | 21908-85-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫色烯
• 中文名称: 4-氯-9H-噻吨-9-酮
• 英文名称: 4-Chlor-thioxanthen-9-on
• 英文别名: 4-Chlor-thioxanthon；4-chlorothioxanthen-9-one；4-chloro-9H-thioxanthen-9-one；4-chlorothioxanthone
• CAS: 21908-85-0
• 化学式: C₁₃H₇ClOS
• 分子量: 246.717
• InChiKey: SGSKTOKJZHJRCN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  42.4
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2932999099

反应信息

• 作为反应物：
  描述：

  4-氯-9H-噻吨-9-酮 在 双氧水 、 溶剂黄146 作用下， 生成 4-chloro-10,10-dioxo-10λ6-thioxanthen-9-one
  参考文献：
  名称：

  Mahishi et al., Journal of the Karnatak University, 1957, vol. 2, p. 50,57

  摘要：

  DOI：
• 作为产物：
  描述：

  邻氯苯硫酚 在 硫酸 、 sodium methylate 、 铜 作用下， 生成 4-氯-9H-噻吨-9-酮
  参考文献：
  名称：

  Mahishi et al., Journal of the Karnatak University, 1957, vol. 2, p. 50,57

  摘要：

  DOI：

文献信息

• COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND AN ELECTRONIC DEVICE THEREOF
  申请人：DUK SAN NEOLUX CO., LTD.

  公开号：US20210147397A1

  公开（公告）日：2021-05-20

  The present invention provides a novel compound that can improve the luminous efficiency, stability and life span of the element, an organic electronic element using the same, and an electronic device thereof.

  本发明提供了一种新型化合物，可以提高元素的发光效率、稳定性和寿命，使用该化合物的有机电子元件，以及其电子设备。
• Process for preparing thioxanthones
  申请人：The Sherwin-Williams Company

  公开号：US04101558A1

  公开（公告）日：1978-07-18

  This invention is directed to a process of preparing thioxanthones derived from ortho-chlorosulfenylbenzoyl chloride and aromatic compounds in the presence of Friedel-Crafts catalyst.

  本发明涉及一种在Friedel-Crafts催化剂存在下，利用ortho-氯硫代苯甲酰氯和芳香族化合物制备硫代黄酮的方法。
• Process for the preparation of thioxanthones
  申请人：——

  公开号：US20030229233A1

  公开（公告）日：2003-12-11

  Processes are described for the preparation of thioxanthones (Formula I). A reactant mixture of a 2-chlorothiobenzoyl chloride (Formula II) and an aromatic compound (Formula III) is added to a slurry of a Friedel-Crafts catalyst in an organic Friedel-Crafts solvent. Products of the processes may be used for the preparation of a pharmaceutical product for use in the field of psycho-therapeutics, or as activators or sensitizers in the photo-polymerization of ethylenically unsaturated monomers. 1

  本文描述了制备噻吲酮（式I）的过程。将2-氯硫代苯甲酰氯（式II）和芳香族化合物（式III）的反应混合物加入有机Friedel-Crafts溶剂中的Friedel-Crafts催化剂浆中。该过程的产物可用于制备用于心理治疗领域的制药产品，或作为乙烯基不饱和单体的光聚合活化剂或敏化剂。
• Energy-curable composition for making a pressure sensitive adhesive
  申请人：——

  公开号：US20030069323A1

  公开（公告）日：2003-04-10

  An energy-curable polymer-forming composition for making a pressure sensitive adhesive includes an unsaturated oligomer resin and an adhesive promoter which increases the peel strength of the adhesive without reducing its tack. The composition also includes a tackifier and various other optional components such as photoinitiator, chain extender, reactive diluent and the like.

  一种用于制造压敏胶的可固化聚合物形成组合物，包括不饱和低聚物树脂和一种粘合促进剂，该促进剂可以增加胶粘剂的剥离强度而不降低其粘性。该组合物还包括粘合剂和各种其他可选组分，例如光引发剂、链延长剂、反应性稀释剂等。
• Sensitisation and stabilisation of organometallic compounds acting as photocatalysts and photosensitisers in photochemical radical polymerisation process
  申请人：CHIMIA PRODOTTI E PROCESSI SRL

  公开号：EP0421512A1

  公开（公告）日：1991-04-10

  Object of the present invention is a radical polymerisation process of compounds containing carbon-carbon double bonds, carried out either photochemically, by means of visible or ultraviolet radiation, or by electron beams, employing at least one organometallic compound in which coordinated central atom is a transition element and ligands are coordinated to central atom by means of at least one element including C,N,P,As,Sb,O,S,Se,Te,B, and/or as elements in the form of the simple uninegative ions H,F,Cl,Br,I, and also employing preferably at least one photosensitizer of some type already known. Object of the present invention is also a chemical stabilisation process for photocatalytic systems above, and particularly for those containing central ion in a high oxidation or relatively unstable state. This process is based on a suitable preparative method of the photocatalytic system, and/or on the addition of small amounts of compounds (mostly Lewis acids or bases), able to impart to the resulting composition a sufficiently lasting stability and efficiency, to the purpose of the present patent.

  本发明的目的是含碳碳双键化合物的自由基聚合工艺，该工艺通过可见光或紫外线辐射或电子束以光化学方式进行、采用至少一种有机金属化合物，其中配位中心原子为过渡元素，配体通过至少一种元素与中心原子配位，这些元素包括 C、N、P、As、Sb、O、S、Se、Te、B 和/或以简单的非负离子 H、F、Cl、Br、I 形式存在的元素，最好还采用至少一种已知类型的光敏剂。 本发明的目的还在于上述光催化系统的化学稳定工艺，特别是那些含有处于高氧化态或相对不稳定态的中心离子的光催化系统。该工艺基于光催化系统的适当制备方法，和/或基于添加少量化合物（主要是路易斯酸或碱），这些化合物能够赋予所产生的组合物足够持久的稳定性和效率，从而达到本专利的目的。