4,4'-bis[(4-diethylaminosalicylaldehyde)diphenyl methane]diimine | 413580-08-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-bis[(4-diethylaminosalicylaldehyde)diphenyl methane]diimine
• 英文别名: 5-(Diethylamino)-2-[[4-[[4-[[4-(diethylamino)-2-hydroxyphenyl]methylideneamino]phenyl]methyl]phenyl]iminomethyl]phenol
• CAS: 413580-08-2
• 化学式: C₃₅H₄₀N₄O₂
• 分子量: 548.728
• InChiKey: VUNQURLNNOHSFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  41
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  71.7
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  cadmium(II) perchlorate hexahydrate 、 4,4'-bis[(4-diethylaminosalicylaldehyde)diphenyl methane]diimine 以 乙醇 、 甲苯 为溶剂， 以71.45%的产率得到
  参考文献：
  名称：

  Synthesis, Spectroscopic, and Electrochemical Characterization of a Schiff Base: 4,4′-bis[(4- diethylaminosalicylaldehyde)diphenyl methane]diimine and Its Complexes With Copper(II), Cobalt(II), and Cadmium(II)

  摘要：

  The synthesis of a new ligand tetradentate Schiff base: 4,4'-bis[(4-diethyl aminosalicylaldehyde) diphenyl methane] diimine (H2L), obtained by condensation of 4,4'-diaminodiphenyl methane with 4-diethylaminosalicylaldehyde, and its complexes with copper(II), cobalt(II) and cadmium(II), is described. The metal complexes were characterized by elemental analysis, by UV-visible, infrared, and EPR spectroscopy, by cyclic voltammetry, and by thermal analysis (DTA-TG). The coordination of the metal ions to the ligand occurs through the N2O2 system. Thermal studies indicate that the ligand is more stable than the metal complexes (up to 310 degrees C).

  DOI：

  10.1080/15533174.2011.614993
• 作为产物：
  描述：

  4-(二乙氨基)水杨醛 、 4,4'-二氨基二苯甲烷 以 甲醇 为溶剂， 反应 6.0h， 以75%的产率得到4,4'-bis[(4-diethylaminosalicylaldehyde)diphenyl methane]diimine
  参考文献：
  名称：

  A dipodal molecular probe for naked eye detection of trivalent cations (Al³⁺, Fe³⁺and Cr³⁺) in aqueous medium and its applications in real sample analysis and molecular logic gates

  摘要：

  设计并合成了一种双极可逆的比色三价金属离子化学传感器（L）。该化学传感器L成功地基于结合位点-信号方法检测铝（Al³⁺）、铁（Fe³⁺）和铬（Cr³⁺），并具有实际应用价值。

  DOI：

  10.1039/c8ra07041e

文献信息

• Fluorescent primary sensor for zinc and resultant complex as secondary sensor towards phosphorylated biomolecules: INHIBIT logic gate
  作者：Kamalpreet Kaur、Vimal K. Bhardwaj、Navneet Kaur、Narinder Singh

  DOI：10.1016/j.ica.2012.12.030

  日期：2013.4

  Imine linked "on-off" multi-responsive and selective chemosensor has been synthesized and evaluated for cation recognition properties. The receptor shows high sensitivity and selectivity for Zn2+ through changes in fluorescence intensity based on ESIPT and charge transfer (CT) mechanism. The Zn2+ complex of the receptor can be used for phosphate quantification and for recognition of phosphorylated biomolecules through cation displacement approach. (C) 2013 Elsevier B.V. All rights reserved.
• A dipodal molecular probe for naked eye detection of trivalent cations (Al³⁺, Fe³⁺and Cr³⁺) in aqueous medium and its applications in real sample analysis and molecular logic gates
  作者：Rukmani Chandra、Amit Kumar Manna、Kalyani Rout、Jahangir Mondal、Goutam K. Patra

  DOI：10.1039/c8ra07041e

  日期：——

  A dipodal reversible colorimetric trivalent metal ion chemosensor (L) has been designed and synthesized. The chemosensor L successfully detects Al³⁺, Fe³⁺ and Cr³⁺ based on binding site-signaling approach and it has practical application.

  设计并合成了一种双极可逆的比色三价金属离子化学传感器（L）。该化学传感器L成功地基于结合位点-信号方法检测铝（Al³⁺）、铁（Fe³⁺）和铬（Cr³⁺），并具有实际应用价值。
• Synthesis, Spectroscopic, and Electrochemical Characterization of a Schiff Base: 4,4′-bis[(4- diethylaminosalicylaldehyde)diphenyl methane]diimine and Its Complexes With Copper(II), Cobalt(II), and Cadmium(II)
  作者：Sonia Benabid、Tahar Douadi、Houria Debab、Marc De Backer、François-Xavier Sauvage

  DOI：10.1080/15533174.2011.614993

  日期：2012.1.1

  The synthesis of a new ligand tetradentate Schiff base: 4,4'-bis[(4-diethyl aminosalicylaldehyde) diphenyl methane] diimine (H2L), obtained by condensation of 4,4'-diaminodiphenyl methane with 4-diethylaminosalicylaldehyde, and its complexes with copper(II), cobalt(II) and cadmium(II), is described. The metal complexes were characterized by elemental analysis, by UV-visible, infrared, and EPR spectroscopy, by cyclic voltammetry, and by thermal analysis (DTA-TG). The coordination of the metal ions to the ligand occurs through the N2O2 system. Thermal studies indicate that the ligand is more stable than the metal complexes (up to 310 degrees C).