N,N'-(((methylenebis(4,1-phenylene))bis(azanediyl))bis(carbonyl))bis(4-methylbenzenesulfonamide) | 151882-81-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-(((methylenebis(4,1-phenylene))bis(azanediyl))bis(carbonyl))bis(4-methylbenzenesulfonamide)
• 英文别名: Benzenesulfonamide, N,N'-(methylenebis(4,1-phenyleneiminocarbonyl))bis(4-methyl-；1-(4-methylphenyl)sulfonyl-3-[4-[[4-[(4-methylphenyl)sulfonylcarbamoylamino]phenyl]methyl]phenyl]urea
• CAS: 151882-81-4
• 化学式: C₂₉H₂₈N₄O₆S₂
• 分子量: 592.697
• InChiKey: XVSRGZPKJKLORS-UHFFFAOYSA-N

物化性质

• 熔点：
  161 - 163°C
• 密度：
  1.396±0.06 g/cm3(Predicted)
• 溶解度：
  DMSO（微溶）、甲醇（微溶、超声处理）

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  41
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  167
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  对甲苯磺酰氯 在 sodium azide 、 palladium diacetate 作用下， 以 水 、 乙腈 为溶剂， 20.0 ℃ 、2.0 kPa 条件下， 反应 0.33h， 生成 N,N'-(((methylenebis(4,1-phenylene))bis(azanediyl))bis(carbonyl))bis(4-methylbenzenesulfonamide)
  参考文献：
  名称：

  产品衍生的双金属钯络合物催化磺酰叠氮化物的直接羰基化

  摘要：

  源自产物的新型双金属钯络合物可催化与σ-供体/π-受体配体CO进行磺酰叠氮化物转移反应，并且由于其广泛的底物范围，高效率和温和的反应条件（CO在室温下为大气压）而具有优势）。这种方法为药物和农用化学品中都存在的磺酰脲类提供了一种新方法。以克为单位的格列本脲的合成进一步揭示了该方法的实用性。从机理上讲，衍生自磺酰脲产物的桥接双金属钯物质的生成被公开为该催化循环的关键步骤。

  DOI：

  10.1002/anie.201600887

文献信息

• RECORDING MATERIAL PRODUCED USING NON-PHENOL COMPOUND
  申请人：NIPPON SODA CO., LTD.

  公开号：US20150284321A1

  公开（公告）日：2015-10-08

  An object of the present invention is to provide a recording material or a recording sheet using, as a color-developing agent, a non-phenol compound that is a safe compound in no danger of corresponding to an endocrine disruptor and is good in color developing performance. The non-phenol compound used in the present invention is at least one selected from the group consisting of compounds represented by the following formulas (I) to (III).

  本发明的目的是提供一种使用非酚类化合物作为显色剂的记录材料或记录纸，该非酚类化合物是一种安全化合物，不会对应到内分泌干扰物，并且在显色性能方面表现良好。本发明中使用的非酚类化合物至少选自以下化合物所代表的化合物组，其化学式为(I)至(III)。
• COLOR DEVELOPING COMPOSITION CONTAINING MOLECULAR COMPOUND, AND RECORDING MATERIAL
  申请人：Kodama Satoshi

  公开号：US20110120345A1

  公开（公告）日：2011-05-26

  Provided is a color-developing composition containing a molecular compound which has as a component compound a compound represented by formula (I) [wherein Y represents a C1-C12 hydrocarbon group which is chained or branched and saturated or unsaturated, or a C1-C8 hydrocarbon group which is chained or branched, saturated or unsaturated and has an ether or thioether bond; R 1 , R 2 , R 3 and R 4 each independently represent a C1-C6 alkyl group or C2-C6 alkenyl group; n, p, q and r each represents any integer of 0 to 4; and m represents any integer of 0 to 2]. Also provided is a recording material with a sufficient color-forming sensitivity, superior storage stability, and especially with an extremely little background fogging in a heat resistance test.

  提供的是一种含有分子化合物的彩色显影组合物，该分子化合物的组分包括由式（I）表示的化合物[其中Y表示链状或支链的C1-C12烃基，饱和或不饱和，或链状或支链的C1-C8烃基，饱和或不饱和，且具有醚或硫醚键；R1、R2、R3和R4各自独立地表示C1-C6烷基或C2-C6烯基；n、p、q和r各自表示0至4的任意整数；m表示0至2的任意整数]。还提供了一种具有足够的显色敏感性、优异的储存稳定性，特别是在耐热性测试中具有极少背景雾化的记录材料。
• Process for the manufacture of 3-dibutylamino-6-methyl-7-anilinofluoran
  申请人：BASF SE

  公开号：EP2289896A1

  公开（公告）日：2011-03-02

  A process for the preparation of 3-dibutylamino-6-methyl-7-anilinofluoran and a heating- and pressure sensitive recording material are claimed.

  本发明涉及制备3-二丁基氨基-6-甲基-7-苯胺基荧光素以及一种热敏感的记录材料的方法。
• Phenolic compound and recording material containing the same
  申请人：Hidaka Tomoya

  公开号：US20050096222A1

  公开（公告）日：2005-05-05

  An object of the present invention is to provide a novel phenolic compound, and a recording material containing the same, which is excellent in storage stability. The object can be achieved by a phenolic compound represented by the formula (I): [wherein m represents an integer of 0 to 2; R 1 and R 2 each independently represents a C1-C6 alkyl group or a C1-C6 alkoxy group; p and q each independently represents an integer of 0 to 4; t and u each independently represents 0 or 1 and do not simultaneously represent 0; and X represents a group represented by any of the formulas (II) to (VII): (wherein R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 each independently represents a hydrogen atom or a C1-C6 alkyl group; a represents an integer of 1 to 6; b represents an integer of 0 to 4; and c represents an integer of 0 to 6)] and a recording material containing the same.

  本发明的目的是提供一种新的酚类化合物和含有该化合物的记录材料，其具有良好的储存稳定性。所述目的可以通过由式（I）表示的酚类化合物实现：[其中，m表示0到2的整数；R1和R2各自独立地表示C1-C6烷基或C1-C6烷氧基；p和q各自独立地表示0到4的整数；t和u各自独立地表示0或1且不同时表示0；X表示由式（II）到（VII）中任意一种表示的基团：[其中，R3、R4、R5、R6、R7、R8、R9、R10和R11各自独立地表示氢原子或C1-C6烷基；a表示1到6的整数；b表示0到4的整数；c表示0到6的整数]，以及含有该化合物的记录材料。
• HEAT-SENSITIVE RECORDING MATERIAL
  申请人：Mitsubishi HiTec Paper Europe GmbH

  公开号：US20200369062A1

  公开（公告）日：2020-11-26

  A heat-sensitive recording material including a substrate, a heat-sensitive recording layer which includes N-(4-methylphenylsulfonyl)-/V-(3-(4-methylphenylsulfonyloxy)pheny-purea and/or N42-(3-phenylureido)phenyl]benzol sulfonamide, and an intermediate layer which is arranged between the substrate and the heat-sensitive recording layer and which includes calcined aluminum silicate, and a method for producing a heat-sensitive recording material and to the use of calcined aluminum silicate in an intermediate layer of a heat-sensitive recording material.

  一种热敏记录材料，包括基材、热敏记录层和中间层。其中，热敏记录层包括N-(4-甲基苯基磺酰基)-/V-(3-(4-甲基苯基磺酰氧基)苯基)脲和/或N42-(3-苯基脲基)苯基]苯磺酰胺。中间层位于基材和热敏记录层之间，包括煅烧铝硅酸盐。还提供了一种制备热敏记录材料的方法，并且在热敏记录材料的中间层中使用了煅烧铝硅酸盐。