1,11-Diamino-4,8-dithiaundecane | 65755-73-9

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 1,11-Diamino-4,8-dithiaundecane
• 英文别名: 3-[3-(3-Aminopropylsulfanyl)propylsulfanyl]propan-1-amine
• CAS: 65755-73-9
• 化学式: C₉H₂₂N₂S₂
• 分子量: 222.419
• InChiKey: SKSDMPDHPIUATK-UHFFFAOYSA-N

物化性质

• 沸点：
  364.5±37.0 °C(Predicted)
• 密度：
  1.047±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  13
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  103
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,11-Diamino-4,8-dithiaundecane 生成 N,N'-(4,8-dithia-undecanediyl)-bis-acetamide
  参考文献：
  名称：

  Sexadentate Chelate Compounds. III¹

  摘要：

  DOI：

  10.1021/ja01136a068
• 作为产物：
  描述：

  N,N'-(4,8-dithia-undecanediyl)-bis-phthalimide 在 乙醇 、 一水合肼 作用下， 生成 1,11-Diamino-4,8-dithiaundecane
  参考文献：
  名称：

  Sexadentate Chelate Compounds. III¹

  摘要：

  DOI：

  10.1021/ja01136a068

文献信息

• Chautemps, Pierre; Gellon, Gisele; Morin, Benedicte, Bulletin de la Societe Chimique de France, 1994, vol. 131, # 4, p. 434 - 443
  作者：Chautemps, Pierre、Gellon, Gisele、Morin, Benedicte、Pierre, Jean-Louis、Provent, Christophe、et al.

  DOI：——

  日期：——
• Preparation and cation complexing properties of some macropolycyclic ligands
  作者：Krzysztof E. Krakowiak、Jerald S. Bradshaw、N. Kent Dalley、Chengyue Zhu、Guoliang Yi、Janet C. Curtis、Du Li、Reed M. Izatt

  DOI：10.1021/jo00037a038

  日期：1992.5

  Five new cryptands have been prepared by a 2:1 cyclocondensation of an alpha,omega-dihalide with an alpha,omega-diamine. In some cases, other products, such as bis(aza-12-crown-4) ligands and products of a 4:2 cyclocondensation, were isolated also. The structures of the cryptands and bis(aza-crown)s of the game molecular weight were established after careful analysis by C-13 NMR and X-ray spectroscopy and a few independent syntheses of the bis(aza-crown) ethers. A new TLC test has been developed to distinguish between the cryptands and the bis(aza-crown)s. Log K values for the interaction of two cryptands, each containing two propylene bridges in one arm, with various cations were determined. The results show a much weaker interaction of the cryptands containing two propylene bridges with various cations than that for the corresponding cryptands with only ethylene bridges. The most stable complexes of these new propylene-containing cryptands were those involving Ba2+ and Sr2+ ions. X-ray analyses of three cryptands, each of which has the [18]N2O4 macrocycle as part of its structure, show different organizations for the ring heteroatoms.
• Tul'chinskii, M. L.; Ostapchuk, P. N.; Strel'tsova, N. R., Journal of general chemistry of the USSR, 1991, vol. 61, # 1.2, p. 179 - 184
  作者：Tul'chinskii, M. L.、Ostapchuk, P. N.、Strel'tsova, N. R.、Frolov, A. B.、Bel'skii, V. K.、Tsivadze, A. Yu.

  DOI：——

  日期：——
• A new method to extend dimercaptan or diamine chains with aminopropyl units using 3-bromo-N-tritylpropanamine
  作者：Krzysztof E. Krakowiak、Peter Huszthy、Jerald S. Bradshaw、Reed M. Izatt

  DOI：10.1016/s0040-4039(00)71207-x

  日期：1991.1

  Dimercaptans and diamines react with 3-bromo-N-tritylpropanamine to give the corresponding N,N'-ditrityldithia and N,N'-ditritylpolyaza compounds in yields of 50-80%. The trityl protecting groups are readily removed in acid. These reactions make possible the synthesis of a number of new alpha-omega-diamino compounds needed for the synthesis of new dithiadiaza, di- and polyaza macrocyclic ligands.
• Sexadentate Chelate Compounds. III¹
  作者：Francis P. Dwyer、Naida S. Gill、Eleonora C. Gyarfas、Francis Lions

  DOI：10.1021/ja01136a068

  日期：1952.8