tridecanediyl diisocyanate | 24019-17-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tridecanediyl diisocyanate
• 英文别名: Tridecandiyldiisocyanat；1,13-Diisocyanatotridecane
• CAS: 24019-17-8
• 化学式: C₁₅H₂₆N₂O₂
• 分子量: 266.384
• InChiKey: HKXZZVNHTYMJPQ-UHFFFAOYSA-N

物化性质

• 沸点：
  155-160 °C(Press: 0.040 Torr)
• 密度：
  0.95±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  19
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  58.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tridecanediyl diisocyanate 在 氨 、 水 、 丙酮 作用下， 生成 N,N''-tridecanediyl-di-urea
  参考文献：
  名称：

  Iwakura et al., Nippon Kagaku Zasshi, 1957, vol. 78, p. 1504

  摘要：

  DOI：
• 作为产物：
  描述：

  癸二酸氢乙酯 在 盐酸 、 甲醇 、 乙醇 、 sodium 、 一水合肼 、 sodium nitrite 作用下， 生成 tridecanediyl diisocyanate
  参考文献：
  名称：

  Iwakura et al., Nippon Kagaku Zasshi, 1957, vol. 78, p. 1504

  摘要：

  DOI：

文献信息

• Release sustaining composition and sustained release preparation
  申请人：Hayakawa Kazuhisa

  公开号：US20050147676A1

  公开（公告）日：2005-07-07

  A release sustaining composition comprising a polyalkylene polyol derivative comprising repeating units U-1 derived from a water-soluble polyalkylene polyol and a polyisocyanate and repeating units U-2 derived from a dihydroxy compound and a polyisocyanate in a molar ratio of U-1/U-2 between 0.5/0.5 and 0.99/0.01 and optionally a water-soluble cellulose ether is combined with an active ingredient to make a sustained release preparation.

  一种持续释放组合物，包括由可溶于水的聚烯烃聚醚和聚异氰酸酯衍生的重复单元U-1以及由二羟基化合物和聚异氰酸酯衍生的重复单元U-2，在U-1/U-2的摩尔比在0.5/0.5至0.99/0.01之间，可选地与可溶于水的纤维素醚结合，用于制备持续释放制剂。
• PREPARATION OF POLYISOCYANATES OF THE TRIMER TYPE
  申请人：Richter Frank

  公开号：US20090234091A1

  公开（公告）日：2009-09-17

  The invention relates to the use of heterocycles containing trivalent phosphorus as a ring member as catalysts for isocyanate modification and to a process for preparing polyisocyanates of the trimer type.

  本发明涉及将含有三价磷的杂环作为催化剂用于异氰酸酯改性，并涉及制备三聚体型聚异氰酸酯的过程。
• Extended polyurethanes
  申请人：COMMUNICATIONS TECHNOLOGY CORPORATION

  公开号：EP0046063A1

  公开（公告）日：1982-02-17

  Polyalphaolefin extended polyurethane systems comprising a reaction product of an isocyanate terminated polyisocyanate with a polyol and, optionally, a liquid ester coupling agent, are characterised in that the reaction is conducted in the presence of a polyalphaolefin derived from dec-1-ene. The systems although usable as general polyurethane elastomers are particularly useful as encapsulants and especially as reenterable encapsulants for sealing insulated electrical devices, since the presence of the polyalphaolefin gives a low-viscosity, low-volatility injectable resin which does not exude the polyalphaolefin when cured.

  聚α烯烃扩展聚氨酯体系包括异氰酸酯封端的聚异氰酸酯与多元醇以及液态酯偶联剂的反应产物，其特征在于反应是在癸-1-烯衍生的聚α烯烃存在下进行的。这些体系虽然可以用作一般的聚氨酯弹性体，但尤其可以用作封装剂，特别是用作密封绝缘电气设备的可再进入封装剂，因为聚α烯烃的存在可以产生一种低粘度、低挥发性的可注射树脂，在固化时不会渗出聚α烯烃。
• Coating compositions and polyhydroxy oligomer precursors therefor
  申请人：FORD MOTOR COMPANY LIMITED

  公开号：EP0086308A1

  公开（公告）日：1983-08-24

  A novel polyhydroxy oligomer crosslinkable with aminoplast resins to form a coating composition adapted for use as an automotive topcoat which upon curing forms a hard, glossy, durable coating with outstanding durability and excellent resistance to solvents and water. The coating composition comprises: (A) a polyhydroxy oligomer having a number average (Mn) molecular weight of between about 250-2000 and being the reaction produce of: (i) an ester having pendant hydroxyl and carboxyl functionality and being made by reacting (a) a C3-Clo aliphatic branched diol, and (b) an alkyl hexahydrophthalic anhydride, wherein (a) and (b) are combined in the reactant mixture in an amount sufficient to allow reaction in at least about a 1:1 molar ratio; and (ii) a C2-C10 monomer, having reactive functionality capable of esterifying said carboxyl functionalilty of said ester, said C2-C10 monomer being selected from the group consisting of: (a) a monomer wherein said reactive functionality reacts with said carboxyl functionality to form an hydroxy in addition to an ester linkage; (b) a monomer bearing hydroxyl functionality in addition to said reactive functionality and wherein said reactive functionality does not generate an hydroxy in addition to an ester linkage; and (c) a monomer bearing hydroxyl functionality in addition to said reactive functionality wherein said reactive functionality reacts with said carboxyl functionality to form a hydroxyl in addition to an ester linkage, wherein said ester and said C.-C1o monomer are combined in the reactant mixture in an amount sufficient to allow reaction in about a 1:1 molar ratio; (B) an amine-aldehyde or polyisocyanate crosslinking agent; and (C) 0-50 weight percent based on the total weight of (A), (B) and (C) of hydroxy functional additive having a number average molecular weight (Mn) of between about 150-6000, In addition, the coating composition of this invention may include conventional additives such as catalysts, antioxidants, U.V. absorbers, flow control or wetting agents, antistatic agents, pigments, plasticiers, solvents, etc. The oligomers of this composition are also compatible with non- agueous dispersions (NAD's).

  一种可与氨基树脂交联的新型聚羟基低聚物，可形成一种用作汽车面漆的涂料组合物，固化后可形成坚硬、有光泽、耐用的涂层，具有出色的耐久性和优异的耐溶剂和耐水性。该涂料组合物包括 (A) 聚羟基低聚物，其平均（Mn）分子量在 250-2000 之间，是下列物质的反应产物： (B) 聚羟基低聚物，其平均（Mn）分子量在 250-2000 之间： (i) 具有羟基和羧基官能团的酯，由以下物质反应生成 (a) C3-Clo 脂肪族支链二元醇，和 (b) 烷基六氢邻苯二甲酸酐，其中(a)和(b)在反应物混合物中的结合量足以使反应至少以大约 1:1 的摩尔比进行；以及 (ii) C2-C10 单体，具有可将所述酯的羧基官能团酯化的反应性官能团，所述 C2-C10 单体选自以下组成的组： (a) 单体，其中所述活性官能团与所述羧基官能团反应，除形成酯连接外，还形成羟基； (b) 除所述反应性官能团外还含有羟基官能团的单体，其中所述反应性官能团除 酯键外不产生羟基；及 (c) 除所述反应性官能团外还含有羟基官能团的单体，其中所述反应性官能团与所述羧基官能团反应以形成除酯连接外的羟基，其中所述酯和所述 C.-C1o 单体在反应物混合物中的结合量足以使反应以约 1:1 的摩尔比进行； (B) 一种胺-醛或多异氰酸酯交联剂；以及 (C) 以(A)、(B)和(C)的总重量为基准，0-50%、 (B)和(C)总重量的 0-50%的羟基官能团添加剂，其平均分子量(Mn)约为 150-6000、 此外，本发明的涂料组合物还可包括常规添加剂，如催化剂、抗氧化剂、紫外线吸收剂、流动控制剂或润湿剂、抗静电剂、颜料、增塑剂、溶剂等。本组合物的低聚物还可与非琼脂分散体（NAD）相容。
• Polyurethane elastomers comprising a charge-control agent and shaped elements therefrom
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0272587A2

  公开（公告）日：1988-06-29

  Herein are disclosed charge-control agents for polyurethane elastomers having the formula: R² represents oxyphenylene sulfonate, oxycyclohexylene sulfonate, or p-toluenesulfonamido­sulfonyl; R³ represents a straight or branched chain alkylene group having 2 to 7 carbon atoms; R⁴ is the same as R³ or is -(-R⁵-O-)R⁵; R⁵ is the same as R³; M represents hydrogen, an alkali metal, ammonium or P⁺(C₆H₅)₃CH₃ and m, n and x are integers which together are of sufficient value to achieve an R¹ molecular weight of 300 to 30,000. The elastomers are useful in making shaped articles.

  本文公开了用于聚氨酯弹性体的电荷控制剂，其式如下 R²代表氧苯磺酸酯、氧环己烷磺酸酯或对甲苯磺酰胺磺酰基； R³ 代表具有 2 至 7 个碳原子的直链或支链亚烷基； R⁴ 与 R³ 相同或为-(-R⁵-O-)R⁵； R⁵ 与 R³ 相同； M 代表氢、碱金属、铵或 P⁺(C₆H₅)₃CH₃，以及 m、n 和 x 是整数，它们的合计值足以使 R¹ 分子量达到 300 至 30000。 这种弹性体可用于制造成型物品。