2,6-diallylnaphthalene-1,5-diol | 132333-50-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2,6-diallylnaphthalene-1,5-diol
• 英文别名: 1,5-Dihydroxy-2,6-diallylnapthalene；2,6-bis(prop-2-enyl)naphthalene-1,5-diol
• CAS: 132333-50-7
• 化学式: C₁₆H₁₆O₂
• 分子量: 240.302
• InChiKey: XYXXWNDQYHVPFN-UHFFFAOYSA-N

物化性质

• 熔点：
  130-132 °C
• 沸点：
  419.3±40.0 °C(Predicted)
• 密度：
  1.148±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,6-diallylnaphthalene-1,5-diol 在 吡啶 、 sodium hydroxide 、 硼烷 、 双氧水 、 potassium carbonate 作用下， 以 二甲基亚砜 、 丙酮 为溶剂， 反应 32.83h， 生成 4-[6-(3-cyanopropyl)-1,5-dimethoxynaphthalen-2-yl]butanenitrile
  参考文献：
  名称：

  Takahashi, I.; Nomura, A.; Kitajima, H., Synthetic Communications, 1990, vol. 20, # 10, p. 1569 - 1575

  摘要：

  DOI：
• 作为产物：
  描述：

  1,5-二羟基萘 在 potassium carbonate 作用下， 以 乙腈 为溶剂， 反应 12.42h， 生成 2,6-diallylnaphthalene-1,5-diol
  参考文献：
  名称：

  烯丙基官能化的双氧萘[38] Crown-10大环：合成，自组装和硫醇官能化

  摘要：

  已合成了五个带有一个，两个，三个或四个烯丙基的二氧萘[38]-冠-10（DNP38C10）大环，并评估了它们与甲基紫精自组装形成[2]假轮烷的能力。发现甲基紫精和几个烯丙基官能化的DNP38C10大环之间的缔合常数与甲基紫精和未官能化的DNP38C10的缔合常数相当，但是，构成总结合自由能的焓和熵因子随烯丙基取代的增加而系统地变化。这些变化是通过对大环及其络合物的固溶相和固相分析相结合来解释的。赋予DNP38C10实用程序 烯丙基部分的大环化合物可通过硫醇-烯点击化学轻松地官能化，进一步证明了这一点。

  DOI：

  10.1002/chem.201303864

文献信息

• NOVEL NAPHTHYLENYL COMPOUNDS FOR LONG-ACTING INJECTABLE COMPOSITIONS AND RELATED METHODS
  申请人：Alkermes Pharma Ireland Limited

  公开号：US20200016151A1

  公开（公告）日：2020-01-16

  The present invention provides compounds useful for the treatment of opioid dependence, alcohol dependence, alcohol use disorder, or the prevention of relapse to opioid dependence in a subject in need thereof. Related pharmaceutical compositions and methods are also provided herein.

  本发明提供了用于治疗阿片类依赖、酒精依赖、酒精使用障碍或预防需要此类治疗的对象复发至阿片类依赖的化合物。相关的药物组合和方法也在此提供。
• 알콕시실릴기 및 활성 에스테르기를 갖는 화합물, 이의 제조방법, 이를 포함하는 조성물 및 용도
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY 한국생산기술연구원(319999029382) BRN ▼119-82-01008

  公开号：KR20170092468A

  公开（公告）日：2017-08-11

  본 발명은 에폭시 조성물의 경화시에 향상된 저흡습성 및/또는 저유전특성을 나타내지만, 열팽창 특성의 손실을 동반하지 않는 알콕시실릴기 및 활성 에스테르기를 갖는 새로운 화합물, 이의 제조방법, 이를 포함하는 조성물 및 용도에 관한 것이다. 본 발명에 의하면, 화학식 AF 내지 LF의 알콕시실릴기 및 활성 에스테르기를 갖는 새로운 화합물, 이의 제조방법, 이를 포함하는 조성물 및 이의 용도가 개시된다.

  这项发明涉及一种具有改进的低吸湿性和/或低膨胀特性而不伴随热膨胀特性损失的含有醇酰亚基和活性酯基的新化合物的固化物，其制备方法，包含它的组合物以及其用途。根据本发明，提供了一种具有化学式AF至LF的醇酰亚基和活性酯基的新化合物，其制备方法，包含它的组合物以及其用途。
• COMPOUND HAVING ALKOXYSILYL GROUP AND ACTIVE ESTER GROUP, METHOD FOR PREPARING SAME, COMPOSITION COMPRISING SAME, AND USE
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US20200165275A1

  公开（公告）日：2020-05-28

  The present invention relates to a novel compound having an alkoxysilyl group and an active ester group, a method for preparing the same, a composition comprising the same, and a use, wherein the novel compound exhibits improved low moisture absorption and/or low dielectric properties when cured as an epoxy composition, but is not accompanied by loss of thermal expansion characteristics. Disclosed are a novel compound of formulae AF to LF having an alkoxysilyl group and an active ester group, and a method for preparing the same, a composition comprising the same, and a use of same.

  本发明涉及一种具有烷氧基硅基团和活性酯基团的新化合物，以及其制备方法、包含该化合物的组合物和用途，其中该新化合物在作为环氧组合物固化时表现出改善的低吸湿性和/或低介电性能，但不伴随热膨胀特性的丧失。公开了具有烷氧基硅基团和活性酯基团的化合物AF至LF的新化合物，以及其制备方法、包含该化合物的组合物和用途。
• THERMOSETTING ALKOXYSILYL COMPOUND HAVING TWO OR MORE ALKOXYSILYL GROUPS, COMPOSITION AND CURED PRODUCT COMPRISING SAME, USE THEREOF, AND METHOD FOR PREPARING ALKOXYSILYL COMPOUND
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US20180155370A1

  公开（公告）日：2018-06-07

  The present invention relates to: a thermosetting alkoxysilyl compound (hereinafter, referred to as “alkoxysilyl compound”)having two or more alkoxysilyl groups showing excellent heat-resistance characteristics in a composite; a composition and a cured product comprising the same; a use thereof; and a method for preparing an alkoxysilyl compound. The composition of an alkoxysilyl compound, comprising a novel alkoxysilyl compound according to the present invention shows, in a composite, improved heat-resistance characteristics, i.e., an effect of decreasing the CTE of the composition of an alkoxysilyl compound and not showing a glass transition temperature (hereinafter, referred to as “Tg-less”). Further, the cured product comprising an alkoxysilyl compound according to the present invention shows excellent flame retardant properties due to the alkoxysilyl groups.

  本发明涉及一种热固性烷氧基硅基化合物（以下简称“烷氧基硅基化合物”），其具有两个或两个以上的烷氧基硅基团，在复合材料中表现出优异的耐热特性；包括该烷氧基硅基化合物的组合物和固化产物；其用途；以及制备烷氧基硅基化合物的方法。根据本发明的一种烷氧基硅基化合物的组合物显示出改善的耐热特性，即降低烷氧基硅基化合物组合物的CTE并且不显示玻璃转变温度（以下简称“Tg-less”）的效果。此外，根据本发明的一种烷氧基硅基化合物的固化产物由于烷氧基硅基团表现出优异的阻燃性能。
• EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, METHOD OF PREPARING THE SAME, COMPOSITION AND CURED PRODUCT COMPRISING THE SAME, AND USES THEREOF
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US20140179836A1

  公开（公告）日：2014-06-26

  Disclosed are an epoxy compound having an alkoxysilyl group, a composite of which exhibits good heat resistant properties and/or a cured product of which exhibits good flame retardant properties, a method of preparing the same, a composition comprising the same, and a cured product and a use of the composition. An alkoxysilylated epoxy compound comprising at least one of Chemical Formula S1 substituent and at least two epoxy groups in a core, a method of preparing the epoxy compound by an allylation, a claisen rearrangement, an epoxidation and an alkoxysilylation, an epoxy composition comprising the epoxy compound, and a cured product and a use of the composition are provided. The composite of the disclosed exhibits improved chemical bonding, good heat resistant properties, a low CTE, a high glass transition temperature or Tg-less The cured product of the composition exhibits good flame retardant properties.

  揭示了一种具有烷氧基硅基团的环氧化合物，其复合材料具有良好的耐热性能和/或其固化产物具有良好的阻燃性能，以及其制备方法，包括该化合物的组合物，固化产物和组合物的用途。所述的烷氧基硅化环氧化合物包括至少一种化学式S1取代基和至少两个环氧基团在核心中，通过烯丙基化、克莱森重排、环氧化和烷氧基硅化制备环氧化合物的方法，包括该环氧化合物的环氧组合物，固化产物和组合物的用途。所述的复合材料具有改善的化学键合、良好的耐热性能、低CTE、高玻璃转变温度或Tg-less。该组合物的固化产物具有良好的阻燃性能。