Butylamine dodecylbenzenesulfonate | 12068-09-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Butylamine dodecylbenzenesulfonate
• 英文别名: butan-1-amine;2-dodecylbenzenesulfonic acid
• CAS: 12068-09-6
• 化学式: C22H41NO3S
• 分子量: 399.6
• InChiKey: RMBGSBIZBRZJPK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.14
• 重原子数：
  27
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  88.8
• 氢给体数：
  2
• 氢受体数：
  4

文献信息

• Thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine and their herbicidal use
  申请人：MONSANTO COMPANY

  公开号：EP0008158A1

  公开（公告）日：1980-02-20

  This disclosure relates to thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine esters, to herbicidal compositions containing same and to the herbicidal use thereof. The thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine esters are useful as herbicides. The novel N-trifluoroacetyl-N-phosphonomethyl-glycinate thio derivatives of this invention are those having the formula wherein R is an alkyl group containing from 1 to 10 carbon atoms, a chloro lower alkyl group containing from 1 to 4 carbon atoms and 1 to 3 chlorine groups, a lower alkoxy lower alkyl group containing from 3 to 6 carbon atoms or an alkoxyalkoxyalkyl group containing from 5 to 9 carbon atoms and R' is a member of the group consisting of lower alkylthio. lower alkenylthio, benzylthio, phenylthio, or substituted phenylthio wherein the phenyl group contains 1 to 2 substituents selected from the group consisting of halo, lower alkyl and lower alkoxy.

  本公开涉及 N-三氟乙酰基-N-膦酰甲基甘氨酸酯的硫代衍生物、含有这些衍生物的除草组合物及其除草用途。N- 三氟乙酰基-N-膦酰甲基甘氨酸酯的硫代衍生物可用作除草剂。 本发明的新型 N-三氟乙酰基-N-膦酰甲基甘氨酸硫代衍生物是具有以下式子的衍生物 其中 R 是含 1 至 10 个碳原子的烷基、含 1 至 4 个碳原子和 1 至 3 个氯基团的氯代低 级烷基、含 3 至 6 个碳原子的低级烷氧基低级烷基或含 5 至 9 个碳原子的烷氧基烷基，而 R' 是由低级烷硫基、低级烯硫基、苄硫基、苯硫基或取代苯硫基组成的组的成员，其中苯基含有 1 至 2 个选自卤代、低级烷基和低级烷氧基组成的组的取代基。
• Amide and hydrazide derivatives of N-trifluoracetyl-N-phosphonomethylglycine, herbicidal compositions and their use
  申请人：MONSANTO COMPANY

  公开号：EP0008852A1

  公开（公告）日：1980-03-19

  This disclosure relates to alkyl N-trifluoroacetyl-N-phosphonomethylglycine amide and hydrazide derivatives, to herbicidal compositions containing same and to the herbicidal use thereof. These amide and hydrazide derivatives are useful as pre-emergent and/or post-emergent herbicides. The novel N-trifluoroacetyl-N-phosphonomethyl- glycinate amide and hydrazide derivatives of this invention are those havina the formula wherein R is an alkyl group of from 1 to 10 carbon atoms, a chloro lower alkyl group, a lower alkoxy lower alkyl group containing from 3 to 6 carbon atoms or a lower alkoxy lower alkoxy lower alkyl group containing from 5 to 9 carbon atoms, R' is hydrogen, lower alkyl, lower alkenyl or lower alkynyl, Z is a member of the class consisting of alkyl of from 1 to 6 carbon atoms, alkenyl of from 2 to 6 carbon atoms, alkynyl of from 3 to 6 carbon atoms, cycloalkyl containing from 3 to 7 carbon atoms or a R2 N - R3 group wherein R2 is lower alkyl, phenyl or substituted phenyl and R3 is hydrogen or lower alkyl and together with the nitrogen atom R2 and R3 can form a heterocyclic ring.

  本公开涉及烷基 N-三氟乙酰基-N-膦酰甲基甘氨酸酰胺和酰肼衍生物、含有这些衍生物的除草组合物及其除草用途。这些酰胺和酰肼衍生物可用作芽前和/或芽后除草剂。 本发明的新型 N-三氟乙酰基-N-膦酰甲基甘氨酸酰胺和酰肼衍生物是那些具有以下式子的衍生物 其中 R 是含 1 至 10 个碳原子的烷基、氯代低级烷基、含 3 至 6 个碳原子的低级烷氧基或含 5 至 9 个碳原子的低级烷氧基，R'是氢、低级烷基、低级烯基或低级炔基，Z 是由含 1 至 6 个碳原子的烷基、含 2 至 6 个碳原子的烯基、含 1 至 10 个碳原子的氯代低级烷基、含 3 至 6 个碳原子的低级烷氧基或含 5 至 9 个碳原子的低级烷氧基组成的类别的成员、R'是氢、低级烷基、低级烯基或低级炔基，Z 是由 1-6 个碳原子的烷基、2-6 个碳原子的烯基、3-6 个碳原子的炔基、含 3-7 个碳原子的环烷基或 R2 N - R3 基团（其中 R2 是低级烷基、苯基或取代苯基，R3 是氢或低级烷基，与氮原子 R2 和 R3 一起可形成杂环）组成的类别的成员。
• Derivatives of N-trifluoroacetyl N-phosphonomethylglycine dichloride, their preparation and their use as herbicides
  申请人：MONSANTO COMPANY

  公开号：EP0005321A1

  公开（公告）日：1979-11-14

  This disclosure relates to N-trifluoroacetyl-N-phosphonomethylglycine dichloride derivatives and to herbicidal compositions containing same. The N-trifluoroacetyl-N-phosphonomethylglycine dichlorides are useful as post-emergent herbicides. The compounds of the present invention are characterised by the formula - wherein R is chlorine, an alkoxy group containing from 1 to 10 carbon atoms, an alkoxyalkoxy group containing from 3 to 6 carbon atoms, an alkoxyalkoxyalkoxy group containing from 5 to 9 carbon atoms or a chloro lower alkoxy group. The herbicidal method of the present invention is characterised by applying a herbicidally effective amount of a compound characterised by the formula as shown above and wherein R is as defined above. The herbicidal composition of the present invention is characterised in that said composition comprises from about 5 to about 95 parts by weight of a compound characterised by the formula as shown above and wherein R is as defined above; the remaining parts being composed of one or more suitable carriers, diluents and/or adjuvants. Another aspect of the present invention is a process for the production of a compound of the present invention which comprises reacting a compound of the formula wherein R' is hydroxy, an alkoxy group containing from 1 to 10 carbon atoms, an alkoxyalkoxy group containing from 3 to 6 carbon atoms, an alkoxyalkoxyalkoxy group containing from 5 to 9 carbon atoms or a chloro lower alkoxy group with trifluoroacetic anhydride at a temperature of from 10°C to 35°C and reacting the resulting product with thionyl chloride at reflux temperature.

  本公开涉及 N-三氟乙酰基-N-膦酰甲基甘氨酸二氯化物衍生物和含有这些衍生物的除草组合物。N- 三氟乙酰基-N-膦酰甲基甘氨酸二氯化物可用作苗后除草剂。 本发明化合物的特征为式-- N-三氟乙酰基-N-膦酰甲基甘氨酸二氯化物。 其中 R 是氯、含 1 至 10 个碳原子的烷氧基、含 3 至 6 个碳原子的烷氧基烷氧基、含 5 至 9 个碳原子的烷氧基烷氧基烷氧基或氯低级烷氧基。 本发明除草方法的特点是施用除草有效量的化合物，该化合物的特征式如上所示，其中 R 如上所定义。 本发明除草组合物的特征在于，所述组合物包括按重量计约 5 至约 95 份由上式表征的化合物，其中 R 如上所定义；其余部分由一种或多种合适的载体、稀释剂和/或佐剂组成。 本发明的另一个方面是生产本发明化合物的工艺，该工艺包括使式如下的化合物反应 其中 R'为羟基、含有 1 至 10 个碳原子的烷氧基、含有 3 至 6 个碳原子的烷氧基烷氧基、含有 5 至 9 个碳原子的烷氧基烷氧基烷氧基或氯代低 级烷氧基烷氧基，与三氟乙酸酐在 10℃至 35℃的温度下反应，并在回流温度下将生成物与亚硫酰氯反应。
• Derivatives of N-trifluoroacetyl-N-phosphonomethylglycinates and the herbicidal use thereof
  申请人：MONSANTO COMPANY

  公开号：EP0007211A1

  公开（公告）日：1980-01-23

  This disclosure relates to derivatives of N-trifluoroacetyl-N-phosphonomethylglycinates wherein different moieties are attached to the phosphorus atom, to herbicidal compositions containing same and to the herbicidal use thereof. The novel N-trifluoroacetyl-N- phosphonomethylglycinates of this invention are those having the formula wherein R is an alkyl group of from 1 to 10 carbon atoms or chlorinated lower alkyl group, R, is a member of the group consisting of lower alkoxy, lower alkylthio, phenoxy, phenylthio, substituted phenoxy, substituted phenylthio, lower alkylamino, lower dialkylamino, morpholino and N-piperidinoamino and R2 is a member of the group consisting of lower alkylthio, phenoxy, phenylthio, substituted phenoxy, substituted phenylthio, lower alkylamino, lower dialkylamino, lower alkenylamino, lower dialkenylamino, lower alkynylamino, lower dialkynylamino, morpholino and N-piperidinoamino with the proviso that R, and R2 cannot represent the same group.

  本发明涉及N-三氟乙酰基-N-膦酰甲基甘氨酸盐的衍生物（其中磷原子上连接有不同的分子）、含有这些衍生物的除草组合物及其除草用途。 本发明的新型 N-三氟乙酰基-N-膦酰甲基甘氨酸盐是那些具有以下式子的化合物 其中 R 是 1 至 10 个碳原子的烷基或氯化低级烷基，R 是由低级烷氧基、低级烷硫基、苯氧基、苯硫基、取代苯氧基、取代苯硫基、低级烷氨基、低级二烷基氨基、吗啉基和 N-哌啶氨基组成的基团的成员，R2 是由低级烷硫基、苯氧基、苯硫基、取代苯氧基、取代苯硫基、低级烷氨基、低级二烷基氨基、吗啉基和 N-哌啶氨基组成的基团的成员、苯氧基、苯硫基、取代的苯氧基、取代的苯硫基、低级烷基氨基、低级二烷基氨基、低级烯基氨基、低级二烯基氨基、低级炔基氨基、低级二炔基、吗啉基和 N-哌啶氨基，但 R 和 R2 不能代表相同的基团。
• Amido and hydrazido derivatives of N-phosphinothioylmethylglycine esters and herbicidal compositions containing them
  申请人：MONSANTO COMPANY

  公开号：EP0031714A1

  公开（公告）日：1981-07-08

  This invention relates to a new class of organic chemical compounds. More particularly, this invention is concerned with amido and hydrazido derivatives of N-phosphinothioylmethylglycine esters. This class of compounds has been found to be useful as herbicides. The compounds of the present invention are compounds of the formula. wherein R is a member of the group consisting of alkyl of from 1 to 8 carbon atoms, chloroalkyl of from 1 to 4 carbon atoms and from 1 to 3 chlorine atoms and alkoxyalkyl containing from 3 to 7 carbon atoms and wherein Z is a member of the class consisting of wherein each R' is individually selected from the class consisting of hydrogen, C1-C4 alkyl, C2-C4 alkenyl, C3-C7 cycloalkyl, benzyl or phenyl; a heterocyclic group selected from the class consisting of morpholine, pyrrolidine or piperidine: or a group wherein Z1 is a group wherein R" is hydrogen, C1-C4 alkyl or phenyl; a heterocyclic group selected from the class consisting of piperidine. pyrrolidine and morpholine.

  本发明涉及一类新的有机化合物。更具体地说，本发明涉及 N-膦硫酰甲基甘氨酸酯的氨基和酰肼衍生物。这一类化合物已被发现可用作除草剂。 本发明的化合物是式中的化合物。 其中 R 是由 1 至 8 个碳原子的烷基、1 至 4 个碳原子和 1 至 3 个氯原子的氯烷基和含 3 至 7 个碳原子的烷氧基烷基组成的组中的成员，Z 是由以下组成的组中的成员 其中每个 R'单独选自氢、C1-C4 烷基、C2-C4 烯基、C3-C7 环烷基、苄基或苯基；选自吗啉、吡咯烷或哌啶的杂环基团；或 其中 Z1 为 其中 R "为氢、C1-C4 烷基或苯基的基团；从哌啶、吡咯烷和吗啉组成的类中选出的杂环基团。