Methyl-bis(dimethylphosphinomethyl)phosphan | 81626-09-7

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: Methyl-bis(dimethylphosphinomethyl)phosphan
• 英文别名: bis(dimethylphosphinomethyl)methylphosphine；bis(dimethylphosphanylmethyl)-methylphosphane
• CAS: 81626-09-7
• 化学式: C₇H₁₉P₃
• 分子量: 196.149
• InChiKey: COFMDJWYDSURQW-UHFFFAOYSA-N

物化性质

• 沸点：
  229.7±25.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Methyl-bis(dimethylphosphinomethyl)phosphan 在 Na(B(C₆H₅)4) 、 sodium iodide 作用下， 以 甲醇 、 二氯甲烷 、 丙酮 为溶剂， 生成 (Rh2(μ-dmmm)2(CO)I)(BPh4)
  参考文献：
  名称：

  Di-rhodium(I) and tri-rhodium(I) complexes with bridging bis(dimethylphosphinomethyl) methylphosphine

  摘要：

  DOI：

  10.1016/0022-328x(88)80454-6
• 作为产物：
  描述：

  甲基氯化镁 、 Dichloro-[[chloro(dichlorophosphanylmethyl)phosphanyl]methyl]phosphane 反应 16.0h， 以43%的产率得到Methyl-bis(dimethylphosphinomethyl)phosphan
  参考文献：
  名称：

  线型低聚磷烷XIII。三磷烷mitdemPCPCP-donorskelett; 配体配体

  摘要：

  在合成Cl 2 PCH 2 PCl 2（II）中，副产物三磷烷Cl 2 PCH 2 PClCH 2 PCl 2（III）形成。用MeMgCl或EtOH（在碱存在下）处理III时，可以令人满意的产率获得甲基或乙氧基衍生物（V或VI）。V与Ni（CO）4或Fe 2（CO）9形成三核络合物[（CO）n M] PMe 2 CH 2 PMe [M（CO）n ] CH 2 PMe 2 [M（CO）n ]（X ，XIII；MFe，Ni；n= 4，3 ）或双核稳定的六元螯合环系统[M（CO）n ]-PMe（CH 2 PMe 2）2 [M（CO）m ]（IX，XIV; M = Fe，Ni：n = 4，3：m = 3，2）。过量的Fe 2（CO）9（摩尔比V / Fe 2（CO）9 1/5）分别产生具有FeFe键的XI或簇XII。在这两种情况下，V都将FeFe键与PCP供体连接。

  DOI：

  10.1016/0022-328x(85)80372-7

文献信息

• Novel luminescent polynuclear gold(I) phosphine complexes. Synthesis, spectroscopy, and X-ray crystal structure of [Au3(dmmp)2]3+[dmmp = bis(dimethylphosphinomethyl)methylphosphine]
  作者：Vivian Wing-Wah Yam、Ting-Fong Lai、Chi-Ming Che

  DOI：10.1039/dt9900003747

  日期：——

  (dmmp) in the presence of thiodiglycol (2,2′-thiodiethanol) in methanol yielded [Au3(dmmp)2]3+, which was isolated as its perchlorate salt. The X-ray crystal structure of [Au3(dmmp)2][ClO4]3 has been determined: monoclinic, space group P21/n, a= 1 2.880(3), b= 14.210(1), c= 21.208(2)Å, β= 106.25(1)°, Z= 4, R= 0.047 for 2 927 observed Mo-Kα data. The Au–Au–Au bond angle of 136.26(4)° is greatly distorted

  K [AuCl 4 ]与双（二甲基膦基甲基）甲基膦（dmmp）在硫二甘醇（2,2'-thiodiethanol）的存在下在甲醇中反应生成[Au 3（dmmp）2 ] 3+，将其作为高氯酸盐分离。已确定[Au 3（dmmp）2 ] [ClO 4 ] 3的X射线晶体结构：单斜晶系，空间群P 2 1 / n，a = 1 2.880（3），b = 14.210（1），c = 21.208（2）Å，β= 106.25（1）°，Z = 4，R= 0.047 2 927观察到钼ķ α的数据。136.26（4）°的Au–Au–Au键角与直线几何形状大相径庭，分子内Au⋯Au距离为2.981（1）和2.962（1）Å。脱气的乙腈溶液激励[金3（DMMP）2 ] 3+在300-370纳米导致双磷光（λ= 467纳米，τ 0 = 1.6±0.2微秒;λ= 580纳米，τ 0 = 7.0± 0.5 µs）。[Au
• [EN] CATALYTIC PROCESS FOR PREPARING AN α,β-ETHYLENICALLY UNSATURATED CARBOXYLIC ACID SALT<br/>[FR] PROCÉDÉ CATALYTIQUE POUR LA PRÉPARATION D'UN SEL D'ACIDE CARBOXYLIQUE À INSATURATION ÉTHYLÉNIQUE α ET β
  申请人：BASF SE

  公开号：WO2021185879A1

  公开（公告）日：2021-09-23

  A catalytic process for preparing an α,β-ethylenically unsaturated carboxylic acid salt, comprising a) contacting an alkene and carbon dioxide with a carboxylation catalyst, an organic solvent, and an alkoxide having a secondary or tertiary carbon atom directly bound to an [O-] group, to obtain a crude reaction product comprising the α,β-ethylenically unsaturated carboxylic acid salt and an alcohol by-product which is the conjugate acid of the alkoxide, b) allowing the α,β-ethylenically unsaturated carboxylic acid salt to precipitate out from the crude reaction product; and c) subjecting at least part of the crude reaction product to a mechanical separation step while maintaining the alcohol by-product in liquid form to obtain a solid phase comprising the α,β-ethylenically unsaturated carboxylic acid salt and a liquid phase comprising the carboxylation catalyst, the organic solvent and the alcohol by-product. The process allows for easy separation of the α,β-ethylenically unsaturated carboxylic acid salt by a mechanical separation operation.

  一种制备α，β-乙烯基不饱和羧酸盐的催化过程，包括a）将烯烃和二氧化碳与羧化催化剂、有机溶剂和直接与[O-]基团相结合的二级或三级碳原子的烷氧基接触，以获得包含α，β-乙烯基不饱和羧酸盐和醇副产物的原始反应产物，该醇副产物是烷氧基的共轭酸，b）使α，β-乙烯基不饱和羧酸盐从原始反应产物中沉淀出来；c）在保持醇副产物处于液态的情况下，对至少部分原始反应产物进行机械分离步骤，以获得包含α，β-乙烯基不饱和羧酸盐的固相和包含羧化催化剂、有机溶剂和醇副产物的液相。该过程允许通过机械分离操作轻松分离α，β-乙烯基不饱和羧酸盐。
• Process for preparing an unsaturated carboxylic acid salt
  申请人：BASF SE

  公开号：US10138196B2

  公开（公告）日：2018-11-27

  A catalytic process for preparing an α,β-ethylenically unsaturated carboxylic acid salt from an alkene, carbon dioxide and an alkoxide having a secondary or tertiary carbon atom directly bound to a [O−] group is described. The alcohol byproduct is distilled off after an intermediate phase separation. This provides pure β,β-ethylenically unsaturated carboxylic acid salt at minimum effort.

  描述了一种从烯、二氧化碳和具有直接与 [O-] 基团结合的仲碳原子或三碳原子的氧化烷烃制备 α、β-乙烯基不饱和羧酸盐的催化工艺。中间相分离后，蒸馏出副产物醇。这样就能以最小的代价得到纯的β,β-乙烯基不饱和羧酸盐。
• Karsch, Hans H.; Appelt, Armin, Phosphorus and Sulfur and the Related Elements, 1983, vol. 18, p. 287 - 290
  作者：Karsch, Hans H.、Appelt, Armin

  DOI：——

  日期：——
• Synthesis, characterization and photophysics of luminescent organogold(I) phosphines
  作者：Vivian Wing-Wah Yam、Sam Wing-Kin Choi

  DOI：10.1039/dt9940002057

  日期：——

  Reaction of [Au2(dmpm)Cl2] or [Au3(dmmp)Cl3] with an excess of organolithium reagent LiR in diethyl ether gave [Au2(dmpm)R2] or [Au3(dmmp)R3] in high yield [dmpm = MePCH2PMe2; dmmp = Me2PCH2P(Me)CH2PMe2; R = Me or C6H4OMe-p]. These compounds were found to be emissive both in the solid state and in fluid solutions. An excited-state redox potential of -2.0(1) V vs. sodium chloride saturated calomel electrode has been estimated for [Au3(dmmp)(C6H4OMe-p)3].