2,2'-oxamidobis(benzoic acid) | 69796-56-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2'-oxamidobis(benzoic acid)
• 英文别名: N,N'-bis(2-dicarboxyphenyl)oxalamide；2,2'-[(1,2-dioxoethane-1,2-diyl)diimino] dibenzoic acid；N,N'-Bis--oxamid；oxamide bis(2-benzoic) acid；N,N'-oxalyl-di-anthranilic acid；N,N'-Oxalyl-di-anthranilsaeure；N.N'-Oxalyl-bis-(2-amino-benzoesaeure)；N.N'-Bis-(2-carboxy-phenyl)-oxamid；Oxanilid-dicarbonsaeure-(2.2')；2-[[2-(2-carboxyanilino)-2-oxoacetyl]amino]benzoic acid
• CAS: 69796-56-1
• 化学式: C₁₆H₁₂N₂O₆
• 分子量: 328.281
• InChiKey: ZWIKJXQWYLXXOG-UHFFFAOYSA-N

物化性质

• 熔点：
  345 °C
• 密度：
  1.574±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  133
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,2'-oxamidobis(benzoic acid) 在 乙酸酐 作用下， 生成 2,2'-bis(benzo-1,3-oxazinyl)-6,6'-dione
  参考文献：
  名称：

  Heller, Chemische Berichte, 1915, vol. 48, p. 1191

  摘要：

  DOI：
• 作为产物：
  描述：

  [(2-甲基苯基)氨基](氧代)乙酸 在 potassium permanganate 、 乙酰氯 作用下， 生成 2,2'-oxamidobis(benzoic acid)
  参考文献：
  名称：

  Mauthner; Suida, Monatshefte fur Chemie, 1888, vol. 9, p. 732

  摘要：

  DOI：

文献信息

• Identification of degradation products of indigoids by tandem mass spectrometry
  作者：Katarzyna Witkoś、Katarzyna Lech、Maciej Jarosz

  DOI：10.1002/jms.3641

  日期：2015.11

  The study concerns identification of photodegradation products of indigotin, indirubin and isoindigo. Experimental methodology consists of degradation of standard solutions of indigoids in a solar box and analysis of samples taken at different aging time by using capillary high-performance liquid chromatography coupled with electrospray ionization tandem mass spectrometric and spectrophotometric detectors. Identification of the formed compounds was based on careful interpretation of the electrospray ionization MS/MS spectra. Apart from the well-known degradation products of indigoids: isatin, isatoic anhydride and anthranilic acid, another seven species were also identified, and their proposed structures were confirmed by high-resolution molecular masses measurements; according to the best knowledge of authors, they have not been reported so far. The obtained results formed the basis for postulating mechanism of the process. Moreover, the MRM (Multiple Reaction Monitoring) method was developed for the identification of natural dyes and their degradation products in textiles of historical value. Apart from such colorants as indigotin and flavonoids, also presence of degradation products of indigoids was confirmed. Copyright © 2015 John Wiley & Sons, Ltd.

  研究涉及靛蓝、靛红和异靛的光降解产物的鉴定。实验方法包括在太阳箱中对靛蓝标准溶液进行降解，并使用毛细管高效液相色谱法结合电喷雾离子化串联质谱和分光光度检测器对不同老化时间的样品进行分析。根据对电喷雾电离 MS/MS 图谱的仔细解读，对形成的化合物进行了鉴定。除了众所周知的靛蓝降解产物：异靛红、异靛酸酐和蚁酸外，还鉴定出另外七种化合物，并通过高分辨率分子质量测量确认了它们的拟议结构；据作者所知，这些化合物迄今为止尚未见报道。所获得的结果为推测这一过程的机理奠定了基础。此外，还开发了 MRM（多重反应监测）方法，用于鉴定具有历史价值的纺织品中的天然染料及其降解产物。除了靛红和类黄酮等着色剂外，还确认了靛蓝的降解产物。Copyright © 2015 John Wiley & Sons, Ltd. All Rights Reserved.
• A novel molecular based ferromagnet ordering at 14 K
  作者：Francisco Lloret、Keitaro Nakatani、Yves Journaux、Olivier Kahn、Yu Pei、Jean Pierre Renard

  DOI：10.1039/c39880000642

  日期：——

  The compound MnCu(obbz)·H2O [obbz = oxamido bis(benzoato)], obtained by reaction of the Mn2+ ion with the copper(II)‘brick’[Cu(obbz)]2–, orders ferromagnetically at Tc= 14 K; below Tc it exhibits a hysteresis loop characteristic of a soft ferromagnet.

  MnCu（obbz）·H 2 O [obbz = oxamido bis（benzoato）]，是通过Mn 2+离子与铜（II）'砖'[Cu（obbz）] 2–的反应获得的，在T c = 14 K; 低于T c时，它表现出软铁磁体的磁滞回线特性。
• Oxalamide based coordination polymers
  作者：Antigoni Margariti、Eleni Moushi、Anastasios J. Tasiopoulos、Albert Escuer、Giannis S. Papaefstathiou

  DOI：10.1080/00958972.2020.1851369

  日期：2021.2.1

  Employment of N,N′-bis(2-dicarboxyphenyl)-oxalamide (H4L) in the M2+ chemistry (M = Mg, Mn, Co, Ni, and Zn) afforded five 2-D coordination polymers and one 1-D coordination polymer. The crystal str...

  在 M2+ 化学（M = Mg、Mn、Co、Ni 和 Zn）中使用 N,N'-双（2-二羧基苯基）-草酰胺 (H4L) 提供了五种二维配位聚合物和一种一维配位聚合物. 水晶头...
• Synthesis of Bridged and Metallobridged Bis(β-cyclodextrin)s Containing Fluorescent Oxamidobisbenzoyl Linkers and Their Selective Binding towards Bile Salts
  作者：Yu Liu、Hong-Mei Yu、Yong Chen、Yan-Li Zhao

  DOI：10.1002/chem.200501187

  日期：2006.5.3

  host-linker-guest binding mode, the stoichiometric 1:1 complexes formed by bis(beta-CD)s 2-5 with bile salts gave high stability constants (KS values) of up to 10(3)-10(4) M(-1). Significantly, benefiting from the intramolecular 1:2 or 2:4 binding stoichiometry, the resulting complexes of metallobis(beta-CD)s 6-9 with bile salts gave much higher KS values of up to 10(6)-10(7) M(-2). The enhanced binding abilities

  一系列β-环糊精（β-CD）二聚体，包含荧光2,2'-氧酰胺基双苯甲酰基和4,4'-氧酰胺基双苯甲酰基接头，即6,6'-[2,2'-氧酰胺基双（苯甲酰基氨基）]亚乙基氨基-6,6'-脱氧双（β-CD）（2），6,6'-[2,2'-氧酰胺基双（苯甲酰氨基）]二亚乙基二氨基-6,6'-脱氧双（β-CD）（ 3），6,6'-[4,4'-氧酰胺基双（苯甲酰基氨基）]亚乙基氨基-6,6'-脱氧双（β-CD）（4）和6,6'-[4,4'-氧酰胺基双（苯甲酰基氨基）二亚乙基二氨基-6,6'-脱氧-双（β-CD）（5）-是通过用单[6-氨基亚乙基氨基-6-脱氧]-处理从相应的氧胺二双（苯甲酸）s合成的β-CD或单[6-二亚乙基三氨基-6-脱氧]-β-CD。用高氯酸铜进一步处理2-5，以令人满意的产率得到它们的Cu（II）络合物6-9。在Tris-HCl缓冲溶液中，通过圆二色性，二维NMR光谱和荧光光谱，全
• EP1489068
  申请人：——

  公开号：——

  公开（公告）日：——