anti-methylphenylglyoxime | 17019-18-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: anti-methylphenylglyoxime
• 英文别名: anti-Methyl-phenyl-glyoxim；β-Phenyl-methyl-glyoxim；1-phenyl-propane-1,2-dione (E,E)-dioxime；1-Phenyl-propan-1,2-dion-(E,E)-dioxim；1-Phenyl-propandion-(1.2)-di-seqtrans-oxim；β-Methylphenylglyoxim；Methylphenyl glyoxime；(NE)-N-[(1E)-1-hydroxyimino-1-phenylpropan-2-ylidene]hydroxylamine
• CAS: 17019-18-0
• 化学式: C₉H₁₀N₂O₂
• 分子量: 178.191
• InChiKey: OHOFOAMRUFMQPH-BDFJVSTISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  65.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  anti-methylphenylglyoxime 在 sodium hydroxide 作用下， 生成 3-methyl-4-phenylfurazan
  参考文献：
  名称：

  Milone, Gazzetta Chimica Italiana, 1932, vol. 62, p. 432,434

  摘要：

  DOI：
• 作为产物：
  描述：

  1-苯基-1,2-丙二酮 在 盐酸羟胺 作用下， 以 乙醇 为溶剂， 反应 6.0h， 以58%的产率得到anti-methylphenylglyoxime
  参考文献：
  名称：

  一种用于金属镍快速检测的新材料及其制备与应用

  摘要：

  本发明公开了一种用于金属镍快速检测的新材料及其制备与应用，所述检测材料为式Ⅰ所示的结构，其中，M1、M2独立地为O或S；R1为三～八元环，该环包括单环或由至少两个单环构成的多环；R2为含有至少一个非H原子的链或三～六元环。该新材料可以选择性的与镍离子结合，并将对镍离子的最低检出浓度提高至0.01mg/L，远远优于国家标准，能够适应更多要求更严格的行业或企业，意义极大，解决了现有技术中的不足。

  公开号：

  CN112979495A

文献信息

• Method for preparing aminoarylborane compounds or derivatives thereof
  申请人：Université de Bordeaux I

  公开号：EP2881398A1

  公开（公告）日：2015-06-10

  The present invention provides a process for the preparation of aminoarylborane compounds and derivatives thereof comprising a step of arylation by reacting an aryl chloride with an aminoborane compound in the presence of a catalytic system. Typically, the transformation comprises, converting Aryl-chloride Ar-Cl with an aminoborane such as into an aminoarylborane compound of the following formula:

  本发明提供了一种制备氨基芳基硼化合物及其衍生物的方法，包括通过在催化体系存在下，将芳基氯化物与氨基硼烷化合物反应进行芳基化的步骤。通常，该转化包括将芳基氯化物Ar-Cl与氨基硼烷化合物反应，转化为以下式的氨基芳基硼化合物：
• PROCESS FOR PREPARING ALPHA-(3-BENZYLPHENYL)PROPIONIC ACID DERIVATIVE
  申请人：NIPPON PETROCHEMICALS COMPANY, LIMITED

  公开号：EP0306538A1

  公开（公告）日：1989-03-15

  A process for preparing a-(3-benzylphenyl)propionic acid or its derivative, a precursor of ketoprofen (trade name), which comprises dehydrogenating a by-product oil fraction formed in the production of ethylbenzene using synthetic zeolite as an alkylating catalyst, and carbonylating the product with carbon monoxide or the like. This precursor can be easily converted into ketoprofen, a useful medicine as an anti-inflammatory agent.

  一种制备 a-(3-苄基苯基)丙酸或其衍生物，即酮洛芬（商品名）前体的工艺，包括使用合成沸石作为烷基化催化剂对乙苯生产过程中形成的副产品油馏分进行脱氢，并用一氧化碳或类似物质对产品进行羰基化。这种前体可以很容易地转化成酮洛芬，它是一种有用的消炎药。
• Alkyl cobalt (III) dioximates and process for forming the same
  申请人：——

  公开号：US20020087006A1

  公开（公告）日：2002-07-04

  This invention is directed to alkyl cobalt (III) dioximates and methods for making these dioximates. The alkyl cobalt (III) dioximate has the following structural formula: 1 wherein R 1 , and R 2 are individually selected from the following group: H, alkyl having at least 2 carbon atoms, substituted alkyl, aryl, substituted aryl, COOR 5 , CONR 6 R 7 , SR 7 , SO 2 R 7 , SO 2 NR 5 R 6 , SOR 5 , SO 3 R 5 , halogen, CCl 3 , CF 3 , COR 5 , CHO, CR 6 R 7 OR 5 , CH(OR 5 )(OR 6 ), CR 5 (OR 6 )(OR 7 ); where R 5 , R 6 , and R 7 are independently selected from the following group: H, alkyl, substituted alkyl, aryl or substituted aryl and A is a substituted alkyl derived from an olefinic component and B is a component of a Lewis base and where the substituents of the substituted alkyl are individually selected from the group of ester, ether, amide, halogen, ketone, hydroxy, aryl, SO 2 -alkyl, sulfamido, and amino groups and the substituents for the substituted aryl are individually selected from the group of ester, ether, amide, halogen, ketone, hydroxy, alkyl, SO 2 -alkyl, sulfamido, and amino groups.

  本发明涉及烷基钴(III)二恶英盐和制造这些二恶英盐的方法。烷基钴（III）二噁英酸盐的结构式如下： 1 其中 R 1 和 R 2 分别选自以下组别：H、至少有 2 个碳原子的烷基、取代的烷基、芳基、取代的芳基、 COOR 5 、CONR 6 R 7 , SR 7 , SO 2 R 7 , SO 2 NR 5 R 6 , SOR 5 , SO 3 R 5 卤素、CCl 3 、CF 3 COR 5 CHO, CR 6 R 7 OR 5 , CH(OR 5 ）(OR 6 ）、CR 5 (OR 6 ）（或 7 ）；其中 R 5 , R 6 和 R 7 独立地选自以下基团：H、烷基、取代的烷基、芳基或取代的芳基，A 是衍生自烯烃组分的取代的烷基，B 是路易斯碱的组分，其中取代的烷基的取代基独立地选自酯、醚、酰胺、卤素、酮、羟基、芳基、SO 2 -烷基、氨基磺酰基和氨基，而取代芳基的取代基则分别选自酯、醚、酰胺、卤素、酮、羟基、烷基、SO 2 -烷基、氨基磺酰基和氨基。
• Alkyl cobalt(III) dioximates and process for forming the same
  申请人：——

  公开号：US20030135054A1

  公开（公告）日：2003-07-17

  This invention is directed to alkyl cobalt (III) dioximates and methods for making these dioximates. The alkyl cobalt (III) dioximate has the following structural formula: 1 wherein R 1 , and R 2 are individually selected from the following group: H, alkyl having at least 2 carbon atoms, substituted alkyl, aryl, substituted aryl, COOR 5 , CONR 6 R 7 , SR 7 , SO 2 R 7 , SO 2 NR 5 R 6 , SOR 5 , SO 3 R 5 , halogen, CCl 3 , CF 3 , COR 5 , CHO, CR 6 R 7 OR 5 , CH(OR 5 )(OR 6 ), CR 5 (OR 6 )(OR 7 ); where R 5 , R 6 , and R 7 are independently selected from the following group: H, alkyl, substituted alkyl, aryl or substituted aryl and A is a substituted alkyl derived from an olefinic component and B is a component of a Lewis base and where the substituents of the substituted alkyl are individually selected from the group of ester, ether, amide, halogen, ketone, hydroxy, aryl, SO 2 -alkyl, sulfamido, and amino groups and the substituents for the substituted aryl are individually selected from the group of ester, ether, amide, halogen, ketone, hydroxy, alkyl, SO 2 -alkyl, sulfamido, and amino groups.

  本发明涉及烷基钴(III)二恶英盐和制造这些二恶英盐的方法。烷基钴（III）二噁英酸盐的结构式如下： 1 其中 R 1 和 R 2 分别选自以下组别：H、至少有 2 个碳原子的烷基、取代的烷基、芳基、取代的芳基、 COOR 5 、CONR 6 R 7 , SR 7 , SO 2 R 7 , SO 2 NR 5 R 6 , SOR 5 , SO 3 R 5 卤素、CCl 3 、CF 3 COR 5 CHO, CR 6 R 7 OR 5 , CH(OR 5 ）(OR 6 ）、CR 5 (OR 6 ）（或 7 ）；其中 R 5 , R 6 和 R 7 独立地选自以下基团：H、烷基、取代的烷基、芳基或取代的芳基，A 是衍生自烯烃组分的取代的烷基，B 是路易斯碱的组分，其中取代的烷基的取代基独立地选自酯、醚、酰胺、卤素、酮、羟基、芳基、SO 2 -烷基、氨基磺酰基和氨基，而取代芳基的取代基则分别选自酯、醚、酰胺、卤素、酮、羟基、烷基、SO 2 -烷基、氨基磺酰基和氨基。
• Pigenet,C. et al., Bulletin de la Societe Chimique de France, 1970, p. 2124 - 2132
  作者：Pigenet,C. et al.

  DOI：——

  日期：——