N-((3-(triethoxysilyl)propyl)carbamothioyl)benzamide | 120183-09-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-((3-(triethoxysilyl)propyl)carbamothioyl)benzamide
• 英文别名: N-(3-triethoxysilylpropylcarbamothioyl)benzamide
• CAS: 120183-09-7
• 化学式: C₁₇H₂₈N₂O₄SSi
• 分子量: 384.572
• InChiKey: FEDFFLNKYWEZKS-UHFFFAOYSA-N

物化性质

• 密度：
  1.108±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.73
• 重原子数：
  25
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  101
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  3-氨基丙基三乙氧基硅烷 、 苯甲酰基异硫氰酸酯 生成 N-((3-(triethoxysilyl)propyl)carbamothioyl)benzamide
  参考文献：
  名称：

  Cauzzi, Daniele; Lanfranchi, Maurizio; Marzolini, Giovanna, Gazzetta Chimica Italiana, 1994, vol. 124, # 10, p. 415 - 422

  摘要：

  DOI：

文献信息

• Highly efficient adsorption behavior of benzoylthiourea functionalized graphene oxide with respect to the removal of Hg(II) from aqueous solutions: isothermal, kinetic and thermodynamic studies
  作者：Farnaz Movahedi、Hassan Masrouri、Hanieh Tayyebi

  DOI：10.1007/s11164-018-3431-z

  日期：2018.9

  silanization reaction between hydroxyl groups on the surface of GO and N -((3-(triethoxysilyl)propyl)carbamothioyl)benzamide (CTBz). The synthesis and immobilization processes were characterized by FT-IR, XRD, CHN, TGA, SEM, TEM and BET. The CTBz-GO was rendered to sequestrate Hg(ΙΙ) from aqueous solution and exhibited a higher adsorption capacity compared to many other previous reports based on the ion exchange

  氧化石墨烯（GO）通过GO和 N 表面的羟基之间的硅烷化反应成功地被苯甲酰硫脲官能化 -（（3-（三乙氧基甲硅烷基）丙基）氨基甲硫酰基）苯甲酰胺（CTBz）。通过FT-IR，XRD，CHN，TGA，SEM，TEM和BET对合成和固定过程进行了表征。与基于离子交换，静电引力，特别是基于表面上CTBz部分的金属络合能力的许多其他先前报道相比，使CTBz-GO从水溶液中螯合Hg（III）并表现出更高的吸附能力。 GO。研究了pH，接触时间，温度和多种金属初始浓度的影响，以优化吸附条件。吸附动力学数据使用拟二级模型很好地描述，平衡数据很好地拟合了Langmuir等温线并遵循化学吸附机理。此外， T  ＝ 25℃。计算得出的热力学参数表明吸附过程是吸热的和自发的。此外，使用2 mol / L硝酸作为再生剂的再生研究表明，其可重复使用性高，最多可进行五个循环。
• Anchoring rhodium(I) on benzoylthiourea-functionalized silica xerogels. Production of recyclable hydroformylation catalysts and the crystal structure of the model compound [Rh(cod)(Hbztu)Cl]
  作者：Daniele Cauzzi、Maurizio Lanfranchi、Giovanna Marzolini、Giovanni Predieri、Antonio Tiripicchio、Mirco Costa、Roberto Zanoni

  DOI：10.1016/0022-328x(94)00009-2

  日期：1995.2

  Two benzoylthiourea-functionalized silica xerogels, 4.5SiO(2).SiO3/2(CH2)(3)NHC(S)NHC(O)Ph (XGbztu) and SiO3/2 (CH2)(3)NHC(S)NHC(O)Ph (XGbztu*) have been prepared from (EtO)(3)Si(CH2)(3)NHC(S)NHC(O)Ph by the sol-gel process. They are able to bind rhodium(I) species giving the composite materials Rh/XGbztu and Rh/XGbztu*, which are very active insoluble and recoverable catalysts for the hydroformylation of styrene. The anchored species undergo major changes during the catalytic cycles, particularly in the Rh/XGbztu system, whose iso/normal selectivity ratio gradually increased in the first five runs. Furthermore, CH3(CH2)(2)NHC(S)NHC(O)Ph (HBztu) has been studied as a model of the surface binding function. The structure of [Rh(cod)(Hbztu)Cl](1), which represents a suitable molecular model for the anchored complexes, has been determined by X-ray diffraction.
• PANSTER, PETER;GRETHE, HORST;KLEINSCHMIT, PETER
  作者：PANSTER, PETER、GRETHE, HORST、KLEINSCHMIT, PETER

  DOI：——

  日期：——
• SKOPENKO, V. V.;TROFIMCHUK, A. K.;BRUSKINA, I. M.;SIMONOVA, L. N.;TRYASHI+
  作者：SKOPENKO, V. V.、TROFIMCHUK, A. K.、BRUSKINA, I. M.、SIMONOVA, L. N.、TRYASHI+

  DOI：——

  日期：——